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GrasaVampiro

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[交流] 【讨论】How does relativistic effect of electron's mass effect Ab-initio calcu?

How does relativistic effect of electron's mass  effect Ab-initio calcu?
We know that the Ab-initio calculation is just based on fundamental QM postulates and several matter constants, include the mass of electron. For some elements, like gold, the mass the inner shell electron can not be considered as constant because of relativistic effect. How this effect the calculation and what is practical solution for this?
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erylingjet(金币+1): 2010-02-08 10:00
请GV斑斑去看看sdd基组和LanL2DZ基组,这是两个著名的赝势基组
赝势基组就是为了解决这个问题而存在的
2楼2010-01-27 21:50:08
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