| 查看: 817 | 回复: 7 | |||
| 当前主题已经存档。 | |||
| 【有奖交流】积极回复本帖子,参与交流,就有机会分得作者 ppcenter 的 1 个金币 | |||
| 当前只显示满足指定条件的回帖,点击这里查看本话题的所有回帖 | |||
[交流]
【求助】请教大虾们sacrificial initiator的翻译thx
|
|||
还是这里人气旺![]() sacrificial initiator一般在ATRP文献中有出现 求教大虾们啦 无限感谢 |
» 猜你喜欢
拟解决的关键科学问题还要不要写
已经有8人回复
26申博
已经有3人回复
存款400万可以在学校里躺平吗
已经有22人回复
最失望的一年
已经有4人回复
国自然申请面上模板最新2026版出了吗?
已经有19人回复
请教限项目规定
已经有3人回复
基金委咋了?2026年的指南还没有出来?
已经有10人回复
基金申报
已经有6人回复
推荐一本书
已经有13人回复
疑惑?
已经有5人回复
|
xgyanger说对了 我看的正是surface initiate ATRP法 但之前没去想过它的具体作用 你的理解可能是对的 再结合下上下文看看 A sacrificial initiator,ethyl 2-bromoisobutyrate(EBiB), was also added so that the molecular weight of the grafted polymer could be tailored. EBiB will also initiate polymerizaiton, causing a bulk polymer to form simultaneously to the graft-copolymer from the surface. Because the amount of sacrificial initiator is much larger than the amount of initiator attached to the surface, the amount of initiator attached to the surface is neglected, and the molecular weight of the resulting bulk and grafted polymer is only a function of the sacrificial initiator-to-monomer ratio. This is a common method to control the length of the grafts from surface confined initiators. 但不大理解倒数第二句only function指的内容 看来得找找文献看看 xgyanger是做ATRP的么 谢谢指教哈 |
7楼2009-08-26 16:25:21
xgyanger
木虫 (著名写手)
- 应助: 17 (小学生)
- 金币: 1731.8
- 散金: 1801
- 红花: 13
- 帖子: 1093
- 在线: 385.1小时
- 虫号: 591071
- 注册: 2008-09-01
- 专业: 电化学
2楼2009-08-26 15:32:59
|
A sacrificial initiator,ethyl 2-bromoisobutyrate(EBiB), was also added so that the molecular weight of the grafted polymer could be tailored. EBiB will also initiate polymerizaiton, causing a bulk polymer to form simultaneously to the graft-copolymer from the surface. 但好像sacrificial initiator一般在ATRP中提到是和initiator terminationi并存的 |
3楼2009-08-26 15:40:45
5楼2009-08-26 15:54:41














回复此楼