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The stress relaxation process of polymer is mainly for polymer chains and rearrangement of movement and key Angle of change. From the theory of sport polymers for chain, polymer stress relaxation is actually the molecular chain along the direction of force to do exercise to decrease or eliminate stress process, molecular chain directly restricts movement speed for the size of the stress relaxation rate. In the stress relaxation process of test sample loading, when the initial deformation produced mainly includes two parts: the key of ordinary long horn changes that elastic deformation and polymer chain period of high elastic deformation motion changes. The initial deformation sample for ordinary elastic deformation, ordinary elastic deformation modulus is very high. In the initial deformation of spontaneous rebound, under the action of stress with the extension of time, the long chain tension, successively gradually from the direction of the effort to extend molecular conformation curly conformation movement, high elastic deformation become. Due to the high elastic deformation modulus far below normal elastic deformation modulus, maintain the same sample of stress, strain and stress relaxation happened. Due to the high elastic deformation gradually replaced the ordinary elastic deformation, stress on the macro was observed with time and reduce the phenomenon, as observed the extension of time, the stress relaxation development should be balanced with the constant disguised stress value of the stress relaxation will stop, achieve stability.
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