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liuth

木虫 (正式写手)

[交流] 硅氢表面的稳定性

我最近在做单晶硅表面的化学单层自组装,其中需要用HF或者NH4F处理单晶硅表面成Si-H,即H-terminated silicon。
    我的问题是:Si-H表面在空气中的稳定性,即可以保留多长时间!我在用氮气吹干的过程中因为处理时间的问题会不会被氧化!
    应该怎么处理操作最好!最好附上参考文献,或者网址!
    不胜感激!
寡聚噻吩,传感,Two-photon,SquaraineDye,Porphyrin
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Skyandsun

金虫 (小有名气)

★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★
liuth(金币+14,VIP+0):谢谢!辛苦了! 10-21 09:33
sparrow1290(金币+0,VIP+0):请在三天内给出合理解释,为何你与楼主的ip地址一模一样,且他对你的奖励也最多,如给不出合理解释,我们将按版规严肃处理http://emuch.net/bbs/viewthread.php?tid=1499116&fpage=1 10-22 08:33
(1)
关键词:The hydrogen-terminated Si(111) surface
prepared was stable under air atmosphere for a day or more.
Spectroscopic Studies on Electroless Deposition of Copper on Hydrogen-Terminated
Si(111) Surface in NH4F Solution Containing Cu(II) Ions
In-Churl Lee, Sang-Eun Bae, Moon-Bong Song, Jong-Soon Lee, Se-Hwan Paek, and Chi-Woo J. Lee*
College of Science and Technology, Korea University, Jochiwon, Choongnam 339-700, Korea
Received July 4, 2003
The electroless deposition of copper on the hydrogen-terminated Si(111) surface was investigated by means of
attenuated total reflection Fourier transform infrared (ATR-FTIR) spectroscopy, scanning tunneling
microscopy (STM), and energy-dispersive spectroscopy (EDS). The hydrogen-terminated Si(111) surface
prepared was stable under air atmosphere for a day or more. It was found from ATR-FTIR that two bands
centered at 2000 and 2260 cm−1 appeared after the H-Si(111) surface was immersed in 40% NH4F solution
containing 10 mM Cu2+. On the other hand, STM image included the copper islands with a height of 5 nm and
a diameter of 10-20 nm. The EDS data displayed the presence of copper, silicon and oxygen species. The results
were rationalized in terms of the redox reaction of surface Si atoms and Cu2+ ions in solutions, which are
changed into Si(OH)x(F)y containing SiF6
2− ions and neutral copper islands.
Key Words : Silicon, Copper, Ammonium fluoride, ATR, STM

(2)Stability Study of Self-Assembled Monolayers on Silicon(111)

Volume 2, Issue 1, Spring 2005 Nanoscape 89-95

希望对你有帮助!

[ Last edited by Skyandsun on 2009-10-22 at 17:21 ]
3楼2009-10-21 09:32:12
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jinlin

至尊木虫 (著名写手)

2楼2009-10-19 13:19:49
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