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【求助】zsm-11和si-2是一种东西嘛
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 请问 si-2分子筛和zsm-11分子筛是一种分子筛吗？我初次接触分子筛这一块，好晕哦 请高人给点指点 小女子这厢谢过了！ |
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3楼2009-10-29 21:31:44
dj_king
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2楼2009-10-29 21:21:17
dj_king
铁杆木虫 (著名写手)
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小木虫(金币+0.5):给个红包，谢谢回帖交流
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查一下它的引用文献： Nature 280, 664 - 665 (23 August 1979); doi:10.1038/280664a0 Silicalite-2, a silica analogue of the aluminosilicate zeolite ZSM-11 D. M. BIBBY, N. B. MILESTONE & L. P. ALDRIDGE Chemistry Division, DSIR, Private Bag, Petone, New Zealand THE structure of silicalite, a new polymorph of silica which was first prepared by Flanigen et al. 1, is so similar to that of the silica-rich aluminosilicate zeolite ZSM-5 (ref. 2) that we suggest that it should be regarded as the aluminium-free end member of this zeolite series. Therefore it should be possible to prepare silica analogues of other silica-rich aluminosilicate zeolites such as ZSM-11 (ref. 3), ZSM-12 (ref. 4), ZSM-21 (ref. 5) and ZSM-34 (ref. 6). We report here the preparation of what we believe is the analogue of ZSM-11, which we call silicalite-2, adopting the terminology silicalite-1 for the form prepared by Flanigen et al. 1 The silicalite-1, ZSM-5, ZSM-11 and, by inference, silicalite-2 frameworks contain 4-, 5- and 6-membered rings linked to form a system of channels with 10-membered ring openings1−3. In silicalite-1 and ZSM-5 the channels are a combination of linear and zig-zag1,2, while in ZSM-113 and silicalite-2 all the channels are linear. The lack of substitutional aluminium results in silicalites having no significant catalytic or cation exchange properties compared with the zeolites. However, silicalites are unusual in that they are the only known hydrophobic forms of silica and are capable of absorbing organic molecules up to 6 Å kinetic diameter. Thermogravimetric studies of silicalites-1 and -2 containing absorbed long straight-chain hydrocarbon compounds (C4−C16) show that degassing occurs in two stages, which we consider to be due to self-blocking of the channels at intersection points. |
4楼2009-10-29 21:41:37
