|
|
★ ★ ★ ★
小木虫(金币+0.5):给个红包，谢谢回帖交流
纳米镍粉(金币+3,VIP+0):谢谢 10-13 07:06
名称：
吴新涛院士课题组（链接：http://www.fjirsm.ac.cn/yjxt/nmclyjs/wxt/ ）
简介：
本课题组成立于上世纪八十年代，课题组长是结构化学家吴新涛院士。在吴院士的指导下，课题组在含硫过渡金属原子簇、配位高聚物纳米材科和稀土-过渡金属-氨基酸原子簇化合物的控制组装与调控以及光、电、磁和吸咐等性能研究方面开展了系统性研究。目前，课题组的研究兴趣主要集中在纳米级高核原子簇化合物、金属-有机框架化合物以及其他金属有机小分子化合物的设计合成及其光、电、磁、吸附等性能的研究方面。吴新涛院士主编出版了英文版”无机组装化学”及”无机系统中的控制组装与调控”等两本书.
方向：
1． 纳米团簇的设计合成、结构调控及其性能研究
2． 半导体或荧光性质的纳米复合材料
3． 纳米分子磁性吸附分离材料
代表论文：
1.
A 3D Canted Antiferromagnetic Porous Metal-Organic Framework with Anatase Topology through Assembly of an Analogue of Polyoxometalate
Shengchang Xiang, Xintao Wu,* Jianjun Zhang, Ruibiao Fu, Shengmin Hu, and Xudong Zhang
J. Am. Chem. Soc., 2005, 127, 16352-16353
2.
Three new structural types of Mo/Ag/S polymeric complexes
Heng Yu, Wenjian Zhang, Xintao Wu*, Tianlu Sheng, Quanming Wang, and Ping Lin
Angew. Chem. Int. Ed. Engl., 1998, 37, 2520-2521
3.
Tetradecanuclear molybdenum (tungsten)/copper/sulfur heterobimetallic clusters [(nBu)4N]4[M4Cu10S16O2E]﹒H2O, (M = Mo, E = O; M = W, E = 1/2O + 1/2S)
Jun Guo, Xintao Wu*, Wenjian Zhang, Tianlu Sheng, Qun Huang, Ping Lin, Quanming Wang, and Jiaxi Lu
Angew. Chem. Int. Ed. Engl., 1997, 36, 2464-2466
4.
Heterometallic polymeric cluster compounds derived from tetrathiotungstate and silver(I): Syntheses and crystal structures of {[AgWS4]}n[NH4]n and {[W4Ag5S16]}n[M(DMF)8]n (M = Nd and La)
Qun Huang, Xintao Wu*, Quanming Wang, Tianlu Sheng, and Jiaxi Lu
Angew. Chem. Int. Ed. Engl., 1996, 35, No. 8, 868-870
5.
[Et4N]2[{MO(S2)2}2(m2-S7)(m2-H2NNH2)] (M = Mo, W)—Doubly Bridged Complexes with S72- and Doubly End-On-Bound H2NNH2 Bridging Ligands
Zhu Nianyong, Du Shaowu, Wu Xintao *, and Lu Jiaxi
Angew. Chem. Int. Ed. Engl., 1992, 31, No. 1, 87-88
6.
Synthesis of Cubane-like and Double Cubane-like Tungsten-Copper-Sulfur Clusters from the "Butterfly" Cluster Cu2S3W(O)(PPh3)3
Shaowu Du, Nianyong Zhu, Pengcheng Chen, Xintao Wu*
Angew. Chem. Int. Ed. Engl., 1992, 31, No. 8, 1085-1087
7.
Two 3D Supramolecular Polymers Constructed from an Amino Acid and a High-Nuclear Ln6Cu24 Cluster Node
Jian-Jun Zhang, Tian-Lu Sheng, Sheng-Min Hu, Sheng-Qing Xia, Guido Leibeling, Franc Meyer, Zhi-Yong Fu, Ling Chen, Rui-Biao Fu, Xin-Tao Wu
Chem. -Eur. J. 2004, 10, 3963-3969
8.
Synthesis and characterization of a series of novel heptanuclear trigonal prismatic polyhedra with different edge ligand.
Jian-Jun Zhang, Sheng-Min Hu, Li-Min Zheng, Xin-Tao Wu*, Zhi-Yong Fu, Jing-Cao Dai, Wen-Xin Du, Han-Hui Zhang, Rui-Qing Sun.
Chem.- Eur. J., 2002, 8, 5742-5749
9.
Assembled bright green fluorescent zinc coordination polymer
Ruibiao Fu, Shengchang Xiang, Shengmin Hu, Longsheng Wang, Yaming Li, Xihe Huang and Xintao Wu
Chem. Commun. 2005, 5292-5294
10.
A novel 2D net-like supramolecular polymer constructed from Ln6Cu24 node and trans-Cu(Gly)2 bridge
Jian-Jun Zhang, Sheng-Qing Xia, Tian-Lu Sheng, Sheng-Min Hu, Guido Leibeling, Franc Meyer, Xin-Tao Wu, Sheng-Chang Xiang Rui-Biao Fu
Chem. Commun., 2004, 1186-1187
11.
A novel ribbon-candy-like supramolecular architecture of cadmium(II)–terephthalate polymer with giant rhombic channels: twofold interpenetration of the 3D 8210-a net
Jing-Cao Dai, Xin-Tao Wu,* Zhi-Yong Fu, Sheng-Min Hu, Wen-Xin Du, Chuan-Peng Cui, Li-Ming Wu, Han-Hui Zhang and Rui-Qing Sun
Chem. Commun., 2002, 12-13
12.
Interpenetration in [Cd(isonicotinate)2(1,2-bis(4-pyridyl)ethane)0.5(H2O)]n, a novel octahedral polymer containing an unusual two-dimensional bilayer motif generated by self-assembly of rectangle building blocks
Zhi-Yong Fu , Xin-Tao Wu* , Jing-Cao Dai , Li-Ming Wu , Chuan-Peng Cui and Sheng-Min Hu
Chem. Commun., 2001, (18), 1856 - 1857
13.
Two new nickel-dmit-based molecular conductors based on heteroleptic polymetallic complexes: synthesis, structures and electrical properties
Tianlu Sheng, Xintao Wu*, Wenjian Zhang, Quanming Wang, Xiancheng Gao and Ping Lin
Chem. Commun., 1998, 263-264
14.
The novel heterometallic polymeric helical chain cluster {[W3Ag3S12]}n[Nd(Me2SO)8]n
Qun Huang, Xintao Wu* and Jiaxi Lu
Chem. Commun., 1997, 703-704
15.
Synthesis and characterization of the first dodecanuclear M-Ag-S cage cluster: [NEt4]2[{M2Ag2S2O2(S2C2H4)2}3(m6-S)].CH2Cl2.MeCN (M = Mo, W)
Ping Lin, Xintao Wu*, Wenjian Zhang, Jun Guo, Tianlu Sheng, Quanming Wang and Jiaxi Lu
Chem. Commun., 1997, 1349-1350
16.
The Synthesis and Characterizations of two Novel Heterometallic Trinuclear Incomplete Cubane-like Cluster [Et4N](M2AgS4)(S2C2H4)2-(PPh3)·CH2Cl2 (M = Mo, W)
Nianyong Zhu, Xintao Wu*, Jiaxi Lu
J. Chem. Soc., Chem. Commun., 1991, 235-237
17.
The Synthesis and Characterizations of Two Novel Cubane-like Clusters [M2Cu2S4(PPh3)2(SCH2CH2S)2] (M = Mo and W)
Nianyong Zhu, Yifan Zheng, Xintao Wu*
J. Chem. Soc., Chem. Commun., 1990, 780-781
18.
Assembly of a Heterometallic Polynuclear SnIV-CuI Cluster Based on Sn(edt)2 (edt = Ethane-1,2-dithiolate) as a Metalloligand
Xin Wang, Tian-Lu Sheng, Rui-Biao Fu, Sheng-Min Hu, Sheng-Chang Xiang, Long-Sheng Wang, and Xin-Tao Wu*
Inorg. Chem., 2006, 45, 5236-5238
19.
Rational Design of New Bright Luminescent Zinc Diphosphonates with 12-Member Ring Channels
Ruibiao Fu, Xihe Huang, Shengmin Hu, Shengchang Xiang, and Xintao Wu*
Inorg. Chem., 2006, 45, 5254-5256
20.
Two Chiral Metal Clusters Derived from Nucleophilic Addition of L-proline to Di-2-pyridyl Ketone
Yamin Li, Shengchang Xiang, Tianlu Sheng, Jianjun Zhang,* Shengmin Hu, Ruibiao Fu, Xihe Huang, and Xintao Wu*
Inorg. Chem., 2006, 45, 6577-6579
21.
Syntheses, structures and properties of high-nuclear 3d-4f clusters with amino acid as ligand: {Gd6Cu24}, {Tb6Cu26} and {(Ln6Cu24)2Cu} (Ln= Sm, Gd)
Jian-Jun Zhang, Sheng-Min Hu, Sheng-Chang Xiang, Tian-Lu Sheng, Xin-Tao Wu,* Ya-Min Li
Inorg. Chem., 2006, 45, 7173-7181
22.
Syntheses and Characterizations of a Series of Novel Ln6Cu24 Clusters with Amino Acids as Ligands
Jian-Jun Zhang, Tian-Lu Sheng, Sheng-Qin Xia, Guido Leibeling, Franc Meyer, Sheng-Min Hu, Rui-Biao Fu, Sheng-Chang Xiang, Xin-Tao Wu
Inorg. Chem., 2004, 43 5472-5478
23.
Synthesis, Structure, and Fluorescence of the Novel Cadmium(II)-Trimesate Coordination Polymers with Different Coordination Architectures
Jing-Cao Dai, Xin-Tao Wu*, Zhi-Yong Fu, Chuan-Peng Cui, Sheng-Min Hu, Wen-Xin Du, Li-Ming Wu, Han-Hui Zhang, and Rui-Qing Sun
Inorg. Chem. 2002, 41, 1391-1396
24.
Solids with Rhombic Channels: Syntheses and Crystal Structures of [Cu3(NTA)2(4,4￠-bpy)2(H2O)2]×9H2O and [{Cu(4,4'-bpy)(H2O)4}{Cu2(NTA)2(4,4'-bpy)}].7H2O (NTA = Nitrilotriacetate, 4,4'-bpy = 4,4'-Bipyridine)
Quanming Wang, Xintao Wu*, Wenjian Zhang, Tianlu Sheng, Ping Lin, and Jianmin Li
Inorg. Chem., 1999, 38, 2223-2226
25.
Syntheses and characterizations of a series of tetradecanuclear molybdenum(tungsten)/copper/sulfur heterobimetallic cluster compounds
Jun Guo, Tianlu Sheng, Wenjian Zhang, Xintao Wu*, Ping Lin, Quanming Wang, and Jiaxi Lu
Inorg. Chem., 1998, 37, 3689-3697
26.
Syntheses and characterizations of the novel dodecanuclear heterobimetallic cage clusters: [Et4N]2[(M2Cu2S2O2edt2)3(m6-S2)].CH2Cl2 (M = Mo, W; edt = -SC2H4S-)
Ping Lin, Xintao Wu*, Qun Huang, Quanming Wang, Tianlu Sheng, Wenjian Zhang, Jun Guo, Jiaxi Lu
Inorg. Chem., 1998, 37, 5672-5674
27.
Heterobimetallic clusters of Copper(I) with trithiotungstate and trithiomolybdate. Syntesis and Characterization of the octanuclear clusters [Et4N]4[M4Cu4S12O4] (M = Mo, W) and the docecanuclear clusters [M4Cu4S12O4(CuTMEN)4] (M = Mo, W; TMEN = N, N, N', N'-tetramethylethylenediamine)
Qun Huang, Xintao Wu*, Quanming Wang, Tianlu Sheng, and Jiaxi Lu
Inorg. Chem., 1996, 35, No. 4, 893-897
28.
The Heterobimetallic Polymeric Zigzag Chain [(W4S16Ag4)4-]n Derived from the Linear Chain [(WS4Ag)-]n: Synthesis, Characterization, and Structure of [W4S16Ag4·2Ca(DMSO)6]n (DMSO = Dimethyl Sulfoxide)
Qun Huang, Xintao Wu*, and Jiaxi Lu
Inorg. Chem., 1996, 35, 7445-7447
29.
Syntheses and crystal structures of two heterobimetallic polymeric cluster complexes [WS4Ag·NH3C(CH2OH)3·2DMF]n (single chain) and [WS4Ag·NH3C(CH2OH)3·H2O]n (double chain)
Qun Huang, Xintao Wu*, Tianlu Sheng and Quanming Wang
Inorg. Chem., 1995, 34, No. 20, 4931-4932
30.
Synthesis and Characterization of Two Novel Oxo-Persulfido Complexes with a Doubly Bridging S72- Ligand and an "End-to-End" Bridging Hydrazine Ligand: [Et4N]2[{MO(S2)2}2(m2-S7)(m2-H2NNH2)]·CH3CN (M = Mo, W)
Du Shaowu, Zhu Nianyong, Wu Xintao*, and Lu Jiaxi
Inorg. Chem., 1992, 31, 2847-2853
31.
Synthesis and Characterizations of Two Novel Heterometallic Trinuclear Incomplete Cubane-like Clusters [(CH3CH2)4N]{M2CuS4}(S2C2H4)2(PPh3) (M = Mo, W)
Nianyong Zhu, Yifan Zheng, Xintao Wu*
Inorg. Chem., 1990, 29, 2705-2707
32.
The syntheses and structures of two hexanuclear copper(II) complexes with amino acids
Shengmin Hu, Wenxin Du, Jingcao Dai, Liming Wu, Chuanpeng Cui, Zhiyong Fu, Xintao Wu*
J. Chem. Soc., Dalton Trans. 2001(20), 2963-2964
33.
The unconventional semiconductors represent two novel structure types of polythiometalates: syntheses, structures and electrical properties of {[W3Ag3S12]·[La(DMAC)5(H2O)3·(DMAC)4]}n and {[W8Ag10S32]·[M(DEF)8]2}n (M = La, Nd)
Ling Chen, Xin-tao Wu*, Xian-cheng Gao, Wen-jian Zhang and Ping Lin
J. Chem. Soc., Dalton Trans., 1999, 4303-4307
34.
Synthesis and structure of a helical polymer [Ag(R,R-DIOP)(NO3)]n {DIOP = (4R,5R)-trans-4,5-bis[(diphenylphosphino)methyl]-2,2-dimethyl-1,3- dioxalane}
Biao Wu, Wenjian Zhang, Shuyan Yu and Xintao Wu*
J. Chem. Soc., Dalton Trans., 1997, 1795-1796
35.
Synthesis and spectroscopy of unsymmetric mononuclear lanthanide cryptates. Structure of two europium(III) cryptates co-existing in the same crystal [EuL(OH2)]·[Eu(HL)(NCS)]·9H2O·2MeCN·EtCN·EtOH (H3L = a phenol-bridged N8O3 Shciff-base cryptand)
Shuyan Yu, Qun Huang, Biao Wu, Wenjian Zhang and Xintao Wu*
J. Chem. Soc., Dalton Trans., 1996, 3883-3888
36.
Synthesis, Characterization and Crystal Structure of the Heterotrimetallic Complexes [Net4][(Ph3P)2AgS2MoS2Cu(CN)] (Linear) and [Net4]-[(Ph3P)2AgS3MoOCu(CN)] (Butterfly)
Shaowu Du, Nianyong Zhu, Pengcheng Chen, Xintao Wu*, Jiaxi Lu
J. Chem. Soc., Dalton Trans., 1992, 1, 339-344
37.
Syntheses, Characterization, and Magnetic Properties of Four New Layered Transition-Metal Hydroxyl-Carboxylate-Phosphonates: [M(CH(OH)(CO2)(PO3H))(H2O)2] (M=Mn, Fe, Co, Zn)
Ruibiao Fu, Shengchang Xiang, Huishuang Zhang, Jianjun Zhang, and Xintao Wu*
Crystal Growth & Design, 2005, 5(5), 1795-1799
38.
A New Spherical Metallacryptate Compound [Naì{Cu6(Thr)8(H2O)2 (ClO4)4}]·ClO4·5H2O: Magnetic Properties and DFT Calculations
Sheng-Chang Xiang, Sheng-Min Hu, Jian-Jun Zhang, Xin-Tao Wu* and Jun-Qian Li
Eur. J. Inorg. Chem. 2005, 2706–2713
39.
Nonlinear Optical Activity and High Thermal Stability of a New 3D Open- Framework with Interconnected 24-, 16-, and 8-Atom Channels: (NH4)Zn[O3PCH(OH)CO2]
Ruibiao Fu, Huishuang Zhang, Longsheng Wang, Shengmin Hu, Yaming Li, Xihe Huang, and Xintao Wu*
Eur. J. Inorg. Chem. 2005, 3211–3213
40.
Crystal Engineering of the Coordination Architecture of Metal Polycarboxylate Complexes by Hydrothermal Synthesis: Assembly and Characterization of Four Novel Cadmium Polycarboxylate Coordination Polymers Based on Mixed Ligands
Jing-Cao Dai, Xin-Tao Wu, Sheng-Min Hu, Zhi-Yong Fu, Jian-Jun Zhang, Wen-Xin Du, Han-Hui Zhang, Rui-Qing Sun
Eur. J. Inorg. Chem. 2004, 2096-2106
41.
Self-Assembly of Organodiphosphonate, Polyoxomolybdate and Diphenanthrolinecobalt(II) into Two Clusters and One Linear Polymer
Rui-Biao Fu, Xin-Tao Wu,* Sheng-Min Hu, Jian-Jun Zhang, Zhi-Yong Fu, Wen-Xin Du, and Sheng-Qing Xia
Eur. J. Inorg. Chem. 2003, 1798-1801
42.
Three Novel Polymeric Frameworks Assembled from CdII ,CoII , and MnII with the Mixed Organic Ligands 3,4-Pyridinedicarboxylate, 1,3-Bis(4-pyridyl)propane, or 1,2-Bis(4-pyridyl)ethane
Zhi-Yong Fu, Sheng-Min Hu, Jing-Cao Dai, Jian-Jun Zhang, and Xin-Tao Wu*
Eur. J. Inorg. Chem. 2003, 2670-2677
43.
The Structure and Fluorescence Properties of Two Novel Mixed-Ligand Supramolecular Frameworks with Different Structural Motifs
Zhi-Yong Fu, Xin-Tao Wu*, Jing-Cao Dai, Sheng-Min Hu, Wen-Xin Du, Han-Hui Zhang, and Rui-Qing Sun
Eur. J. Inorg. Chem. 2002, 2730-2735
44.
Hydrothermal synthesis and crystal structure of two hetero-transition metal polymers:[Co(1,10-phen)2(V2O4)(O3PCH2CH2CH2PO3)]n and [{Co(1,10-phen)2}2(V4O10)(O3PCH2CH2CH2CH2PO3)(2H2O)]n
Rui-Biao Fu, Sheng-Min Hu, Zhi-Yong Fu, Jian-Jun Zhang and Xin-Tao Wu*
New J. Chem., 2003, 27, 230 –232
45.
A novel 2D bilayer architecture generated viap-p interactions and host–guest molecular recognition: assembly and structure of {[Cd(Htma)(bpy)(H2O)]·(H2tp)0.5·2H2O}n polymer (tma = trimesate, bpy = 4,4'-bipyridine, tp = terephthalate)
Jing-Cao Dai, Sheng-Min Hu, Xin-Tao Wu*, Zhi-Yong Fu, Wen-Xin Du, Han-Hui Zhang and Rui-Qing Sun
New J. Chem., 2003, 27(6), 914 - 918
46.
A novel mixed-ligand molecular bilayer generated by self-assembly of "T-shaped" moieties,displaying an unusual entanglement
Zhi-Yong Fu, Xin-Tao Wu*, Jing-Cao Dai, Sheng-Min Hu and Wen-Xin Du
New J. Chem., 2002, 26, 978 –980
[ Last edited by yanhualover on 2009-9-15 at 13:44 ] |
|
回复此楼
200+3