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大家帮我看看,自己不确定什么意思。
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第一次投稿,助编的意见,说修改后才送审,具体要修改啥,我也仔细看了,但不确定,求高手指点,尤其是做动力学的高手。我是搞催化的,这块不懂,什么术语的意思,麻烦解释下,抓重点说。谢谢了! Dear Dr. Zhu: Thank you for submitting your manuscript for publication in Energy & Fuels. I understand that you have explored a novel way of treating the side stream from the Fischer Tropsch process. However, before I can send the manuscript out for review, I must ask you to revise it to address two issues that I am certain will concern the reviewers. First, I must ask you to report the conversion data as reaction rates, normalized by the number of ostensible catalytic sites (i.e., turnover rates). Preferably, the kinetics results would be captured as rate equations in which the Arrhenius parameters (normalized pre-exponential factor, apparent activation energy) could be compare with those expected from the likely rate determining step and with those obtained in other laboratories. Hydrogen or CO titration are the usual ways of counting sites in catalysts where the active site is presumed to be a Pt group metal. Second, especially because you have studied a liquid phase reaction, I must ask you to present evidence that the reaction rates have not been influenced by the rates of transport. A Koros-Nowak or Madon-Boudart test would suffice. You will understand that I am striving to archive results that can be readily compared across laboratories and that bear on the underlying molecular phenomena. I am formally rejecting this manuscript to give you the opportunity to make those changes or, if you prefer, to submit it to a journal with a less picky editor. However, I hope you will continue to consider that Energy & Fuels can provide your work with an attentive audience. Therefore, when further experimentation, analysis, and revisions allow you to address the referees concerns in full we would be happy to consider a revised manuscript as a new submission. Please refer to the Manuscript ID above and include a detailed list of the changes you make when you submit the new manuscript so we can process it rapidly. With sincere regards, |
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Second, especially because you have studied a liquid phase reaction, I must ask you to present evidence that the reaction rates have not been influenced by the rates of transport. A Koros-Nowak or Madon-Boudart test would suffice. 2,特别是因为你已经研究了液相反应,我必须要求你提供证据证明反应速率没有收到传输速率的影响。做一个Koros-Nowak 或者Madon-Boudart测试就可以了。 |
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