| 查看: 405 | 回复: 0 | ||
| 【悬赏金币】回答本帖问题，作者jcj312将赠送您 5 个金币 | ||
jcj312金虫 (小有名气)
|
[求助]
提高阳极氯化的法拉第效率
|
|
|
Anodic electrochemical reactions in aqueous solutions often suffer from low Faradaic efficiency (FE) due to the competing oxygen evolution reaction (OER). To address this issue, the modification of carbon paper (CP) electrode is coupled with a membranefree biphasic electrochemical device. Scanning electron microscopy (SEM) and water contact angle measurements confirmed the hydrophobic properties of the modified CPs. The in situ infrared (IR) spectroscopy and molecular dynamics (MD) simulation demonstrated that the hydrophobic surface repels water at the electrode interface,significantly reducing its local concentration. The biphasic electrochemical device is promoted by surfactants. Transmission electron microscope (TEM) and dynamic light scattering (DLS) confirmed the formation of reverse micelles in the organic layer, which encapsulates water-soluble reactants to enhance mass transfer. Through pulsed square-wave potentials, this combined strategy increased the FE by 2.4 times or the formation of chlorobenzene. https://aiche.onlinelibrary.wiley.com/doi/abs/10.1002/aic.18880 |
回复此楼» 猜你喜欢
核磁分析软件MestReNova打开文件时报错
已经有0人回复
-
在职博后不能申请博后基金了，那么在职博后意义何在？
已经有2人回复
-
物理化学论文润色/翻译怎么收费?
已经有65人回复
-
青岛大学化学化工学院分子测量学研究院2026年招收博士研究生
已经有0人回复
-
香港科技大学（广州）诚招电催化方向博士生（2026秋入学）
已经有0人回复
-
求助Cu2+1O的CIF文件(PDF: 05-0667)
已经有1人回复
-
KAUST（阿卜杜拉国王科技大学）MXene 器件方向博士后招聘
已经有0人回复
-
沙特阿拉伯阿卜杜拉国王科技大学（KAUST）电池方向博士后招聘
已经有0人回复
-
福州大学新能源材料与工程研究院招收2026年入学博士
已经有0人回复