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huahua1211

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［128］ Rychcik M, Skyllas-Kazacos M. Evaluation of electrode materials for all-vanadium redox flow cell [J]. Journal of Power Sources, 1987, 19:45-54
［129］ Skyllas-Kazacos M. All-vanadium redox battery with additives [P]. Australia Patent: PCT/AU 8800472, 1988-10-05

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winter2002

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Title: ALL-VANADIUM REDOX BATTERY AND ADDITIVES

Abstract: An all-vanadium redox battery having a catholyte and an anolyte, a positive carbon electrode and a negative carbon electrode and which includes stabilizing/kinetic enhancing ions in the catholyte and hydrogen inhibiting ions in the anolyte is disclosed. The positive carbon electrode in this battery can be impregnated with Au, Mn, Pt, Ir, Ru, Os, Re, Rh, Sb, Te, Pb and/or Ag. The negative carbon electrode in this battery can be impregnated with Pb, Bi, Tl, Hg, Cd, In, Ag, Be, Ga, Sb, As, Zn, Ca and/or Mg. Also disclosed is an all-vanadium redox battery having a catholyte and an anolyte, a positive carbon electrode and a negative carbon electrode wherein the positive carbone electrode in this battery is impregnated with Au, Mn, Pt, Ir, Ru, Os, Re, Rh, Sb, Te, Pb and/or Ag and the negative carbon electrode is impregnated with Pb, Bi, Tl, Hg, Cd, In, Ag, Be, Ga, Sb, As, Zn, Ca and/or Mg. An all-vanadium redox battery having a catholyte and an anolyte, a positive carbon electrode and a negative carbon electrode wherein the positive carbon electrode in this battery is impregnated with Au, Mn, Pt, Ir, Ru, Os, Re, Rh, Sb, Te, Pb and/or Ag and the anolyte contains hydrogen inhibiting ions is also disclosed. Additionally, an all-vanadium redox battery having a catholyte and an anolyte, a positive carbon electrode and a negative carbon electrode and which includes stabilizing/kinetic enhancing ions in the catholyte and wherein the negative carbon electrode is impregnated with Pb, Bi, Tl, Hg, Cd, In, Ag, Be, Ga, Sb, As, Zn, Ca and/or Mg is disclosed.