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Polymer stress relaxation process is mainly manifested in the polymer chain segment of the movement and rearrangement, as well as bond angle changes. From the kinetic theory of polymer chain segments, the polymer stress relaxation is actually the molecular chains along the direction of external forces for campaigns to reduce or eliminate stress in the process of fast and slow movement of molecular chain segments directly hinders the stress relaxation rate size. In the stress relaxation experiment, the initial load the specimen deformation resulting from two main parts: the bond length and bond angle changes in the ordinary elastic deformation and changes in polymer chain segment motion high-elastic deformation. The initial sample deformation is mainly ordinary elastic deformation, normal elastic deformation of high modulus. Spontaneous rebound in the initial deformation under the action of internal stress, with time, those who stretch longer chain segment, has gradually along the direction of force by the coil molecular conformation to the extended molecular conformation movement, developed into a high-elastic deformation. Deformation due to the high elastic modulus much lower than the average modulus of elastic deformation, allowing the specimen to maintain the same strain of the internal stress reduced stress relaxation took place. Due to the high elastic deformation gradually replaced the ordinary elastic deformation, macroscopic stress on the observed increase over time reduce the phenomenon, with the extension of observation time, stress relaxation and constant strain developed to balance the stress values, stress relaxation will cease to stabilize.
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