| 查看: 130 | 回复: 1 | |||
| 当前主题已经存档。 | |||
[交流]
活化C-H键相关翻译！
|
|||
| -Bond activation by atomic metal ions can be explained using a simple donor-acceptor modelSuch reactions require electronic configurations in which there is an empty acceptor orbital on the metal ion into which the electrons of a bond to be broken are donated. Concomitantly, metal electrons in orbitals having pi-symmetry back donate into the antibonding orbital of the bond to be broken. If the acceptor orbital is occupied a repulsive interaction can result leading to inefficient reaction either by more direct abstraction pathways or by introduction of a barrier to the reaction. |
回复此楼» 猜你喜欢
081700，311，求调剂
已经有15人回复
-
一志愿北京化工085600 310分求调剂
已经有18人回复
-
085600材料与化工301分求调剂院校
已经有4人回复
-
材料与化工371求调剂
已经有14人回复
-
336材料与化工085600求调剂
已经有7人回复
-
材料334求调剂
已经有18人回复
-
331求调剂
已经有8人回复
-
332求调剂
已经有17人回复
-
一志愿南京航空航天大学 材料与化工329分求调剂
已经有4人回复
-
材料专硕322
已经有7人回复
2楼2009-08-20 13:36:40
5