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zyp2886

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[交流] 重金求助！十万火急!!!

1.
题目：Biphenyl from benzene
作者：R.G.Ismailov, D.A.Aliev and T.M.Ivanova.
CA信息：CA 60,26h,5253h

2.
题目：Investigation of the thermal condensation of petroleum-derived benzene for the production of biphenyl
作者：R.G.Ismailov, D.A.Aliev, and T.M.Ivanova.

都是1963年的，告诉我CA摘要页可以，或者是知道发表的杂志名字

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zyp2886(金币+2,VIP+0): 12-18 15:01

Preparation of  biphenyl  from the crude  benzene  fraction of pyrolysis products. II.    Ismailov, R. G.; Aliev, D. A.; Ivanova, T. M. Azarbaycan Neft Tasarrufati  (1963),  42(5),  33-5.  CODEN: AZNKAY  ISSN: 0365-8554.  Journal  written in Russian. CAN 64:26521 AN 1966:26521 CAPLUS

Abstract

cf. CA 60, 5253h.  The possibility of the use of the crude benzene fraction for the prepn. of Ph2 and pure C6H6 was investigated.  The thermal condensation of this fraction at 850 yields 5.8-9.3% gas, 4.3-9.1% coke, and 79.1-82.8% tar.  The components of the gas are H 58.8-76.4, CH4 17.4-30.8, C2H6 1.6-2.9, and C2H4 4.1-7.8%.  Steam distn. of the tar fraction yields 53.8-57.3% C6H6 and 12.2-16.1% Ph2.  The process comprises pyrolysis and cyclization of the olefins, partial decompn. of C6H6, and condensation of C6H6 to Ph2.  The Ph2 obtained by recrystn. has a purity of 98.8-9.0% and a m.p. of 66.6-8.8.  A high-quality, pure C6H6 contg. 98.8-9% aromatic compds. can also be obtained by this process without H2SO4 purification.

Indexing -- Section 27  (Petroleum and Petroleum Derivatives)

Hydrocarbon oils
(manuf. of benzene and biphenyl from benzene fraction of pyrolysis product of)

90607-03-7
(Derived from data in the 7th Collective Formula Index (1962-1966)

92-52-4P, Biphenyl
Role: PREP (Preparation)
(manuf. of, by benzene pyrolysis)