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Study on Aqueous Solution of Ammonium Nitrate
Hot Safety Test System
Abstract
In general, ammonium nitrate is stable and safe, but with temperature increasing, as well as impurities participation, ammonium nitrate will decompose and release heat, resulting in the burning or explosion. In view of the ammonium nitrate risk, a great deal of researches has been done at home and abroad. However, studies on the critical detonation temperature rarely can be seen.
In this paper, thermal explosion theory is applied to study the thermal safety of ammonium nitrate in aqueous solution, and design a set of detonation temperature test. The whole is divided into two parts. The first part is the design of explosive vessel which is mainly used to test the critical explosion temperature of aqueous solution of ammonium nitrate. The second part is the design of the test device. Guided by design theory of dynamics in the explosion and relevant theories, according to the theory that largest vessel charged with 10ml80% aqueous solution of ammonium nitrate is almost 5gTNT equivalent, and the actual use conditions for vessel volume of ¦µ23mm ¡Á 57mm, then the relevant formula is used to calculate the incident shock wave pressure and Equivalent static load of 36.9 MPa of the vessel is arrived at. On the basis of the above data, the explosive vessel wall thickness calculations, stress analysis, strength check as well as the design and calculations of discharge bursting disc device are all carried out. Determined by the calculations, the explosive vessel wall thickness is 20mm, the design pressure 40MPa, the flange thickness 22mm, head thickness 26mm, bolt diameter 6mm, and the burst pressure of rupture disc 39.6 MPa. On the basis of these calculated explosive vessel data, the heat set size of ¦µ170mm ¡Á 140mm can be drawn, security box. E-type thermocouple and TD7¡ªRB10temperature controller are selected in accordance with experimental conditions.
Processing map will be drawn by AUTOCAD and airtight checks will be carried out until good gastight device is attained. 10ml80% aqueous solution of ammonium nitrate will be added to debugged device to measure the temperature of thermal explosion. Many occasions on 10ml80% aqueous solution of ammonium nitrate come to the determination of the explosive temperature 239-241 ¡æ. If a certain amount of Cl-concentration and nitrate is dropwise added to 10ml80% aqueous solution of ammonium nitrate, explosive changes in temperature. In this paper, the explosive temperature of aqueous solution of ammonium nitrate is very close to decomposition characteristics of ammonium nitrate at temperature of 210 ~ 260 ¡æ that Saunders studied.
It can be seen in this paper that the hot safety test system of ammonium nitrate in aqueous solution can be used for scientific experiments. This test system can not only be used to study the hot safety test system of ammonium nitrate in aqueous solution, at the same time it is with an important practical value in safe production of fertilizers.

Key word:  Ammonium nitrate, Thermal explosion theory, Explosives vessel, Strength checks.

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ÒÑÔÄ   ¹Ø×¢TA ¸øTA·¢ÏûÏ¢ ËÍTAºì»¨ TAµÄ»ØÌû

conanthird

½ð³æ (ÖøÃûдÊÖ)

¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï
515825903931(½ð±Ò+25,VIP+0): 5-27 17:54
(Studies/ A study) on Aqueous Solution of Ammonium Nitrate
Hot Safety Test System
Abstract
In general, ammonium nitrate is stable and safe, but with temperature increasing, as well as impurities participation, ammonium nitrate will decompose and release heat, (Which results in)resulting in the burning or explosion. In view of the ammonium nitrate risk, a great deal of (research)researches has been done at home and abroad. However, studies on the critical detonation temperature(have been rarely reported) .
In this paper, thermal explosion theory is applied to study the thermal safety of ammonium nitrate in aqueous solution, and design a set of detonation temperature test. The whole (research) is divided into two parts. The first part is the design of explosive vessel which is mainly used to test the critical explosion temperature of aqueous solution of ammonium nitrate .The second part is the design of the test device. Guided by design theory of dynamics in the explosion and relevant theories(, )according to the theory that largest vessel charged with 10ml80% aqueous solution of ammonium nitrate is almost 5gTNT equivalent, and the actual use conditions for vessel volume of ¦µ23mm ¡Á 57mm, then the relevant formula is used to calculate the incident shock wave pressure and Equivalent static load of 36.9 MPa of the vessel is arrived at. On the basis of the above data, the explosive vessel wall thickness calculations, stress analysis, strength check as well as the design and calculations of discharge bursting disc device are all carried out. (Via calculating, several parameters were acuquried as showed below,)the explosive vessel wall thickness is 20mm, the design pressure 40MPa, the flange thickness 22mm, head thickness 26mm, bolt diameter 6mm, and the burst pressure of rupture disc 39.6 MPa. On the basis of these calculated explosive vessel data, the heat set size of ¦µ170mm ¡Á 140mm can be drawn, security box. E-type thermocouple and TD7¡ªRB10temperature controller are selected in accordance with experimental conditions.
Processing map will be drawn by AUTOCAD and airtight checks will be carried out until good gastight device is attained. 10ml80% aqueous solution of ammonium nitrate will be added to debugged device to measure the temperature of thermal explosion. Many occasions on 10ml80% aqueous solution of ammonium nitrate come to the determination of the explosive temperature 239-241 ¡æ. If a certain amount of Cl-concentration and nitrate is  added to 10ml80% aqueous solution of ammonium nitrate(dropwisely), explosive changes in temperature. In this paper, the explosive temperature of aqueous solution of ammonium nitrate is very close to decomposition characteristics of ammonium nitrate at temperature of 210 ~ 260 ¡æ (which had been done by Saunders and colleges).
It can be seen(here)that the hot safety test system of ammonium nitrate in aqueous solution can be used for scientific experiments. This test system can not only be used (for the study )the hot safety test system of ammonium nitrate in aqueous solution, (but also of  important practical value ) in safe production of fertilizers.
2Â¥2009-05-27 00:30:44
ÒÑÔÄ   ¹Ø×¢TA ¸øTA·¢ÏûÏ¢ ËÍTAºì»¨ TAµÄ»ØÌû

conanthird

½ð³æ (ÖøÃûдÊÖ)

¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï
515825903931(½ð±Ò+25,VIP+0): 5-27 17:55
Please check the parts within the brackets.
Good Luck.
3Â¥2009-05-27 00:32:01
ÒÑÔÄ   ¹Ø×¢TA ¸øTA·¢ÏûÏ¢ ËÍTAºì»¨ TAµÄ»ØÌû

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