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1.As the TGA curves almost overlap each other, they have not been given here. ÏëÒª±í´ïµÄÒâ˼ÊÇ£ºÓÉÓÚTGAÇúÏß²î±ðºÜС£¬¼¸ºõÖØµþÔÚÒ»Æð£¬ÎÄÕÂÖÐÎÒÃÇûÓиø³öTGAÇúÏß¡£ 2. owing to the less stability of tertiary carbon atoms presented in PT ÏëÒª±í´ïµÄÒâ˼ÊÇ£ºÕâÊÇÒòΪPT·Ö×ÓÖдæÔڵļ¾Ì¼Ô×ÓµÄÎȶ¨ÐԽϲî 3. Thus, it can be undoubtedly concluded that the copolymers have satisfactory thermal stability, which is appropriate to application. ÏëÒª±í´ïµÄÒâ˼ÊÇ£ºÒò´Ë£¬¿ÉÒԵóö½áÂÛ£¬¹²¾ÛÎï¾ßÓÐÁîÈËÂúÒâµÄÈÈÎȶ¨ÐÔ£¬Ó¦Óò»´æÔÚÈÈÎȶ¨ÐÔÎÊÌâ¡£ 4.ÔÙ¾ÍÊÇÇëÎÊTgºÍTmÇ°Ãæ¿ÉÒÔ¼Ó²»¶¨¹Ú´ÊaÂ𣿠5.Te of PT5 is higher than room temperature and the values of t1/2 for PT5 are 0.52 and 0.39 min at cooling rates of 20 and 40 oC min-1, respectively, which may be suitable for common processing such as injection moulding, membrane blowing and melt spinning. ÏëÒª±í´ïµÄÒâ˼ÊÇ£ºPT5µÄ½á¾§ÖÕֹζȸßÓÚÊÒΣ¬½µÎÂËÙÂÊΪ20 ºÍ 40 oC min-1ʱ,Æät1/2Öµ·Ö±ðΪ0.52ºÍ0.39·ÖÖÓ¡£ÕâÑùµÄ½á¾§ËÙ¶ÈÊʺÏÓÚͨ³£µÄ¼Ó¹¤Èç×¢Éä³ÉÐÍ£¬´µÄ¤ºÍÈÛÈÚ·ÄË¿¡£ 6. The surface of PT30 is not full of crystals, which may be due to the low crystallization rate and inadequate crystallization during the process of nonisothermal crystallization. Owing to the same reason, exothermic peak can be detected during the process of nonisothermal crystallization. ÏëÒª±í´ïµÄÒâ˼ÊÇ£ºPT30µÄ±íÃæÃ»Óг¤ÂúÇò¾§£¬ÕâÊÇÓÉÓÚÆä½á¾§ËٶȺÜÂý£¬ÔڷǵÈνᾧ¹ý³ÌÖнᾧ²»ÍêÈ«Ëùµ¼Ö¡£ÓÉÓÚͬÑùµÄÔÒò£¬ÔڷǵÈνᾧ¹ý³ÌδÄÜ̽²âµ½·ÅÈÈ·å¡£ 7. This seeming anomalous trend can be rationalized by the fact that ÏëÒª±í´ïµÄÒâ˼ÊÇ£ºÕâÖÖ¿´ËÆ·´³£µÄÏÖÏó¿ÉÒÔͨ¹ý¡£¡£¡£¡£À´½âÊÍ¡£ 8. This substantial improvement in tensile strength can be attributed to the rigidity of aromatic PT segment as compared to that of aliphatic PS. ÏëÒª±í´ïµÄÒâ˼ÊÇ£ºÀÉìÇ¿¶ÈÏÔÖøµÄÌá¸ßµÄÔÒòÊÇÓëÖ¬·¾×åµÄPSÁ´¶ÎÏà±È£¬PTÁ´¶Î¾ßÓнÏÇ¿µÄ¸ÕÐÔ¡£ |
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