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zyp2886金虫 (小有名气)
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1. 题目：Biphenyl from benzene 作者：R.G.Ismailov, D.A.Aliev and T.M.Ivanova. CA信息：CA 60,26h,5253h 2. 题目：Investigation of the thermal condensation of petroleum-derived benzene for the production of biphenyl 作者：R.G.Ismailov, D.A.Aliev, and T.M.Ivanova. 都是1963年的，告诉我CA摘要页可以，或者是知道发表的杂志名字 |
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至尊木虫 (文坛精英)
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2楼2009-12-18 11:07:33
caozhichao0
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3楼2009-12-18 11:40:08
wizardd
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4楼2009-12-18 11:58:44
zq20051215
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zyp2886(金币+2,VIP+0): 12-18 15:01
zyp2886(金币+2,VIP+0): 12-18 15:01
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Preparation of biphenyl from the crude benzene fraction of pyrolysis products. II. Ismailov, R. G.; Aliev, D. A.; Ivanova, T. M. Azarbaycan Neft Tasarrufati (1963), 42(5), 33-5. CODEN: AZNKAY ISSN: 0365-8554. Journal written in Russian. CAN 64:26521 AN 1966:26521 CAPLUS Abstract cf. CA 60, 5253h. The possibility of the use of the crude benzene fraction for the prepn. of Ph2 and pure C6H6 was investigated. The thermal condensation of this fraction at 850 yields 5.8-9.3% gas, 4.3-9.1% coke, and 79.1-82.8% tar. The components of the gas are H 58.8-76.4, CH4 17.4-30.8, C2H6 1.6-2.9, and C2H4 4.1-7.8%. Steam distn. of the tar fraction yields 53.8-57.3% C6H6 and 12.2-16.1% Ph2. The process comprises pyrolysis and cyclization of the olefins, partial decompn. of C6H6, and condensation of C6H6 to Ph2. The Ph2 obtained by recrystn. has a purity of 98.8-9.0% and a m.p. of 66.6-8.8. A high-quality, pure C6H6 contg. 98.8-9% aromatic compds. can also be obtained by this process without H2SO4 purification. Indexing -- Section 27 (Petroleum and Petroleum Derivatives) Hydrocarbon oils (manuf. of benzene and biphenyl from benzene fraction of pyrolysis product of) 90607-03-7 (Derived from data in the 7th Collective Formula Index (1962-1966) 92-52-4P, Biphenyl Role: PREP (Preparation) (manuf. of, by benzene pyrolysis) |
5楼2009-12-18 13:43:50
zq20051215
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6楼2009-12-18 13:47:09
zq20051215
木虫 (正式写手)
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zyp2886(金币+20,VIP+0): 12-18 15:01
zyp2886(金币+39): 2010-03-25 20:20
zyp2886(金币+20,VIP+0): 12-18 15:01
zyp2886(金币+39): 2010-03-25 20:20
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第二篇：Bibliographic Information Investigation of the thermal condensation of petroleum-derived benzene for the production of biphenyl. Ismailov, R. G.; Aliev, D. A.; Ivanova, T. M. Azarbaycan Neft Tasarrufati (1963), 42(4), 35-7. CODEN: AZNKAY ISSN: 0365-8554. Journal language unavailable. CAN 60:30034 AN 1964:30034 CAPLUS Abstract A study was made of the prepn. of biphenyl (I) (used as a heat-transfer agent and in the manuf. of elec. insulating fluids) by thermal condensation of petroleum-derived C6H6. Pure C6H6 from the light oil fraction obtained by pyrolysis of liquid petroleum distillates was used as raw material, and the reaction was studied in a lab. app. consisting of a Cr-Ni reaction tube heated in an elec. furnace, condensers for liquid products, and a flask for measuring the vol. of gaseous products. Liquid products were sepd. by steam-distn. into a C6H6 fraction and a I fraction. I was purified by recrystn. from EtOH. The reaction was investigated at temps. ranging from 600 to 850. No condensation occurred at temps. of 600-700, and only small amts. of I and gaseous products were formed at 750. At 800-50, condensation of C6H6 gave 88.4-91.5% resinous products, and 2.5-4.0% gaseous products, and 3.3-4.6% coke. Gaseous products consisted of 89.3-90.6% H and 9.4-10.7% CH4. The yield of I increased with temp. from 8.7 to 18.6%. Decreasing the contact time to 0.33 sec. at 850 increased the yield of I to 19.6%. Indexing -- Section 27 (Petroleum and Petroleum Derivatives) Condensation, chemical (of benzene, to biphenyl) 71-43-2, Benzene (condensation of, to biphenyl) 92-52-4P, Biphenyl Role: PREP (Preparation) (manuf. of, by benzene condensation) |
7楼2009-12-18 13:52:10
zq20051215
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8楼2009-12-18 13:53:03
zq20051215
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9楼2009-12-18 13:54:03
zyp2886
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10楼2009-12-18 15:03:00