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rank citations author(s) title year, volume, pages 1 10638 Lineweaver, H.; Burk, D. The Determination of Enzyme Dissociation Constants 1934, 56, 658–666 2 7623 Dewar, M. J. S.; Zoebisch, E. G.; Healy, E. F.; Stewart, J. J. P. AM1: A New General Purpose Quantum Mechanical Molecular Model 1985, 107, 3902–3909 3 5373 Dewar, M. J. S.; Thiel, W. Ground States of Molecules. 38. The MNDO Method. Approximations and Parameters 1977, 99, 4899–4907 4 4808 Brunauer, S.; Emmett, P. H.; Teller, E. Adsorption of Gases in Multimolecular Layers 1938, 60, 309–319 5 4450 Merrifield, R. B. Solid Phase Peptide Synthesis. I. The Synthesis of a Tetrapeptide 1963, 85, 2149–2154 6 2920 Onsager, L. Electric Moments of Molecules in Liquids 1936, 58, 1486–1493 7 2799 Binkley, J. S.; Pople, J. A.; Hehre, W. J. Self-Consistent Molecular Orbital Methods. 21. Small Split-Valence Basis Sets for First-Row Elements 1980, 102, 939–947 8 2720 Allinger, N. L. Conformational Analysis. 130. MM2. A Hydrocarbon Force Field Utilizing V1 and V2 Torsional Terms 1977, 99, 8127–8134 9 2698 Sweeley, C. C.; Bentley, R.; Makita, M.; Wells, W. W. Gas–Liquid Chromatography of Trimethylsilyl Derivatives of Sugars and Related Substances 1963, 85, 2497–2507 10 2673 Weiner, S. J.; Kollman, P. A.; Case, D. A.; Singh, U. C.; Ghio, C.; Alagona, G.; Profeta, S., Jr.; Weiner, P. A New Force Field for Molecular Mechanical Simulation of Nucleic Acids and Proteins 1984, 106, 765–784 11 2648 Benesi, H. A.; Hildebrand, J. H. A Spectrophotometric Investigation of the Interaction of Iodine with Aromatic Hydrocarbons 1949, 71, 2703–2707 12 2645 Pedersen, C. J. Cyclic Polyethers and Their Complexes with Metal Salts 1967, 89, 7017–7036 13 2603 Pearson, R. G. Hard and Soft Acids and Bases 1963, 85, 3533–3539 14 2522 Williams, M. L.; Landel, R. F.; Ferry, J. D. The Temperature Dependence of Relaxation Mechanisms in Amorphous Polymers and Other Glass-forming Liquids 1955, 77, 3701–3707 15 2384 Hammond, G. S. A Correlation of Reaction Rates 1955, 77, 334–338 16 2362 Cremer, D.; Pople, J. A. General Definition of Ring Puckering Coordinates 1975, 97, 1354–1358 17 2171 Karplus, M. Vicinal Proton Coupling in Nuclear Magnetic Resonance 1963, 85, 2870–2871 18 2074 Bingham, R. C.; Dewar, M. J. S.; Lo, D. H. Ground States of Molecules. XXV. MINDO/3. Improved Version of the MINDO Semiempirical SCF-MO Method 1975, 97, 1285–1293 19 2045 Boyer, P. D. Spectrophotometric Study of the Reaction of Protein Sulfhydryl Groups with Organic Mercurials 1954, 76, 4331–4337 20 2022 Bax, A.; Summers, M. F. Proton and Carbon-13 Assignments from Sensitivity-Enhanced Detection of Heteronuclear Multiple-Bond Connectivity by 2D Multiple Quantum NMR 1986, 108, 2093–2094 21 1974 Mulliken, R. S. Molecular Compounds and their Spectra. II 1952, 74, 811–824 22 1961 Dewar, M. J. S.; Thiel, W. Ground States of Molecules. 39. MNDO Results for Molecules Containing Hydrogen, Carbon, Nitrogen, and Oxygen 1977, 99, 4907–4917 23 1824 Corey, E. J.; Venkateswarlu, A. Protection of Hydroxyl Groups as tert-Butyldimethylsilyl Derivatives 1972, 94, 6190–6191 24 1636 Cohn, E. J.; Strong, L. E.; Hughes, W. L., Jr.; Mulford, D. J.; Ashworth, J. N.; Melin, M.; Taylor, H. L. Preparation and Properties of Serum and Plasma Proteins. IV. A System for the Separation into Fractions of the Protein and Lipoprotein Components of Biological Tissues and Fluids 1946, 68, 459–475 25 1631 Peterson, E. A.; Sober, H. A. Chromatography of Proteins. I. Cellulose Ion-Exchange Adsorbents 1956, 78, 751–755 Date Available: March 2003 rank citations author(s) title year, volume, pages top 26 1588 Dale, J. A.; Mosher, H. S. Nuclear Magnetic Resonance Enantiomer Reagents. Configurational Correlations via Nuclear Magnetic Resonance Chemical Shifts of Diastereomeric d Mandelate, O-Methylmandelate, and -Methoxy--trifluoromethylphenylacetate (MTPA) Esters 1973, 95, 512–519 27 1469 Pople, J. A.; Gordon, M. Molecular Orbital Theory of the Electronic Structure of Organic Compounds. I. Substituent Effects and Dipole Moments 1967, 89, 4253–4261 28 1461 Hubbell, W. L.; McConnell, H. M. Molecular Motion in Spin-Labeled Phospholipids and Membranes 1971, 93, 314–326 29 1458 Borch, R. F.; Bernstein, M. D.; Durst, H. D. Cyanohydridoborate Anion as a Selective Reducing Agent 1971, 93, 2897–2904 30 1451 Altona, C.; Sundaralingam, M. Conformational Analysis of the Sugar Ring in Nucleosides and Nucleotides. New Description Using the Concept of Pseudorotation 1972, 94, 8205–8212 31 1431 Bothner-By, A. A.; Stephens, R. L.; Lee, J.; Warren, C. D.; Jeanloz, R. W. Structure Determination of a Tetrasaccharide: Transient Nuclear Overhauser Effects in the Rotating Frame 1984, 106, 811–813 32 1428 Wilson, G. M. Vapor–Liquid Equilibrium. XI. A New Expression for the Excess Free Energy of Mixing 1964, 86, 127–130 33 1415 Beck, J. S.; Vartuli, J. C.; Roth, W. J.; Leonowicz, M. E.; Kresge, C. T.; Schmitt, K. D.; Chu, C. T.-W.; Olson, D. H.; Sheppard, E. W.; McCullen, S. B.; Higgins, J. B.; Schlenker, J. L. A New Family of Mesoporous Molecular Sieves Prepared with Liquid Crystal Templates 1992, 114, 10834–10843 34 1369 Brown, H. C.; Okamoto, Y. Electrophilic Substituent Constants 1958, 80, 4979–4987 35 1367 Anderson, G. W.; Zimmerman, J. E.; Callahan, F. M. The Use of Esters of N-Hydroxysuccinimide in Peptide Synthesis 1964, 86, 1839–1842 36 1348 Sheehan, J. C.; Hess, G. P. A New Method of Forming Peptide Bonds 1955, 77, 1067–1068 37 1310 Hinze, J.; Jaffé, H. H. Electronegativity. I. Orbital Electronegativity of Neutral Atoms 1962, 84, 540–546 38 1304 Wani, M. C.; Taylor, H. L.; Wall, M. E.; Coggon, P.; McPhail, A. T. Plant Antitumor Agents. VI. Isolation and Structure of Taxol, a Novel Antileukemic and Antitumor Agent from Taxus brevifolia 1971, 93, 2325–2327 39 1299 Fujita, T.; Iwasa, J.; Hansch, C. A New Substituent Constant, , Derived from Partition Coefficients 1964, 86, 5175–5180 40 1294 Stork, G.; Brizzolara, A.; Landesman, H.; Szmuszkovicz, J.; Terrell, R. The Enamine Alkylation and Acylation of Carbonyl Compounds 1963, 85, 207–222 41 1294 Teo, B.-K.; Lee, P. A. Ab Initio Calculations of Amplitude and Phase Functions for Extended X-ray Absorption Fine Structure Spectroscopy 1979, 101, 2815–2832 42 1276 Langmuir, I. The Adsorption of Gases on Plane Surfaces of Glass, Mica and Platinum 1918, 40, 1361–1403 43 1274 Porter, M. D.; Bright, T. B.; Allara, D. L.; Chidsey, C. E. D. Spontaneously Organized Molecular Assemblies. 4. Structural Characterization of n-Alkyl Thiol Monolayers on Gold by Optical Ellipsometry, Infrared Spectroscopy, and Electrochemistry 1987, 109, 3559–3568 44 1261 Hansch, C.; Fujita, T. -- Analysis. A Method for the Correlation of Biological Activity and Chemical Structure 1964, 86, 1616–1626 45 1253 Kay, E. R. M.; Simmons, N. S.; Dounce, A. L. An Improved Preparation of Sodium Desoxyribonucleate 1952, 74, 1724–1726 Date Available: May 2003 rank citations author(s) title year, volume, pages top 46 1251 Fuoss, R. M. Ionic Association. III. The Equilibrium between Ion Pairs and Free Ions 1958, 80, 5059–5061 47 1249 Kosower, E. M. The Effect of Solvent on Spectra. I. A New Empirical Measure of Solvent Polarity: Z-Values 1958, 80, 3253–3260 48 1223 Ammeter, J. H.; Buergi, H.-B.; Thibeault, J. C.; Hoffman, R. Counterintuitive Orbital Mixing in Semiempirical and ab Initio Molecular Orbital Calculations 1978, 100, 3686–3692 49 1222 Piantini, U.; Sorensen, O. W.; Ernst, R. R. Multiple Quantum Filters for Elucidating NMR Coupling Networks 1982, 104, 6800–6801 50 1216 Bain, C. D.; Troughton, E. B.; Tao, Y.-T.; Evall, J.; Whitesides, G. M.; Nuzzo, R. G. Formation of Monolayer Films by the Spontaneous Assembly of Organic Thiols from Solution onto Gold 1989, 111, 321–335 51 1203 Corey, E. J.; Chaykovsky, M. Dimethyloxosulfonium Methylide ((CH3)2SOCH2) and Dimethylsulfonium Methylide ((CH3)2SCH2). Formation and Application to Organic Synthesis 1965, 87, 1353–1364 52 1176 Mayo, F. R.; Lewis, F. M. Copolymerization. I. A Basis for Comparing the Behavior of Monomers in Copolymerization; The Copolymerization of Styrene and Methyl Methacrylate 1941, 66, 1594–1601 53 1138 Barrett, E. P.; Joyner, L. G.; Halenda, P. P. The Determination of Pore Volume and Area Distributions in Porous Substances. I. Computations from Nitrogen Isotherms 1951, 73, 373–380 54 1128 Katsuki, T.; Sharpless, K. B. The First Practical Method for Asymmetric Epoxidation 1980, 102, 5974–5976 55 1112 Vosburgh, W. C.; Cooper, G. R. Complex Ions. I. The Identification of Complex Ions in Solution by Spectrophotometric Measurements 1941, 63, 437–442 56 1101 Morris, G. A.; Freeman, R. Enhancement of Nuclear Magnetic Resonance Signals by Polarization Transfer 1979, 101, 760–762 57 1099 Huggins, M. L. The Viscosity of Dilute Solutions of Long-Chain Molecules. IV. Dependence on Concentration 1942, 64, 2716–2718 58 1093 Cotton, F. A.; Kraihanzel, C. S. Vibrational Spectra and Bonding in Metal Carbonyls. I. Infrared Spectra of Phosphine-substituted Group VI Carbonyls in the CO Stretching Region 1962, 84, 4432–4438 59 1086 Simon, E. J.; Shemin, D. The Preparation of S-Succinyl Coenzyme A 1953, 75, 2520–2520 60 1080 Taylor, R.; Kennard, O. Crystallographic Evidence for the Existence of C–HO, C–HN, and C–HCl Hydrogen Bonds 1982, 104, 5063–5070 61 1075 Lauher, J. W.; Hoffmann, R. Structure and Chemistry of Bis(cyclopentadienyl)–MLn Complexes 1976, 98, 1729–1742 62 1073 Gao, Y.; Hanson, R. M.; Klunder, J. M.; Ko, S. Y.; Masamune, H.; Sharpless, K. B. Catalytic Asymmetric Epoxidation and Kinetic Resolution: Modified Procedures Including in situ Derivatization 1987, 109, 5765–5780 63 1071 Swain, C. G.; Lupton, E. C., Jr. Field and Resonance Components of Substituent Effects 1968, 90, 4328–4337 64 1069 Pulay, P.; Fogarasi, G.; Pang, F.; Boggs, J. E. Systematic ab Initio Gradient Calculation of Molecular Geometries, Force Constants, and Dipole Moment Derivatives 1979, 101, 2550–2560 65 1067 Kielland, J. Individual Activity Coefficients of Ions in Aqueous Solutions 1937, 59, 1675–1678 Date Available: July 2003 rank citations author(s) title year, volume, pages top 66 1063 Budzikiewicz, H.; Wilson, J. M.; Djerassi, C. Mass Spectrometry in Structural and Stereochemical Problems. XXXII. Pentacyclic Triterpenes 1963, 85, 3688–3699 67 1056 Flory, P. J. Statistical Thermodynamics of Liquid Mixtures 1965, 87, 1833–1838 68 1054 Allinger, N. L.; Yuh, Y. H.; Lii, J.-H. Molecular Mechanics. The MM3 Force Field for Hydrocarbons. 1 1989, 111, 8551–8566 69 1048 Gordon, M. S.; Binkley, J. S.; Pople, J. A.; Pietro, W. J.; Hehre, W. J. Self-Consistent Molecular-Orbital Methods. 22. Small Split-Valence Basis Sets for Second-Row Elements 1982, 104, 2797–2803 70 1013 Blodgett, K. B. Films Built by Depositing Successive Monomolecular Layers on a Solid Surface 1935, 57, 1007–1022 71 1012 Lipari, G.; Szabo, A. Model-Free Approach to the Interpretation of Nuclear Magnetic Resonance Relaxation in Macromolecules. 1. Theory and Range of Validity 1982, 104, 4546–4559 72 1002 Klopman, G. Chemical Reactivity and the Concept of Charge- and Frontier-Controlled Reactions 1968, 90, 223–234 73 1002 Metcalf, B. W.; Bey, P.; Danzin, C.; Jung, M. J.; Casara, P.; Vevert, J. P. Catalytic Irreversible Inhibition of Mammalian Ornithine Decarboxylase (E.C. 4.1.1.17) by Substrate and Product Analogs 1978, 100, 2551–2553 74 998 Hughes, E. W. The Crystal Structure of Melamine 1941, 63, 1737–1752 75 993 Brunauer, S.; Deming, L. S.; Deming, W. E.; Teller, E. On a Theory of the van der Waals Adsorption of Gases 1940, 62, 1723–1732 76 988 Zachariasen, W. H. The Atomic Arrangement in Glass 1932, 54, 3841–3851 77 969 Melby, L. R.; Harder, R. J.; Hertler, W. R.; Mahler, W.; Benson, R. E.; Mochel, W. E. Substituted Quinodimethans. II. Anion-radical Derivatives and Complexes of 7,7,8,8-Tetracyanoquinodimethan 1962, 84, 3374–3387 78 961 Tauster, S. J.; Fung, S. C.; Garten, R. L. Strong Metal-Support Interactions. Group 8 Noble Metals Supported on Titanium Dioxide 1978, 100, 170–175 79 950 Pauling, L. Atomic Radii and Interatomic Distances in Metals 1947, 69, 542–553 80 950 Chen, C.-S.; Fujimoto, Y.; Girdaukas, G.; Sih, C. J. Quantitative Analyses of Biochemical Kinetic Resolutions of Enantiomers 1982, 104, 7294–7299 |
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81 945 Kalyanasundaram, K.; Thomas, J. K. Environmental Effects on Vibronic Band Intensities in Pyrene Monomer Fluorescence and Their Application in Studies of Micellar Systems 1977, 99, 2039–2044 82 941 Åkerlöf, G. Dielectric Constants of Some Organic Solvent–Water Mixtures at Various Temperatures 1932, 54, 4125–4139 83 941 Halverstadt, I. F.; Kumler, W. D. Solvent Polarization Error and its Elimination in Calculating Dipole Moments 1942, 64, 2988–2992 84 929 Grunwald, E.; Winstein, S. The Correlation of Solvolysis Rates 1948, 70, 846–854 85 923 Cornell, W. D.; Cieplak, P.; Bayly, C. I.; Gould, I. R.; Merz, K. M., Jr.; Ferguson, D. M.; Spellmeyer, D. C.; Fox, T.; Caldwell, J. W.; Kollman, P. A. A Second Generation Force Field for the Simulation of Proteins, Nucleic Acids, and Organic Molecules 1995, 117, 5179–5197 Date Available: September 2003 rank citations author(s) title year, volume, pages top 86 910 Bodanszky, M.; du Vigneaud, V. 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