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Makoto FUJITA
★
小木虫(金币+0.5):给个红包，谢谢回帖交流
Makoto FUJITA
Professor
Department of Applied Chemistry,
The University of Tokyo
课题组链接：http://fujitalab.t.u-tokyo.ac.jp/index_e/
Profile
1980: B.S. Faculty of Engineering, Chiba University
1982: M.S. Graduate School of Engineering, Chiba University
1987: Ph.D.Tokyo Institute of Technology
1982-1987: Research Fellow at Sagami Chemical Research Center
1988-1991: Assistant Professor at Faculty of Engineering, Chiba University
1991-1994: Lecture at the same university
1994-1997: Associate Professor at the same university
1997-1999: Associate Professor at Institute of Molecular Science
1999-2002: Professor at Graduate School of Engineering, Nagoya University
2002-present: Professor at School of Engineering, The University of Tokyo
1997-present: Project Leader of CREST, Japan Science and Technology Corporation(JST)
Awards
1994: Progress Award in Synthetic Organic Chemistry, Japan
2000: Division Award of Chemical Society of Japan (Organic Chemistry)
2001: Tokyo Techno Forum 21 Gold Medal
2001: Japan IBM Award
2003: Nagoya Silver Medal
2003: Earl L. Muetterties Memorial Lecturers
2004: Izatt-Christensen Award
2006: G.W.Wheland Award (Chicago University Lectureship Award)
2007: Honorary Professor at Renmin University (China)
RESEARCH
Weak interactions induce the spontaneous organization of various biological structures. Such an elegant mechanism in nature has prompted us to design a nd establish self-assembling molecular systems. Thus, we have been showing that well-designed molecules are spontaneously organized into functional mol ecular systems.
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1. Self-assembling molecular systems utilizing transition metals: The simple combination of transition metal geometry with well-designed bridging ligands gives rise to the quantitative self-assembly of nano-sized, discrete organic frameworks. Representative examples include square molecules, linked-ring m olecules, cages, capsules, and tubes that are self-assembled from simple and small components.
2. Chemistry of isolated nano-space: The metal-directed self-assembly of nan o-meter sized frameworks gives us an opportunity to develop the chemistry of "isolated nano-space". For example, stabilization of labile molecules, spec ific chemical transformations, and the synthesis of labile molecules have be en achieved within the cavities of the self-assembled cages and capsules.
3. Coordination polymers: The metal-directed self-assembly has been also appl ied to the preparation of non-covalent polymers with well-defined structures and interesting properties.
publication
2010
"Engineering Double to Quintuple Stacks of a Polarized Aromatic in Confined Cavities"
Y. Yamauchi, M. Yoshizawa, M. Akita, M. Fujita
J. Am. Chem. Soc. 2010, 132, in press. []
"Template synthesis of precisely monodisperse silica nanoparticles within self-assembled organometallic spheres"
K. Suzuki, S. Sato, and M. Fujita
Nature Chem. 2010, 2, 25-29. [10.1038/nchem.446]
2009
"Conformational Preferences of Short Peptide Fragments"
Y. Hatakeyama, T. Sawada, M. Kawano, and M. Fujita
Angew. Chem. Int. Ed. 2009, in press. [10.1002/anie.200903563]
"ON/OFF Red Emission from Azaporphine in a Coordination Cage in Water"
K. Ono, J. K. Klosterman, M. Yoshizawa, K. Sekiguchi, T. Tahara, and M. Fujita
J. Am. Chem. Soc. 2009, 131, 12526–12527. [10.1021/ja904875y]
"Energy Transfer in a Mechanically Trapped Exciplex"
J. K. Klosterman, M. Iwamura, T. Tahara, and M. Fujita
J. Am. Chem. Soc. 2009, 131, 9478–9479. [10.1021/ja901674g]
"Switchable trans-cis interconversion of an amphiphilic anthracene trimer"
J. Iwasa, K. Ono, M. Fujita, M. Yoshizawa, and M. Akita
Chem. Commun. 2009, 5746-5748. [10.1039/b912365b]
"X-ray observation of a transient hemiaminal trapped in a porous network"
T. Kawamichi, T. Haneda, M. Kawano, and M. Fujita
Nature 2009, 461, 633-635. [10.1038/nature08326]
"Engineering Non-Covalent Spin-Spin Interactions in an Organic-Pillared Spin Cage"
Y. Ozaki, M. Kawano, and M. Fujita
Chem. Commun. 2009, 4245-4247. [10.1039/b906674h]
"Fluorous Pores in Coordination Networks"
M. Jang, T. Yamaguchi, K. Ohara, M. Kawano, and M. Fujita
Chem. Asian J. 2009, 4, 1524-1526. [10.1002/asia.200900293]
"Engineering discrete stacks of aromatic molecules"
J. K. Klosterman, Y. Yamauchi, and M. Fujita
Chem. Soc. Rev. 2009, 38, 1714–1725. [10.1039/b901261n]
"Remarkable Stabilization of M12L24 Spherical Frameworks through the Cooperation of 48 Pd(II)-Pyridine Interactions"
S. Sato, Y. Ishido, and M. Fujita
J. Am. Chem. Soc. 2009, 131, 6064–6065. [10.1021/ja900676f]
"Discrete stack of an odd number of polarized aromatic compounds: the importance of net vs. local dipoles"
Y. Yamauchi, M. Yoshizawa, M. Akita, and M. Fujita
Proc. Nat. Acad. Sci. USA. 2009, 106, 10435-10437. [10.1073/pnas.0810319106]
"In situ Spectroscopic, Electrochemical, and Theoretical Studies on the Photoinduced Host-Guest Electron Transfer that Precedes Unusual Host-mediated Alkane Photooxidation"
Y. Furutani, H. Kandori, M. Kawano, K. Nakabayashi, M. Yoshizawa, and M. Fujita
J. Am. Chem. Soc. 2009, 131, 4764–4768. [10.1021/ja8089075]
"Formation of a Thermally Stable, Porous Coordination Network via Crystalline-to-Amorphous-to-Crystalline Phase Transitions"
K. Ohara, J. Martí-Rujas, T. Haneda, M. Kawano, D. Hashizume, F. Izumi, and M. Fujita
J. Am. Chem. Soc. 2009, 131, 3860–3861. [10.1021/ja9005145]
"Photo-Induced Self-Assembly of Pt(II)-Linked Rings and Cages via the Photolabilization of a Pt(II)－py Bond"
K. Yamashita, K. Sato, M. Kawano, and M. Fujita
New J. Chem. 2009, 33, 264-270. [10.1039/b817713a]
"Self-assembly of a M6L12 coordination cube"
K. Suzuki, M. Tominaga, M. Kawano, and M. Fujita
Chem. Commun. 2009, 1638-1640. [10.1039/b822311d]
"Functional Molecular Flasks: New Properties and Reactions within Discrete, Self-Assembled Hosts"
M. Yoshizawa, J. K. Klosterman, and M. Fujita
Angew. Chem. Int . Ed. 2009, 48, 3418-3438. [10.1002/anie.200805340]
"Minimal Nucleotide Duplex Formation in Water through Enclathration in Self-Assembled Hosts"
T. Sawada, M. Yoshizawa, S. Sato, and M. Fujita
Nature Chem. 2009, 1, 53-56. [10.1038/nchem.100]
"Spin Crossover by Encapsulation"
K. Ono, M. Yoshizawa, M. Akita, T. Kato, Y. Tsunobuchi, S. Ohkoshi, and M. Fujita
J. Am. Chem. Soc. 2009, 131, 2782–2783. [10.1021/ja8089894]
2008
"Single-Crystalline Molecular Flasks: Chemical Transformation with Bulky Reagents in the Pores of Porous Coordination Networks"
T. Kawamichi, T. Kodama, M. Kawano, and M. Fujita
Angew. Chem. Int. Ed. 2008, 47, 8030-8032. [10.1002/anie.200802545]
"Discrete and Well-Defined Hydrophobic Phases Confined in Self-Assembled Spherical Complexes"
K. Suzuki, J. Iida, S. Sato, M. Kawano, and M. Fujita
Angew. Chem. Int. Ed. 2008, 47, 5780-5782. [10.1002/anie.200801700]
"Asymmetric [2+2] Olefin Cross Photoaddition in a Self-assembled Host with Remote Chiral Auxiliaries"
Y. Nishioka, T. Yamaguchi, M. Kawano, and M. Fujita
J. Am. Chem. Soc. 2008, 130, 8160–8161. [10.1021/ja802818t]
"A Selective Instant Synthesis of a Coordination Network and its ab initio Powder Structure Determination"
M. Kawano, T. Haneda, D. Hashizume, and M. Fujita
Angew. Chem. Int. Ed. 2008, 47, 1269-1271. [10.1002/anie.200704809]
"Direct Observation of the Labile Imine Formation through Single-Crystal-to-Single-Crystal Reactions in the Pores of a Porous Coordination Network"
T. Haneda, M. Kawano, T. Kawamichi, and M. Fujita
J. Am. Chem. Soc. 2008, 130, 1578-1579. [10.1021/ja7111564]
"Polymerisation of an Anionic Monomer in a Self-Assembled M12L24 Coordination Sphere with Cationic Interior"
T. Kikuchi, T. Murase, S. Sato, and M. Fujita
Supramol. Chem. 2008, 20, 81-94. [10.1080/10610270701742579]
"Highly Selective Photomediated 1,4-Radical Addition to o-Quinones Controlled by a Self-Assembled Cage"
T. Yamaguchi and M. Fujita
Angew. Chem. Int. Ed. 2008, 47, 2067-2069. [10.1002/anie.200705139]
"A Self-Assembled Spin Cage"
K. Nakabayashi, Y. Ozaki, M. Kawano, and M. Fujita
Angew. Chem. Int. Ed. 2008, 47, 2046-2048. [10.1002/anie.200704924]
"Three-Metal-Center Spin Interactions through the Intercalation of Metal Azaporphines and Porphines into an Organic Pillared Coordination Box"
K. Ono, M. Yoshizawa, T. Kato, and M. Fujita
Chem. Commun. 2008, 2328-2330. [10.1039/b801701h]
"Engineering Stacks of Aromatic Rings by the Interpenetration of Self-Assembled Coordination Cages"
Y. Yamauchi, M. Yoshizawa, and M. Fujita
J. Am. Chem. Soc. 2008, 130, 5832–5833. [10.1021/ja077783+] |
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