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[交流]
IP Paris CSC合作项目的PHD
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导师招生 以下是关于课题的详细,如有意愿可与老师联系,发送CV至老师邮件,讲明申请意愿. 导师人超级nice,实验室氛围融洽,希望大家踊跃申请. 老师邮箱:sebastien.prevost@ensta-paris.fr 实验室主页: https://lso.polytechnique.fr 招生导师: Sébastien Prévost 课题组链接 : https://sebastienprevost1.wixsite.com/chemistrygroup 招生课题详细信息链接: https://adum.fr/as/ed/voirpropos ... atricule_prop=51024 如若不能打开,以下是详细要求. METAL-CATALYZED C7-FUNCTIONALIZATION OF NAPHTHALENES VIA C-H ACTIVATION Keywords: C-H activation, catalysis, naphthalene Profile and skills required: The candidate should have a very strong background in organic chemistry and organometallic catalysis. Konwledge in analyticalchemistry (NMR, MS...) are also required. Niveau d'anglais requis: Intermédiaire: Vous pouvez parler la langue de manière compréhensible, cohérente et avec assurance sur des sujets de la vie courante qui vous sont familiers. Project description: Catalysis is one of the fundamental pillars of the green chemistry and thus one of the most attractive fields in chemistry. Among this area, C-H activation has significantly grown in importance during the last decade. Indeed, the direct functionalization of C-H bond allows a fast access to complex molecules without the introduction of an activated group which is important from an atom economy point of view. However, due to the large number of C-H bonds in molecules, C-H activation strategies are often very challenging. Regarding naphthalene skeleton, several C-H bonds can be selectively functionalized. During our research program on C-H activation, we previously focused on the C8-H bond and some applications in natural product synthesis. In this PhD project, the objective will be to target the C7-H bond which has been very little studied. This work would open an access to polyfunctionalized naphthalenes. References (1) Garrec, J.; Cordier, M.; Frison, G.; Prévost, S. Chem. Eur. J. 2019,25, 14441. (2) Berrou, C.; Prévost, S. Adv. Synth. Catal. 2021, 363, 4091. (3) Amistadi-Revol, H.; Garrec, J.; Casaretto, N.; Prévost, S. Eur. J. Org. Chem. 2023, 26, e202300359. (4) Liu, S.; Prévost Org. Lett. 2023, 25, 1380. |
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8楼2023-11-17 06:48:53
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Freyass(金币+1): 谢谢参与
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