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| Low-temperature synthesis and characterization of helical carbon fibers by one-step chemical vapour deposition, Applied Surface Science, 2015 324£¨1£©:438-442 |
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±»ÒýƵ´Î: 7 Low-temperature synthesis and characterization of helical carbon fibers by one-step chemical vapour deposition ×÷Õß:Jin, YZ (Jin, Yongzhong)[ 1 ] ; Chen, J (Chen, Jian)[ 1 ] ; Fu, QS (Fu, Qingshan)[ 1 ] ; Li, BH (Li, Binghong)[ 2,3 ] ; Zhang, HZ (Zhang, Huazhi)[ 1 ] ; Gong, Y (Gong, Yong)[ 1 ] ²é¿´ Web of Science ResearcherID ºÍ ORCID APPLIED SURFACE SCIENCE ¾í: 324 Ò³: 438-442 DOI: 10.1016/j.apsusc.2014.10.107 ³ö°æÄê: JAN 1 2015 ÎÄÏ×ÀàÐÍ:Article ²é¿´ÆÚ¿¯Ó°ÏìÁ¦ ÕªÒª Helical carbon fibers (HCNFs) were synthesized by one-step chemical vapour deposition using cupric tartrate as a catalyst at temperature below 500 degrees C. The bound rubber of natural rubber (NR)/HCNFs were also prepared in this study. The results of thermogravimetry-differential scanning calorimetry (TG/DSC) for cupric tartrate nanoparticles show that the transformation of C4H4CuO6 -> Cu reaction occurs at similar to 250-310 degrees C. The characterization of scanning electron microscopy (SEM), transmission electron microscope (TEM), X-ray diffraction (XRD) and Raman spectrum for the synthesized products confirms that the synthesis of HCNFs is highly temperature-dependent. The straight fibers with the fiber diameter of 100-400 nm are obtained at 280 degrees C and HCNFs can be synthesized at higher temperature, with the coil diameter of 0.5-1 mu m and fiber diameter of 100-200 nm at 380 degrees C, and the coil diameter of 100 nm and fiber diameter of similar to 80 nm at 480 degrees C. The maximum of the bound-rubber content (37%) can be obtained with the addition of similar to 100 wt.% HCNFs in NR, which indicates that the coiled configuration of HCNFs makes a noticeable contribution to the reinforcement of NR/CB system. (C) 2014 Elsevier B.V. All rights reserved. ¹Ø¼ü´Ê ×÷Õ߹ؼü´Ê:Helical carbon fibers; Nanomaterials; Chemical vapor deposition; Bound rubber KeyWords Plus:NANOTUBES; MECHANISM; DECOMPOSITION; ACETYLENE; COMPOSITE ×÷ÕßÐÅÏ¢ ͨѶ×÷ÕßµØÖ·: Chen, J (ͨѶ×÷Õß) ÏÔʾ¸ü¶à Sichuan Univ Sci & Engn, Dept Mat & Chem Engn, Zigong 643000, Sichuan, Peoples R China. µØÖ·: ÏÔʾ¸ü¶à [ 1 ] Sichuan Univ Sci & Engn, Dept Mat & Chem Engn, Zigong 643000, Sichuan, Peoples R China [ 2 ] China Rubber Grp Carbon Black Ind Res, Zigong 643000, Sichuan, Peoples R China [ 3 ] Design Inst, Zigong 643000, Sichuan, Peoples R China µç×ÓÓʼþµØÖ·:wuhangzs@163.com »ù½ð×ÊÖúÖÂл »ù½ð×ÊÖú»ú¹¹ÏÔʾÏêÇé ÊÚȨºÅ National Natural Science Foundation of China 51072125 Scientific and Technical Project of Sichuan Province 2013JQ0024 2013JY0124 Breeding Project of Sichuan University of Science and Engineering 2011PY06 ²é¿´»ù½ð×ÊÖúÐÅÏ¢ ³ö°æÉÌ ELSEVIER, RADARWEG 29, 1043 NX AMSTERDAM, NETHERLANDS Àà±ð / ·ÖÀà Ñо¿·½Ïò:Chemistry; Materials Science; Physics Web of Science Àà±ð:Chemistry, Physical; Materials Science, Coatings & Films; Physics, Applied; Physics, Condensed Matter ÎÄÏ×ÐÅÏ¢ ÓïÑÔ:English Èë²ØºÅ: WOS:000346088500057 ISSN: 0169-4332 eISSN: 1873-5584 ÆäËûÐÅÏ¢ IDS ºÅ: AW1ZT Web of Science ºËÐĺϼ¯ÖÐµÄ "ÒýÓõIJο¼ÎÄÏ×": 26 Web of Science ºËÐĺϼ¯ÖÐµÄ "±»ÒýƵ´Î": 6 |
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±»ÒýƵ´Î: 7 Low-temperature synthesis and characterization of helical carbon fibers by one-step chemical vapour deposition ×÷Õß:Jin, YZ (Jin, Yongzhong)[ 1 ] ; Chen, J (Chen, Jian)[ 1 ] ; Fu, QS (Fu, Qingshan)[ 1 ] ; Li, BH (Li, Binghong)[ 2,3 ] ; Zhang, HZ (Zhang, Huazhi)[ 1 ] ; Gong, Y (Gong, Yong)[ 1 ] ²é¿´ Web of Science ResearcherID ºÍ ORCID APPLIED SURFACE SCIENCE ¾í: 324 Ò³: 438-442 DOI: 10.1016/j.apsusc.2014.10.107 ³ö°æÄê: JAN 1 2015 ÎÄÏ×ÀàÐÍ:Article ²é¿´ÆÚ¿¯Ó°ÏìÁ¦ ÕªÒª Helical carbon fibers (HCNFs) were synthesized by one-step chemical vapour deposition using cupric tartrate as a catalyst at temperature below 500 degrees C. The bound rubber of natural rubber (NR)/HCNFs were also prepared in this study. The results of thermogravimetry-differential scanning calorimetry (TG/DSC) for cupric tartrate nanoparticles show that the transformation of C4H4CuO6 -> Cu reaction occurs at similar to 250-310 degrees C. The characterization of scanning electron microscopy (SEM), transmission electron microscope (TEM), X-ray diffraction (XRD) and Raman spectrum for the synthesized products confirms that the synthesis of HCNFs is highly temperature-dependent. The straight fibers with the fiber diameter of 100-400 nm are obtained at 280 degrees C and HCNFs can be synthesized at higher temperature, with the coil diameter of 0.5-1 mu m and fiber diameter of 100-200 nm at 380 degrees C, and the coil diameter of 100 nm and fiber diameter of similar to 80 nm at 480 degrees C. The maximum of the bound-rubber content (37%) can be obtained with the addition of similar to 100 wt.% HCNFs in NR, which indicates that the coiled configuration of HCNFs makes a noticeable contribution to the reinforcement of NR/CB system. (C) 2014 Elsevier B.V. All rights reserved. ¹Ø¼ü´Ê ×÷Õ߹ؼü´Ê:Helical carbon fibers; Nanomaterials; Chemical vapor deposition; Bound rubber KeyWords Plus:NANOTUBES; MECHANISM; DECOMPOSITION; ACETYLENE; COMPOSITE ×÷ÕßÐÅÏ¢ ͨѶ×÷ÕßµØÖ·: Chen, J (ͨѶ×÷Õß) ÏÔʾ¸ü¶à Sichuan Univ Sci & Engn, Dept Mat & Chem Engn, Zigong 643000, Sichuan, Peoples R China. µØÖ·: ÏÔʾ¸ü¶à [ 1 ] Sichuan Univ Sci & Engn, Dept Mat & Chem Engn, Zigong 643000, Sichuan, Peoples R China [ 2 ] China Rubber Grp Carbon Black Ind Res, Zigong 643000, Sichuan, Peoples R China [ 3 ] Design Inst, Zigong 643000, Sichuan, Peoples R China µç×ÓÓʼþµØÖ·:wuhangzs@163.com »ù½ð×ÊÖúÖÂл »ù½ð×ÊÖú»ú¹¹ÏÔʾÏêÇé ÊÚȨºÅ National Natural Science Foundation of China 51072125 Scientific and Technical Project of Sichuan Province 2013JQ0024 2013JY0124 Breeding Project of Sichuan University of Science and Engineering 2011PY06 ²é¿´»ù½ð×ÊÖúÐÅÏ¢ ³ö°æÉÌ ELSEVIER, RADARWEG 29, 1043 NX AMSTERDAM, NETHERLANDS Àà±ð / ·ÖÀà Ñо¿·½Ïò:Chemistry; Materials Science; Physics Web of Science Àà±ð:Chemistry, Physical; Materials Science, Coatings & Films; Physics, Applied; Physics, Condensed Matter ÎÄÏ×ÐÅÏ¢ ÓïÑÔ:English Èë²ØºÅ: WOS:000346088500057 ISSN: 0169-4332 eISSN: 1873-5584 ÆäËûÐÅÏ¢ IDS ºÅ: AW1ZT Web of Science ºËÐĺϼ¯ÖÐµÄ "ÒýÓõIJο¼ÎÄÏ×": 26 Web of Science ºËÐĺϼ¯ÖÐµÄ "±»ÒýƵ´Î": 6 |
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