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Low-temperature synthesis and characterization of helical carbon fibers by one-step chemical vapour deposition, Applied Surface Science, 2015        324(1):438-442

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被引频次: 7
Low-temperature synthesis and characterization of helical carbon fibers by one-step chemical vapour deposition
作者:Jin, YZ (Jin, Yongzhong)[ 1 ] ; Chen, J (Chen, Jian)[ 1 ] ; Fu, QS (Fu, Qingshan)[ 1 ] ; Li, BH (Li, Binghong)[ 2,3 ] ; Zhang, HZ (Zhang, Huazhi)[ 1 ] ; Gong, Y (Gong, Yong)[ 1 ]

查看 Web of Science ResearcherID 和 ORCID
APPLIED SURFACE SCIENCE

卷: 324  页: 438-442
DOI: 10.1016/j.apsusc.2014.10.107

出版年: JAN 1 2015

文献类型:Article

查看期刊影响力

摘要
Helical carbon fibers (HCNFs) were synthesized by one-step chemical vapour deposition using cupric tartrate as a catalyst at temperature below 500 degrees C. The bound rubber of natural rubber (NR)/HCNFs were also prepared in this study. The results of thermogravimetry-differential scanning calorimetry (TG/DSC) for cupric tartrate nanoparticles show that the transformation of C4H4CuO6 -> Cu reaction occurs at similar to 250-310 degrees C. The characterization of scanning electron microscopy (SEM), transmission electron microscope (TEM), X-ray diffraction (XRD) and Raman spectrum for the synthesized products confirms that the synthesis of HCNFs is highly temperature-dependent. The straight fibers with the fiber diameter of 100-400 nm are obtained at 280 degrees C and HCNFs can be synthesized at higher temperature, with the coil diameter of 0.5-1 mu m and fiber diameter of 100-200 nm at 380 degrees C, and the coil diameter of 100 nm and fiber diameter of similar to 80 nm at 480 degrees C. The maximum of the bound-rubber content (37%) can be obtained with the addition of similar to 100 wt.% HCNFs in NR, which indicates that the coiled configuration of HCNFs makes a noticeable contribution to the reinforcement of NR/CB system. (C) 2014 Elsevier B.V. All rights reserved.

关键词
作者关键词:Helical carbon fibers; Nanomaterials; Chemical vapor deposition; Bound rubber

KeyWords Plus:NANOTUBES; MECHANISM; DECOMPOSITION; ACETYLENE; COMPOSITE

作者信息
通讯作者地址: Chen, J (通讯作者)

显示更多        Sichuan Univ Sci & Engn, Dept Mat & Chem Engn, Zigong 643000, Sichuan, Peoples R China.
地址:

显示更多        [ 1 ] Sichuan Univ Sci & Engn, Dept Mat & Chem Engn, Zigong 643000, Sichuan, Peoples R China
              [ 2 ] China Rubber Grp Carbon Black Ind Res, Zigong 643000, Sichuan, Peoples R China
              [ 3 ] Design Inst, Zigong 643000, Sichuan, Peoples R China
电子邮件地址:wuhangzs@163.com

基金资助致谢
基金资助机构显示详情        授权号
National Natural Science Foundation of China

51072125
Scientific and Technical Project of Sichuan Province        
2013JQ0024
2013JY0124
Breeding Project of Sichuan University of Science and Engineering        
2011PY06
查看基金资助信息   
出版商
ELSEVIER, RADARWEG 29, 1043 NX AMSTERDAM, NETHERLANDS

类别 / 分类
研究方向:Chemistry; Materials Science; Physics

Web of Science 类别:Chemistry, Physical; Materials Science, Coatings & Films; Physics, Applied; Physics, Condensed Matter

文献信息
语言:English

入藏号: WOS:000346088500057

ISSN: 0169-4332

eISSN: 1873-5584

其他信息
IDS 号: AW1ZT

Web of Science 核心合集中的 "引用的参考文献": 26

Web of Science 核心合集中的 "被引频次": 6
3楼2020-03-09 08:46:31
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感谢参与,应助指数 +1
bringlee: 金币+25, ★★★★★最佳答案 2020-03-09 08:51:28
心静_依然: LS-EPI+1, 感谢应助 2020-03-09 10:50:48
被引频次: 7
Low-temperature synthesis and characterization of helical carbon fibers by one-step chemical vapour deposition
作者:Jin, YZ (Jin, Yongzhong)[ 1 ] ; Chen, J (Chen, Jian)[ 1 ] ; Fu, QS (Fu, Qingshan)[ 1 ] ; Li, BH (Li, Binghong)[ 2,3 ] ; Zhang, HZ (Zhang, Huazhi)[ 1 ] ; Gong, Y (Gong, Yong)[ 1 ]

查看 Web of Science ResearcherID 和 ORCID
APPLIED SURFACE SCIENCE

卷: 324  页: 438-442
DOI: 10.1016/j.apsusc.2014.10.107

出版年: JAN 1 2015

文献类型:Article

查看期刊影响力

摘要
Helical carbon fibers (HCNFs) were synthesized by one-step chemical vapour deposition using cupric tartrate as a catalyst at temperature below 500 degrees C. The bound rubber of natural rubber (NR)/HCNFs were also prepared in this study. The results of thermogravimetry-differential scanning calorimetry (TG/DSC) for cupric tartrate nanoparticles show that the transformation of C4H4CuO6 -> Cu reaction occurs at similar to 250-310 degrees C. The characterization of scanning electron microscopy (SEM), transmission electron microscope (TEM), X-ray diffraction (XRD) and Raman spectrum for the synthesized products confirms that the synthesis of HCNFs is highly temperature-dependent. The straight fibers with the fiber diameter of 100-400 nm are obtained at 280 degrees C and HCNFs can be synthesized at higher temperature, with the coil diameter of 0.5-1 mu m and fiber diameter of 100-200 nm at 380 degrees C, and the coil diameter of 100 nm and fiber diameter of similar to 80 nm at 480 degrees C. The maximum of the bound-rubber content (37%) can be obtained with the addition of similar to 100 wt.% HCNFs in NR, which indicates that the coiled configuration of HCNFs makes a noticeable contribution to the reinforcement of NR/CB system. (C) 2014 Elsevier B.V. All rights reserved.

关键词
作者关键词:Helical carbon fibers; Nanomaterials; Chemical vapor deposition; Bound rubber

KeyWords Plus:NANOTUBES; MECHANISM; DECOMPOSITION; ACETYLENE; COMPOSITE

作者信息
通讯作者地址: Chen, J (通讯作者)

显示更多        Sichuan Univ Sci & Engn, Dept Mat & Chem Engn, Zigong 643000, Sichuan, Peoples R China.
地址:

显示更多        [ 1 ] Sichuan Univ Sci & Engn, Dept Mat & Chem Engn, Zigong 643000, Sichuan, Peoples R China
              [ 2 ] China Rubber Grp Carbon Black Ind Res, Zigong 643000, Sichuan, Peoples R China
              [ 3 ] Design Inst, Zigong 643000, Sichuan, Peoples R China
电子邮件地址:wuhangzs@163.com

基金资助致谢
基金资助机构显示详情        授权号
National Natural Science Foundation of China

51072125
Scientific and Technical Project of Sichuan Province        
2013JQ0024
2013JY0124
Breeding Project of Sichuan University of Science and Engineering        
2011PY06
查看基金资助信息   
出版商
ELSEVIER, RADARWEG 29, 1043 NX AMSTERDAM, NETHERLANDS

类别 / 分类
研究方向:Chemistry; Materials Science; Physics

Web of Science 类别:Chemistry, Physical; Materials Science, Coatings & Films; Physics, Applied; Physics, Condensed Matter

文献信息
语言:English

入藏号: WOS:000346088500057

ISSN: 0169-4332

eISSN: 1873-5584

其他信息
IDS 号: AW1ZT

Web of Science 核心合集中的 "引用的参考文献": 26

Web of Science 核心合集中的 "被引频次": 6
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