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Supramolecular Polymerization Tom F. A. De Greef, Maarten M. J. Smulders, Martin Wolffs, Albert P. H. J. Schenning, Rint P. Sijbesma, and E. W. Meijer* Institute for Complex Molecular Systems and Laboratory of Macromolecular and Organic Chemistry, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven, The Netherlands Received May 7, 2009 Contents 1. Definitions A 1.1. Background A 1.2. Classification C 1.3. Supramolecular Polymerization Mechanisms D 2. Isodesmic Supramolecular Polymerization E 2.1. Definition and Covalent Counterpart E 2.2. Thermodynamic Aspects of Isodesmic Supramolecular Polymerizations E 2.3. Examples of Isodesmic Supramolecular Polymerization H 2.3.1. Systems with Electronically Coupled Polymerizable Functionalities H 2.3.2. Supramolecular Polymers Built by Monomers Containing Electronically Noncoupled End Groups L 2.4. Concluding Remarks on Isodesmic Supramolecular Polymerization Q 3. Ring-Chain Supramolecular Polymerization R 3.1. Definition and Covalent Counterpart R 3.2. Thermodynamic Aspects of Ring-Chain Supramolecular Polymerization S 3.3. Examples of Supramolecular Polymerization Processes Involving Ring-Chain Equilibria U 4. Cooperative Supramolecular Polymerization AC 4.1. Definition and Covalent Counterparts AC 4.2. Thermodynamic Aspects of Cooperative Supramolecular Polymerizations AE 4.3. Hysteresis Effects in Supramolecular Polymers AK 4.4. Heterogeneous versus Homogeneous Nucleation AK 4.5. Thermodynamic Aspects of Anticooperative Supramolecular Polymerizations AK 4.6. General Molecular Mechanisms of Cooperative Supramolecular Polymerizations AM 4.6.1. Electronic Effects AM 4.6.2. Structural Effects AM 4.6.3. Cooperativity Arising Due to the Hydrophobic Effect AO 4.7. Examples of Cooperative Supramolecular Polymerization AO 4.7.1. Cooperativity Due to Electronic Effects AP 4.7.2. Structural/Allosteric Cooperativity AU 4.7.3. Cooperativity through the Hydrophobic Effect AZ 4.7.4. Solvent Effects BD 4.8. Anticooperative Supramolecular Polymerization BD 5. Functional Supramolecular Polymers BF 5.1. Mechanical Properties BF 5.2. Electronic Properties BG 5.3. Biological Properties BH 6. Conclusions and Prospects BI 7. Acknowledgments BJ 8. References BJ Ŀ¼ÈçÉÏ£º ÓбØÒªÏµĻ°¼ûÏÂÃæµØÖ·£º http://d.namipan.com/d/5192113c0 ... 16338aebb79352f2400 ¼ÇµÃÒª¸øÐÇÐÇ£¡£¡£¡£¡£¡£¡£¡£¡£¡ [ Last edited by zhousatan on 2009-10-14 at 00:37 ] |
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