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xinbingjing

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[交流] [b]求助[/b]：I离子和N-H之间形成氢键的键长是多少

请高手指教如果有参考文献给我发一个

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1楼2009-06-12 10:41:32

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xi2004

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在google中键如N-H...I
搜索一下吧,

文献很多,

如:

1. 作者: Lin Li Jia-Xiang Yang Hong-Ping Zhou 刊名: Inorganic Chemistry Communications 年,卷(期): 2007 Vol.10(no.2) 分类号: 关键词: Supramolecular chemistry Mercury(II) complex Crystal structure

2. A three-dimensional framework of bis[tris(ethylenediamine)zinc] tetra-iodocadmate diiodide assisted by N-H...I hydrogen bonds

References: 14 Times Cited: 0

Author(s):
Nesterova Oksana V Department of Inorganic Chemistry, National Taras Shevchenko University, Volodymyrska Street 64, Kie
Abstract:
The title salt, [Zn(C2N2H8)3]2[CdI4]I2, conventionally abbreviated [Zn(en)3]2[CdI4]l2, where en is ethylenediamine, contains discrete [Zn(en)3]2+ cations and [CdI4]2~ anions with distorted octahedral and nearly tetrahedral geometries, respectively, as well as uncoordinated I~ ions. The cation and the free I~ anion lie on twofold rotation axes and the [CdI4]2~ anion lies on a 4 axis in the space group I42d. The structure exhibits numerous weak inter-ionic hydrogen bonds of two types, viz- N-H...I~-(free ion) and N-H... I([CdI4]2~), which support the resulting three-dimensional framework.

Source:
Acta Crystallographica. Section C, Crystal Structure Communications , 2006, 62 (7) : P.m281-283

3. http://www.ncbi.nlm.nih.gov/pubmed/15640579

读这写文献, 再进一步找其他文献.