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Freyass

新虫 (小有名气)

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虫号: 14774975

[交流] IP Paris CSC合作项目的PHD

导师招生
以下是关于课题的详细,如有意愿可与老师联系,发送CV至老师邮件,讲明申请意愿. 导师人超级nice,实验室氛围融洽,希望大家踊跃申请.
老师邮箱:sebastien.prevost@ensta-paris.fr

实验室主页: https://lso.polytechnique.fr

招生导师: Sébastien Prévost

课题组链接 : https://sebastienprevost1.wixsite.com/chemistrygroup
招生课题详细信息链接:
         https://adum.fr/as/ed/voirpropos ... atricule_prop=51024

   如若不能打开,以下是详细要求.
                           METAL-CATALYZED C7-FUNCTIONALIZATION OF NAPHTHALENES VIA C-H ACTIVATION
Keywords:
         C-H activation, catalysis, naphthalene
Profile and skills required:
   The candidate should have a very strong background in organic chemistry and organometallic catalysis. Konwledge in analyticalchemistry (NMR, MS...) are also required.
   Niveau d'anglais requis: Intermédiaire: Vous pouvez parler la langue de manière compréhensible, cohérente et avec assurance sur des sujets de la vie courante qui vous sont familiers.
   Project description:
   Catalysis is one of the fundamental pillars of the green chemistry and thus one of the most attractive fields in chemistry. Among this area, C-H activation has significantly grown in importance during the last decade. Indeed, the direct functionalization of C-H bond allows a fast access to complex molecules without the introduction of an activated group which is important from an atom economy point of view.
   However, due to the large number of C-H bonds in molecules, C-H activation strategies are often very challenging. Regarding naphthalene skeleton, several C-H bonds can be selectively functionalized. During our research program on C-H activation, we previously focused on the C8-H bond and some applications in natural product synthesis. In this PhD project, the objective will be to target the C7-H bond which has been very little studied. This work would open an access to polyfunctionalized naphthalenes.

   References
(1) Garrec, J.; Cordier, M.; Frison, G.; Prévost, S. Chem. Eur. J. 2019,25, 14441.
(2) Berrou, C.; Prévost, S. Adv. Synth. Catal. 2021, 363, 4091.
(3) Amistadi-Revol, H.; Garrec, J.; Casaretto, N.; Prévost, S. Eur. J. Org. Chem. 2023, 26, e202300359.
(4) Liu, S.; Prévost Org. Lett. 2023, 25, 1380.

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