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[资源] 【资源】超分子聚合反应综述Supramolecular Polymerization【2009】

Supramolecular Polymerization
Tom F. A. De Greef, Maarten M. J. Smulders, Martin Wolffs, Albert P. H. J. Schenning, Rint P. Sijbesma, and
E. W. Meijer*
Institute for Complex Molecular Systems and Laboratory of Macromolecular and Organic Chemistry, Eindhoven University of Technology,
P.O. Box 513, 5600 MB Eindhoven, The Netherlands
Received May 7, 2009
Contents
1. Deﬁnitions A
1.1. Background A
1.2. Classiﬁcation C
1.3. Supramolecular Polymerization Mechanisms D
2. Isodesmic Supramolecular Polymerization E
2.1. Deﬁnition and Covalent Counterpart E
2.2. Thermodynamic Aspects of Isodesmic
Supramolecular Polymerizations
E
2.3. Examples of Isodesmic Supramolecular
Polymerization
H
2.3.1. Systems with Electronically Coupled
Polymerizable Functionalities
H
2.3.2. Supramolecular Polymers Built by
Monomers Containing Electronically
Noncoupled End Groups
L
2.4. Concluding Remarks on Isodesmic
Supramolecular Polymerization
Q
3. Ring-Chain Supramolecular Polymerization R
3.1. Deﬁnition and Covalent Counterpart R
3.2. Thermodynamic Aspects of Ring-Chain
Supramolecular Polymerization
S
3.3. Examples of Supramolecular Polymerization
Processes Involving Ring-Chain Equilibria
U
4. Cooperative Supramolecular Polymerization AC
4.1. Deﬁnition and Covalent Counterparts AC
4.2. Thermodynamic Aspects of Cooperative
Supramolecular Polymerizations
AE
4.3. Hysteresis Effects in Supramolecular Polymers AK
4.4. Heterogeneous versus Homogeneous
Nucleation
AK
4.5. Thermodynamic Aspects of Anticooperative
Supramolecular Polymerizations
AK
4.6. General Molecular Mechanisms of Cooperative
Supramolecular Polymerizations
AM
4.6.1. Electronic Effects AM
4.6.2. Structural Effects AM
4.6.3. Cooperativity Arising Due to the
Hydrophobic Effect
AO
4.7. Examples of Cooperative Supramolecular
Polymerization
AO
4.7.1. Cooperativity Due to Electronic Effects AP
4.7.2. Structural/Allosteric Cooperativity AU
4.7.3. Cooperativity through the Hydrophobic
Effect
AZ
4.7.4. Solvent Effects BD
4.8. Anticooperative Supramolecular Polymerization BD
5. Functional Supramolecular Polymers BF
5.1. Mechanical Properties BF
5.2. Electronic Properties BG
5.3. Biological Properties BH
6. Conclusions and Prospects BI
7. Acknowledgments BJ
8. References BJ

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[ Last edited by zhousatan on 2009-10-14 at 00:37 ]

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