课题组介绍:http://www.ipcm.fr/bouteiller-laurent-777?lang=en#opennewwindow
项目介绍:csc与索邦大学(sorbonne université)的合作项目
招生类型:
1. 应届与往届硕士毕业生
招生要求:
1. 性格开朗,勤奋好学;
2. 仅考虑有机合成/方法学候选人,有均相催化背景的学生更佳;
3. 有至少一篇一作的英文文章;
4. 需要与课题组一起申请csc。
团队优势:
1. 法国最好的大学(居里夫妇的母校)
2. 超一流的实验条件与强大的公共测试/仪器平台(经培训后可自主操作);
3. 年轻的团队,和谐的师生关系。
研究内容:selectivity switchable catalyst for asymmetric cascade reactions
简要介绍:our project is at the forefront of innovation in the field of homogeneous catalysis. in the domain of supramolecular catalysis, non-covalent interactions are designed between the partners of the catalytic reaction in order to build catalysts with new functions or modify the catalytic performance of an existing catalyst.[1] we propose a new approach in which hydrogen-bonded supramolecular polymers, formed by means of non-covalent interactions between structurally-simple monomers, are used as a scaffold for catalysis. as a proof-of-concept, we performed asymmetric reactions by means of intrinsically achiral metal complexes positioned at the periphery of chiral assemblies. these chiral assemblies are formed by mixing chiral and achiral bta monomers.[2-7] the topic of this thesis concerns the use of selectivity switchable catalysts in stereoselective cascade reactions, following our recently published papers.
major publications in the domain:
[1] m. raynal, p. ballester, a. vidal-ferran, p. w. n. m. van leeuwen chem. soc. rev. 2014, 43, 1660
[2] a. desmarchelier, x. caumes, m. raynal, a. vidal-ferran, p. w. n. m. van leeuwen, l. bouteiller j. am. chem. soc. 2016, 138, 4908
[3] j. m. zimbron, x. caumes, y. li, c. m. thomas, m. raynal, l. bouteiller angew. chem. int. ed. 2017, 56, 14016
[4] y. li, x. caumes, m. raynal, l. bouteiller chem. commun. 2019, 55, 2162
[5] y. li, l. bouteiller, m. raynal chemcatchem 2019, 11, 5212
[6] m. martinez-aguirre, y. li, n. vanthuyne, l. bouteiller, m. raynal, angew. chem. int. ed., 10.1002/anie.202012457.
[7] y. li, a. hammoud, l. bouteiller, m. raynal, j. am. chem. soc., 2020, 142, 5676-5688
a strong expertise in organic synthesis and practical experience in homogeneous catalysis is required. a good background in analytical chemistry will also be appreciated.
联系人:
prof. bouteiller laurent
laurent.bouteiller@sorbonne-universite.fr |