| 查看: 489 | 回复: 0 | ||
| 【悬赏金币】回答本帖问题，作者jcj312将赠送您 5 个金币 | ||
jcj312金虫 (小有名气)
|
[求助]
提高阳极氯化的法拉第效率
|
|
|
Anodic electrochemical reactions in aqueous solutions often suffer from low Faradaic efficiency (FE) due to the competing oxygen evolution reaction (OER). To address this issue, the modification of carbon paper (CP) electrode is coupled with a membranefree biphasic electrochemical device. Scanning electron microscopy (SEM) and water contact angle measurements confirmed the hydrophobic properties of the modified CPs. The in situ infrared (IR) spectroscopy and molecular dynamics (MD) simulation demonstrated that the hydrophobic surface repels water at the electrode interface,significantly reducing its local concentration. The biphasic electrochemical device is promoted by surfactants. Transmission electron microscope (TEM) and dynamic light scattering (DLS) confirmed the formation of reverse micelles in the organic layer, which encapsulates water-soluble reactants to enhance mass transfer. Through pulsed square-wave potentials, this combined strategy increased the FE by 2.4 times or the formation of chlorobenzene. https://aiche.onlinelibrary.wiley.com/doi/abs/10.1002/aic.18880 |
回复此楼» 猜你喜欢
0703调剂
已经有4人回复
-
1
已经有21人回复
-
物理化学论文润色/翻译怎么收费?
已经有254人回复
-
0703 调剂
已经有6人回复
-
招收
已经有0人回复
-
西南某211招27届博士
已经有32人回复
-
大连工业杰青/长江团队-生物质材料-储能电池方向招收2026级博士生
已经有0人回复
-
求调剂一志愿海大，0703化学学硕304分，有大创项目，四级已过
已经有10人回复
-
070300 求调剂
已经有1人回复
-
深圳大学高等研究院赵伟课题组招收化学调剂生
已经有2人回复
