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wangyi

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[交流] 【求助】循环伏安曲线滞后问题

最近投稿一篇论文,主编的审稿意见中有这样一句话:Fig. 3B clearly demonstrates the main problem of the subsequent kinetic data treatment: the reaction is surely irreversible, and hystereis is rather pronounced. This can result from some changes of the electrode surface state, like self-poisoning. Under these circumstances, the construction of Tafel plots from any voltammetry
(even at low scan rate) is senseless, Tafel plot makes sense only for steady-state proceses with coinciding direct and reverse courses.
我认为应该是说循环伏安曲线反应峰不明显,有滞后,是由于电机表面变化或中毒产生的,在这个条件中不能通过伏安法得到Tafel曲线,我想请问一下,这个问题该如何回答?
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