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luozhonghua金虫 (小有名气)
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[求助]
荧光方面的 审稿意见
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In figure 4, PL spectra show a main band accompanied by a shoulder for bisbenzimidazoles 4b and 4h, which also exhibit the lowest fluorescence quantum yield. Authors pointed out the role of bromine atom favoring intersystem crossing.\ Reviewer also thinks that this study also reveals that torsional relaxation (due to the bromine substituents) to twisted state competes with radiative transitions and leads to fluorescence quenching. Reference that could be included or other. |
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liuxinlin-yj
金虫 (正式写手)
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【答案】应助回帖
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In figure 4, PL spectra show a main band accompanied by a shoulder for bisbenzimidazoles 4b and 4h, which also exhibit the lowest fluorescence quantum yield. Authors pointed out the role of bromine atom favoring intersystem crossing. 在图4中，PL光谱表明 双苯并咪唑基)烷烃给出一个伴有肩峰的主峰（不了解你的专业4b和4h不知道是是什么意思好像是谱带），4b and 4h也显示出低的量子收率。作者指出硼原子有助于系间跨越。 intersystem crossing ：系统间过渡，在生物物理学译成“系间跨越” Reviewer also thinks that this study also reveals that torsional relaxation (due to the bromine substituents) to twisted state competes with radiative transitions and leads to fluorescence quenching. Reference that could be included or other. 审稿人认为这一研究也揭示了由于硼取代基的存在，扭曲态的扭力松弛与辐射跃迁存在竞争，导致荧光熄灭。应该采用参照物，或其他方法。 Reference，有很多意思，不知道你的具体内容，参照标准或校正是否正确。 |
2楼2010-04-02 14:39:34