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sunxinli

[交流] 【求助】三氧化二铁的晶体结构求助

请问三氧化二铁是什么类型的晶体结构?另还有a-氧化铁、r-氧化铁和三氧化二铁的区别是什么?各自晶体结构和性质能否提供一些。谢谢
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queji

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At high pressure, it can transform to be amorphous .
7楼2009-06-16 20:45:24
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queji

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sunxinli(金币+1,VIP+0):谢谢 11-17 15:17
ferric oxide has Different forms:
Alpha phase,
Beta phase,
Gamma phase,
Epsilon phase,
and
amorphous phase.

[ Last edited by queji on 2009-6-16 at 20:47 ]
2楼2009-06-16 20:39:01
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queji

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sunxinli(金币+1,VIP+0):认真 11-17 15:17
Alpha phase
α-Fe2O3 has the rhombohedral, corundum (α-Al2O3) structure and is the most common form. It occurs naturally as the mineral hematite which is mined as the main ore of iron. It is antiferromagnetic below ~260 K (Morin transition temperature), and weak ferromagnetic between 260 K and 950 K (Neel temperature).[1] It is easy to prepare using both thermal decomposition and precipitation in the liquid phase. Its magnetic properties are dependent on many factors, e.g. pressure, particle size, and magnetic field intensity.

[ Last edited by queji on 2009-6-16 at 20:47 ]
3楼2009-06-16 20:39:41
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queji

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sunxinli(金币+1,VIP+0):认真 11-17 15:17
Beta phase
Cubic face centered, metastable, at temperatures above 500 °C converts to alpha phase. It can be prepared by reduction of hematite by carbon, pyrolysis of iron(III) chloride solution, or thermal decomposition of iron(III) sulfate.
4楼2009-06-16 20:40:58
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