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zhangwengui330(金币+4):谢谢详细解说！！ 2010-05-20 14:35:10
A mesoporous material is a material containing pores with diameters between 2 and 50 nm.
Porous materials are classified into several kinds by their size. According to IUPAC notation (see J. Rouquerol et al., Pure & Appl. Chem, 66 (1994) 1739-1758), microporous materials have pore diameters of less than 2 nm and macroporous materials have pore diameters of greater than 50 nm; the mesoporous category thus lies in the middle.have similarly-sized fine mesopores. Mesoporous oxides of niobium, tantalum, titanium, zirconium, cerium and tin have also been reported. According to the IUPAC notation, a mesoporous material can be disordered or ordered in a mesostructure.
The first mesoporous material, with a long range order, was synthesized in the late 80s/ early 90s, by a research group of the former Mobil Oil Company (see Kresge et al., Nature 359 (1992) 710). Since then, research in this field has steadily grown. Notable examples of prospective applications are catalysis, sorption, gas sensing, optics, and photovoltaics.
1.介孔材料的诞生－－1992年MS41系列分子筛(典型的是MCM-41,MCM-48,MCM-50)的合成（严格来讲，应该是1991年日本人合成出来）：
Nature. 1992, 359, 710-712（J. S. Beck）1y O) J Am Chem Soc. 1992, 114: 10834-10843（J. S. Beck）
Science. 1993, 261: 1299-1303(霍启升）
2. 介孔材料制备的另一里程碑－－1998年赵东元合成了SBA-15
Science. 1998, 279: 548-552（赵东元）
J. Am. Chem. Soc. 1998, 120, 6024-6036 （赵东元）
3.通过硬模板法合成炭基介孔材料，也是一大重要成绩－－1999年由韩国人刘龙完成：
J Am Chem Soc. 2002, 124: 1156-1157( Ryoo R.)
介孔相关的几个牛人的课题组：
http://www.mrl.ucsb.edu/mrl/info/publications/ （G. D. Stucky
http://www.cem.msu.edu/~pinnweb/ （Thomas J. Pinnavaia）
http://www.chem.toronto.edu/staff/GAO/flashed/menu.htm （Ozin's group）
http://homepage.fudan.edu.cn/~dyzhao/ （赵东元） http://rryoo.kaist.ac.kr/pub.html (韩国刘龙 （R. Ryoo）)
http://cheed.nus.edu.sg/~chezxs/Zhao/publication.htm（新加坡赵修松 Xiusong Zhao)
http://www.ucm.es/info/inorg/inv ... iones/2001/2001.htm (西班牙M. Vallet-Regi 首先把介孔材料应用到药物缓释）
还有几个课题组现在没有了链接，但是其课题负责人还是记得： 台湾的牟中原和他的弟子林弘平；上海硅所的施剑林；吉林大学的肖丰收和裘式伦；大化所的包信和（涉及得不多）
推荐几篇介孔材料重要的综述：
Chem. Mater. 1996, 8, 1147-1160 Surfactant Control of Phases in the Synthesis of Mesoporous Silica-Based Materials(Stucky和霍启升 表面活性剂的堆积参数和结构的关系）
Chem. Rev. 1997, 97, 2373-2419 From Microporous to Mesoporous Molecular Sieve Materials and Their Use in Catalysis（主要介绍介孔作催化载体的应用）
Chem. Rev. 2006, 106, 3790-3812 Advances in the Synthesis and Catalytic Applications of Organosulfonic-Functionalized Mesostructured Materials（有机官能化介孔的合成及在催化中的应用）
Acc. Chem. Res. 2002, 35, 927-935 Structural and Morphological Control of Cationic Surfactant-Templated Mesoporous Silica（牟中原 具体谈论介孔形貌的形成）
Angew. Chem. Int. Ed. 2006, 45, 3216–3251 Silica-Based Mesoporous Organic-Inorganic Hybrid Materials（Frank Hoffmann 所著，非常好）
Acc.Chem.Res.2005, 38,305-312 Past, Present, and Future of Periodic Mesoporous Organosilicas-The PMOs（O'zin 重点介绍周期性介孔）
NATURE 2002 417 813 Ordered porous materials for emergeing application
（大牛Davis所著）Chem. Mater. 1999, 11, 2633-2656 Tailored Porous Materials(Thomas J.)
介孔分子筛的应用
介孔分子筛吸附氨基酸：
Carbon 44 (2006) 530–536 Adsorption of L-histidine over mesoporous carbon molecular sieves(印度人 A. Vinu）
Separation and Purification Technology 48 (2006) 197–201 Amino acid adsorption onto mesoporous silica molecular sieves （首篇）
介孔分子筛吸附蛋白质（酶）
Journal of Molecular Catalysis B－ Enzymatic 2（1996） 115－ 126 Enzyme immobilization in MCM-4 1 molecular sieve（首篇）
J. Am. Chem. Soc. 1999, 121, 9897-9898 Mesoporous Silicate Sequestration and Release of Proteins（stucky)
J. AM. CHEM. SOC. 2004, 126, 12224-12225 Protein Encapsulation in Mesoporous Silicate-The Effects of Confinement on Protein Stability, Hydration, and Volumetric Properties
J. Phys. Chem. B 2003, 107, 8297-8299 Adsorption of Cytochrome C on New Mesoporous Carbon Molecular Sieves(Vinu, A)
介孔分子筛负载催化剂
J. Phys. Chem. B 2006, 110, 15212-15217 Fabrication and characterization of mesoporous Co3O4 core-mesoporous silica shell nanocomposites（典型的core－shell结构）
CHEM. COMMUN., 2003, 1522–1523 Ultra-thin porous silica coated silver–platinum alloy nano-particle as a new catalyst precursor)
Applied Catalysis A General 308 (2006) 19–30 Carbon oxide hydrogenation over silica-supported iron-based catalysts Influence of the preparation route%m;
Chem. Commun., 2005, 348–350 Metallic Ni nanoparticles confined in hexagonally ordered mesoporous silica material)
介孔分子筛在药物可控释放方面的应用
Chem. Mater. 2001, 13, 308-311 A New Property of MCM-41, Drug Delivery System（Vallet-Regi 首篇）
Nature 2003, 421, 350 – 353 Photocontrolled reversible release of guest molecules from coumarinmodified modified mesoporous silica（第一次只能化）
J. AM. CHEM. SOC. 2005, 127, 8916-8917 Fabrication of Uniform Magnetic Nanocomposite Spheres with a Magnetic Core-Mesoporous Silica Shell Structure-support（施剑林 所谓的“药物分子运输车”）
Angew. Chem. Int. Ed. 2005, 44, 5038 –5044 Stimuli-Responsive Controlled-Release Delivery System Based on Mesoporous Silica Nanorods Capped with Magnetic Nanoparticles（Victor S.-Y. Lin* 在智能介孔药物释放方面是贡献巨大）介孔分子筛吸附废水阳离子
Chemosphere 59 (2005) 779–786 Heavy metals removal from electroplating wastewater by aminopropyl-Si
Environ. Sci. Technol.2000, 34,4822-4827 Surfactant-Templated Mesoporous Silicate Materials as Sorbents for Organic Pollutants in Water
Ind. Eng. Chem. Res. 2004, 43, 1478-1484 Highly Selective Adsorption of Pt2+ and Pd2+ Using Thiol-Functionalized Mesoporous Silica
介孔分子筛在色谱中的应用
Chem. Commun., 2002, 752 - 753 Biomolecule separation using large pore mesoporous SBA-15 as a substrate in high performance liquid chromatography
Electrophoresis 2006,27,742–748 Large-pore mesoporous SBA-15 silica particles with submicrometer size as stationary phases for high-speed CEC seperation
介孔分子筛作为硬模板
Adv. Mater. 2001, 13, 677-681 Ordered Mesoporous Carbons（Ryong Ryoo）
Microporous and Mesoporous Materials 63 (2003) 1–9 Synthesis and characterization of spherical carbon and polymer capsules with hollow macroporous core and mesoporous shell structures
介孔分子筛复合材料（实现光学性能，比如掺入二氧化钛，量子点）
J. Phys. Chem. B 2005, 109, 12309-12315 Synthesis and Characterization of Nano titania Particles Embedded in Mesoporous Silica with Both High Photocatalytic Activity and Adsorption Capability
Chem. Mater. 2005, 17, 1269-1271 Preparation of Mesoporous Titania Thin Films with Remarkably High Thermal Stability
J. AM. CHEM. SOC. 2006, 128, 688-689 Magnetic Fluorescent Delivery Vehicle Using Uniform Mesoporous Silica Spheres Embedded with Monodisperse Magnetic and Semiconductor Nanocrystals
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