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心清若镜捐助贵宾 (正式写手)
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[交流]
请问tobermorite、jennite以及c-s-h的晶体结构
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请问这三种物质的晶体结构是怎么样的？（注意：C-S-H和CSH是两个不同的概念） 请给出相应的文献出处。 能够直接提供相关文献下载、CIF文件等等那就更符合题意了，有可能得到所有的金币。 当然，我也不拒绝其他能够说明其晶体结构的方式，只要它是大家通用的，易于接受的。 -------------------- 这个问题肯定不是一两句话能够回答清楚的，需要“高超”的文献检索能力。 如果只想混点分，即便我很有爱，这也是不可能的，这样对认真回答他人问题的虫友很不公平。毕竟不能坏了小木虫互帮互助的规矩。 请有意者认真帮忙查阅一下相关资源，我暂时不方便上教育网，所以更加不方便。 提前说一声谢谢！ ------------------------ 暂定截止日期为下周六。 如果我自己搞定了（小概率事件），我会在回帖中说明。 --------------------------------- 如果有雷同回答等，以最后编辑时间为准，优先发放金币。 --------------- 请热心的朋友帮个忙，谢谢！ [ Last edited by zzgyb on 2009-9-24 at 14:02 ] |
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vjyong
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到 http://rruff.geo.arizona.edu/AMS/amcsd.php 搜索 http://rruff.geo.arizona.edu/AMS/result.php Tobermorite Mineral Data Tobermorite Download hom/tobermorite.pdf Merlino S, Bonaccorsi E, Armbruster T Download am/vol84/AM84_1613.pdf American Mineralogist 84 (1999) 1613-1621 Tobermorites: Their real structure and order-disorder (OD) character Sample: 9 Angstrom 11.156 7.303 9.566 101.08 92.83 89.98 C-1 atom x y z Uiso Si1 .3859 .2158 .2234 .013 Si2 .3181 -.0193 .4343 .025 Si3 .3883 .6416 .2173 .015 O1 .390 .150 .377 .030 O11 .390 -.209 .371 .024 O2 .499 .663 .121 .024 O21 .502 .152 .136 .018 O3 .268 .649 .118 .013 O31 .267 .163 .133 .018 O4 .403 .441 .277 .022 O6 .179 -.040 .384 .041 OH6 .152 .488 .390 .050 Ca1 .3713 .0981 -.1040 .017 Ca2 .499 .460 .502 .035 Ca3 .3647 .5966 -.1175 .017 Download AMC data (View Text File) Download CIF data (View Text File) Download diffraction data (View Text File) View JMOL 3-D Structure Tobermorite Download hom/tobermorite.pdf Merlino S, Bonaccorsi E, Armbruster T Download am/vol84/AM84_1613.pdf American Mineralogist 84 (1999) 1613-1621 Tobermorites: Their real structure and order-disorder (OD) character Sample: 11 Angstrom 6.735 7.385 22.487 90 90 123.25 Bm atom x y z Uiso Si1 .7581 .3862 .15738 .0054 Si2 .9087 .7531 .07116 .0086 Si3 .7592 .9697 .15773 .0056 O1 .771 .5059 .0942 .014 O2 .759 .178 .1327 .0127 O3 .985 .5369 .1982 .0090 O4 .519 .3063 .1942 .012 O5 .894 .746 0 .017 OH6 .188 .893 .0940 .018 Wat6 .270 .434 .0939 .045 O7 .770 .860 .0951 .015 O8 .523 .8110 .1951 .011 O9 .987 .0459 .1985 .010 Ca1 .2651 .4328 .20557 .0085 Ca3 .7499 .9228 .29348 .0074 Wat1 .427 .219 0 .14 Wat2 .879 .237 0 .061 Wat3 .422 .800 0 .13 Download AMC data (View Text File) Download CIF data (View Text File) Download diffraction data (View Text File) View JMOL 3-D Structure Tobermorite Download hom/tobermorite.pdf Merlino S, Bonaccorsi E, Armbruster T European Journal of Mineralogy 12 (2000) 411-429 The real structure of clinotobermorite and tobermorite 9 A: OD character, polytypes, and structural relationships Sample: MDO2 11.156 7.303 9.566 101.08 92.83 89.98 C-1 atom x y z occ Uiso Ca1 .3713 .0981 -.1040 .017 Ca2 .499 .460 .502 .5 .035 Ca3 .3647 .5966 -.1175 .017 Si1 .3859 .2158 .2234 .013 Si2 .3181 -.0193 .4343 .025 Si3 .3883 .6416 .2173 .015 O1 .390 .150 .377 .030 O11 .390 -.209 .371 .024 O2 .499 .663 .121 .024 O21 .502 .152 .136 .018 O3 .268 .649 .118 .013 O31 .267 .163 .133 .018 O4 .403 .441 .277 .022 O6 .179 -.040 .384 .041 OH6 .152 .488 .390 .050 Download AMC data (View Text File) Download CIF data (View Text File) Download diffraction data (View Text File) View JMOL 3-D Structure Tobermorite Download hom/tobermorite.pdf Merlino S, Bonaccorsi E, Armbruster T European Journal of Mineralogy 13 (2001) 577-590 The real structure of tobermorite 11A: normal and anomalous forms, OD character and polytypic modifications Note: sample MD01 Locality: Wessels mine, South Africa 11.265 7.386 44.970 90 90 90 F2dd atom x y z Uiso Ca1 .0048 .9977 .1034 .0078 Ca3 .9984 .5009 .1026 .0074 Si1 .2500 .2900 .0790 .006 Si2 .1760 -.001 .0356 .008 Si3 .2518 .7077 .0789 .004 O1 .136 .263 .1006 .003 O1b .138 .757 .0975 .007 O2 .620 .505 .1511 .011 O2b .620 .003 .1541 .007 O3 .183 0 0 .017 O5 .251 .499 .0667 .010 O6 .248 .179 .0475 .019 O6b .244 .824 .0476 .011 O7 .034 .007 .0457 .024 O7b .996 .508 .0478 .044 Wat2 .692 0 0 .06 Wat3 .416 .298 .001 .06 Download AMC data (View Text File) Download CIF data (View Text File) Download diffraction data (View Text File) View JMOL 3-D Structure Tobermorite Download hom/tobermorite.pdf Merlino S, Bonaccorsi E, Armbruster T European Journal of Mineralogy 13 (2001) 577-590 The real structure of tobermorite 11A: normal and anomalous forms, OD character and polytypic modifications Note: sample MD02 Locality: Wessels mine, South Africa 6.735 7.385 22.487 90 90 123.25 Bm atom x y z Uiso Ca1 .2651 .4328 .20557 .0085 Ca3 .7499 .9228 .29348 .0074 Si1 .7581 .3862 .15738 .0054 Si2 .9087 .7531 .07117 .0086 Si3 .7592 .9697 .15773 .0056 O1 .771 .5059 .0942 .014 O2 .759 .178 .1327 .0127 O3 .985 .5369 .1982 .0091 O4 .519 .3063 .1942 .012 O5 .894 .746 0 .017 O6 .188 .893 .0940 .018 Wat6 .270 .434 .0939 .045 O7 .770 .8601 .0951 .015 O8 .523 .8110 .1950 .011 O9 .987 .0459 .1985 .010 Wat1 .427 .219 0 .14 Wat2 .879 .237 0 .060 Wat3 .422 .800 0 .13 Download AMC data (View Text File) Download CIF data (View Text File) Download diffraction data (View Text File) View JMOL 3-D Structure Tobermorite Download hom/tobermorite.pdf Merlino S, Bonaccorsi E, Armbruster T European Journal of Mineralogy 13 (2001) 577-590 The real structure of tobermorite 11A: normal and anomalous forms, OD character and polytypic modifications Note: sample MDO2 - conventional X-ray source Locality: Bascenov, Urals, Russia 6.732 7.369 22.680 90 90 123.18 Bm atom x y z occ Uiso Ca1 .2632 .4310 .2069 .011 Ca2 .559 .078 .044 .25 .035 Ca3 .7519 .9228 .2945 .009 Si1 .757 .3876 .1574 .007 Si2 .915 .756 .0710 .015 Si3 .758 .967 .1589 .007 O1 .754 .499 .0949 .018 O2 .772 .185 .1328 .014 O3 .992 .537 .1971 .011 O4 .523 .312 .1946 .015 O5 .898 .752 0 .017 O6 .197 .896 .0949 .018 Wat6 .237 .416 .097 .09 O7 .752 .853 .0972 .017 O8 .524 .807 .1962 .008 O9 .984 .045 .2002 .011 Wat1 .42 .26 -.020 .5 .13 Wat2 .922 .250 0 .07 Wat3 .40 .76 -.019 .5 .10 Download AMC data (View Text File) Download CIF data (View Text File) Download diffraction data (View Text File) View JMOL 3-D Structure Tobermorite Download hom/tobermorite.pdf Merlino S, Bonaccorsi E, Armbruster T European Journal of Mineralogy 13 (2001) 577-590 The real structure of tobermorite 11A: normal and anomalous forms, OD character and polytypic modifications Note: MDO2 - synchrotron radiation source Locality: Bascenov, Urals, Russia 6.732 7.369 22.680 90 90 123.18 Bm atom x y z occ Uiso Ca1 .277 .4257 .2083 .024 Ca2 .562 .064 .045 .25 .038 Ca3 .763 .916 .2951 .027 Si1 .771 .383 .1578 .031 Si2 .925 .750 .0721 .030 Si3 .772 .962 .1596 .027 O1 .774 .495 .0932 .039 O2 .762 .169 .1305 .019 O3 .002 .527 .2000 .032 O4 .536 .304 .1926 .035 O5 .910 .747 0 .034 O6 .202 .887 .0942 .053 Wat6 .289 .436 .094 .076 O7 .769 .843 .0953 .027 O8 .537 .798 .1968 .036 O9 .004 .043 .2008 .034 Wat1 .433 .223 -.025 .5 .072 Wat2 .949 .256 0 .08 Wat3 .43 .77 -.022 .5 .09 Download AMC data (View Text File) Download CIF data (View Text File) Download diffraction data (View Text File) View JMOL 3-D Structure jennite的晶体结构 1 matching records for this search. Jennite Download hom/jennite.pdf Bonaccorsi E, Merlino S, Taylor H F W Cement and Concrete Research 34 (2004) 1481-1488 The crystal structure of jennite, Ca9Si6O18(OH)6*8H2O Locality: Fuka, Japan 10.576 7.265 10.931 101.30 96.98 109.65 P-1 atom x y z Uiso Ca1 .0601 .3632 .3648 .059 Ca2 .4226 .7984 .3617 .056 Ca3 .0658 .8664 .3769 .061 Ca4 .4289 .2954 .3531 .061 Ca5 0 .5 0 .072 Si1 .8014 .942 .1939 .060 Si2 .7248 .241 .3748 .063 Si3 .7222 .673 .3784 .058 O1 .970 .024 .246 .051 OH2 .273 .962 .308 .069 O3 .588 .129 .423 .047 O4 .872 .318 .487 .057 O5 .742 .121 .246 .068 O6 .720 .747 .249 .060 O7 .701 .433 .331 .071 O8 .756 .859 .0409 .047 O9 .581 .658 .429 .055 O10 .866 .794 .480 .058 OH11 .273 .458 .303 .066 OH12 .985 .542 .230 .065 Wat13 .443 .193 .129 .086 Wat14 .542 .191 .863 .080 Wat1 .914 .143 .941 .079 Wat2 .781 .519 .964 .083 Download AMC data (View Text File) Download CIF data (View Text File) Download diffraction data (View Text File) View JMOL 3-D Structure Download in: Multiple datasets can be concatenated into a single downloadable file by selecting the datasets and then hitting the "Download Selected Data" button. Total number of retrieved datasets: 1 View in amclongform, download in amc Return to AMCSD Home Page C-S-H晶体结构 Hillebrandite Download hom/hillebrandite.pdf Dai Y S, Post J E Download am/vol80/AM80_841.pdf American Mineralogist 80 (1995) 841-844 Crystal structure of hillebrandite: A natural analogue of calcium silicate hydrate (CSH) phases in Portland cement 3.6389 16.311 11.829 90 90 90 Cmc2_1 atom x y z occ Uiso Ca1 0 .2164 .064 .0137 Ca2 .5 .3992 -.0479 .0114 Ca3 .5 .0490 .1888 .0118 Si1 .430 .0863 -.1019 .5 .011 Si2 .5 .3727 .2134 .5 .008 OH1 0 .3091 -.0812 .014 O2 .5 .1259 .0198 .013 O3 .5 .4637 .138 .024 O4 .5 .2964 .1251 .019 O5 0 .4890 -.1123 .010 OH6 0 .1370 .2361 .013 O7 .364 .1328 -.205 .5 .014 O8 0 .110 -.127 .5 .014 Download AMC data (View Text File) Download CIF data (View Text File) Download diffraction data (View Text File) View JMOL 3-D Structure |
4楼2009-09-21 09:04:19
心清若镜
捐助贵宾 (正式写手)
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（后者淘宝见……有意者站内信联系） 2楼2009-09-20 22:42:34
vjyong
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Tobermorite Mineral Data Help on Axial Ratios: Axial Ratios: a:b:c =1.5416:1:3.0832 Help on Cell Dimensions: Cell Dimensions: a = 11.3, b = 7.33, c = 22.6, Z = 4; V = 1,871.94 Den(Calc)= 2.49 Help on Crystal System: Crystal System: Orthorhombic - DisphenoidalH-M Symbol (2 2 2) Space Group: C 2221 Help on X Ray Diffraction: X Ray Diffraction: By Intensity(I/Io): 14(1), 3.706(0.65), 3.001(0.45),1.835(0.35), 2.812(0.3), 5.5(0.25), 2.793(0.13), from:http://webmineral.com/data/Tobermorite.shtml 有详细数据。 jennite的晶体结构 Help on Axial Ratios: Axial Ratios: a:b:c =1.4557:1:1.5046 Help on Cell Dimensions: Cell Dimensions: a = 10.576, b = 7.265, c = 10.931, Z = 1; alpha = 101.3°, beta = 96.98°, gamma = 109.65° V = 769.89 Den(Calc)= 2.29 Help on Crystal System: Crystal System: Triclinic - PinacoidalH-M Symbol ( 1) Space Group: P1 Help on X Ray Diffraction: X Ray Diffraction: By Intensity(I/Io): 10.5(1), 2.92(0.8), 3.04(0.6), Click Here for Large Jennite Structure Window Crystal Structure: Mouse drag1 - LMB Manipulate Structure drag2 - RMB Resize/Rotate Keyboard S - Stereo Pair on/off H - Help Screen I - Data Info A - Atoms On/Off P - Polyhedra On/Off B - Bonds On/Off Help on Above Bonaccorsi E , Merlino S , Taylor H F W , Cement and Concrete Research , 34 (2004) p.1481-1488, The crystal structure of jennite, Ca9Si6O18(OH)6*8H2O, Locality: Fuka, Japan http://webmineral.com/data/Jennite.shtml c-s-h的晶体结构 http://commons.wikimedia.org/wik ... tructure_RasMol.gif  Crystal structure of hillebrandite: A natural analogue of calcium silicate hydrate. (CSH) phases in Portland |
3楼2009-09-21 08:57:46
心清若镜
捐助贵宾 (正式写手)
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你这是GOOGLE随便复制粘贴来的吧？ 太乱了—— 而且tobermorite的结构是GOOGLE的第一条对吧？呵呵。我早用过GOOGLE了。 如果没有研究背景等等，直接GOOGLE的一个最大坏处是，可以得到很多很多信息，但不知道哪些信息是可靠的。 就好像你直接复制粘贴这么多内容上来，但我根本不知道哪些内容是比较权威的。 感谢你的辛苦复制粘贴！ 但这样的回答真的得不到多少分—— 理想的回答格式比如： tobermorite: 一共有a种晶体结构 1.来自文献XXX 文献下载链接 对应CIF文件 2.来自文献XXX 文献下载链接 对应CIF文件 …… junite: 一共有b种晶体结构 …… C-S-H： 一共有c种晶体结构 …… |
5楼2009-09-21 12:22:35
