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| Hydrothermal synthesis has afforded coordination polymers incorporating the kinked dipodal organodiimine 4,4¡ä- dipyridylamine (dpa) and the flexible aliphatic dicarboxylate suberate dianion, with a general formulation of [M(sub)(dpa)(H2O)]n (sub ) suberate, M ) Co, 1; M ) Ni, 2). Both 1 and 2 exhibit crystallographically disordered suberate ligands, producing a threedimensional ¡°ligand vacancy¡± R-Po coordination polymer network composed of two different types of [M(sub)(dpa)(H2O)]n idealized layers. |
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sltmac(½ð±Ò+3): ¹ÄÀøÐ³潻Á÷£¬»¶Ó³£À´±¾°æ~~ 2011-04-22 22:11:52
lingling0302(½ð±Ò+10, ·ÒëEPI+1): 2011-04-24 17:39:40
sltmac(½ð±Ò+3): ¹ÄÀøÐ³潻Á÷£¬»¶Ó³£À´±¾°æ~~ 2011-04-22 22:11:52
lingling0302(½ð±Ò+10, ·ÒëEPI+1): 2011-04-24 17:39:40
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