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Çë°ïÖú²éѯEIÎÄÕµÄÊÕ¼Â룺£¨1£©Preparation of NiWO4/g-C3N4 and its ultra-deep desulfurization properties in ionic liquid¡£
AUTHORS:
ÀîÐãÆ¼
ÕÔÈÙÏé
ÐÏÅô·É
LI Xiu-ping
ZHAO Rong-xiang
XING Peng-fei
SOURCE:
ȼÁÏ»¯Ñ§Ñ§±¨ / Journal of Fuel Chemistry and Technology. 45(11):1340-1348
PUBLICATION DATE:
2017-01-01
LANGUAGE:
Chinese and English
£¨2£©Preparation of NiWO4 Catalyst and Its Application in the Oxidation Desulfurization of Model Oil¡£
AUTHORS:
Xing, Pengfei (1); Shi, Weiwei (1); Li, Xiuping (2); Zhao, Rongxiang (1)
Source: Shiyou Xuebao, Shiyou Jiagong/Acta Petrolei Sinica (Petroleum Processing Section), v 33, n 2, p 334-341,
March 25, 2017; Language: Chinese; ISSN: 10018719; DOI: 10.3969/j.issn.1001-8719.2017.02.019; Publisher:
Science Press

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Accession number: 20180604769956


Preparation of NiWO4/g-C3N4and its ultra-deep desulfurization properties in ionic liquid
Accession number: 20180604769956
Authors: Li, Xiu-Ping 1 ; Zhao, Rong-Xiang 2   ; Xing, Peng-Fei 2
Author affiliations : 1 School of chemistry and Materials Science, College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning University of Petroleum & Chemical Technology, Fushun; 113001, China
2 School of Petrochemical Engineering, College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning University of Petroleum & Chemical Technology, Fushun; 113001, China
Corresponding author: Zhao, Rong-Xiang (zylhzrx@126.com)
Source title: Ranliao Huaxue Xuebao/Journal of Fuel Chemistry and Technology
Abbreviated source title: Ranliao Huaxue Xuebao J. Fuel Chem. Technol.
Volume: 45
Issue: 11
Issue date: November 1, 2017
Publication Year: 2017
Pages: 1340-1348
Language: Chinese
ISSN: 02532409
CODEN: RHXUD8
Document type: Journal article (JA)
Publisher: Science Press
Abstract: The NiWO4nanoparticles were synthesized by hydrothermal method. The supported catalysts NiWO4/g-C3N4were prepared by a simple mixing-calcination method. XRD, FT-IR, EDS, SEM, BET and XPS were used to characterize the morphology and structure of NiWO4/g-C3N4. The prepared NiWO4/g-C3N4was used as catalyst, hydrogen peroxide as oxidant, 1-butyl-3-methylimidazolium tetrafluoroborate ionic liquid ([BMIM]BF4) as extractant for oxidative desulfurization. The effects of catalyst loading, the amount of hydrogen peroxide, ionic liquid and catalyst, reaction temperature, reaction time, and different sulfur compounds on desulfurization efficiency were studied. The desulfurization rate can reach 97.35% at the optimum reaction conditions: 5 mL of model oil, 0.2 mL of hydrogen peroxide, 1.0 mL of [BMIM] BF4, 0.03 g of NiWO4/g-C3N4, 80¡æ of reaction temperature and 140 min of reaction time. The results showed that NiWO4/g-C3N4had good catalytic stability, and the catalytic activity was not significantly reduced after 5 repeated reactions.
© 2017, Science Press. All right reserved.
Number of references: 45
Main heading: Nickel compounds
Controlled terms: Catalyst activity -  Desulfurization -  Hydrogen peroxide -  Ionic liquids -  Oxidation -  Peroxides -  Sulfur compounds -  Synthesis (chemical)
Uncontrolled terms: 1-Butyl-3-methylimidazolium tetrafluoroborate -  Desulfurization efficiency -  Dibenzothiophenes -  Hydrothermal methods -  Morphology and structures -  NiWO4/g-C3N4 -  Optimum reaction conditions -  Oxidative desulfurization
Classification code: 802.2Chemical Reactions  -  804Chemical Products Generally  -  804.2Inorganic Compounds
Numerical data indexing: Mass 3.00e-05kg, Percentage 9.73e+01%, Time 8.40e+03s, Volume 1.00e-06m3, Volume 2.00e-07m3, Volume 5.00e-06m3
Database: Compendex
Compilation and indexing terms, © 2018 Elsevier Inc.
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zylhzrx: ½ð±Ò+10, ¡ï¡ï¡ï¡ï¡ï×î¼Ñ´ð°¸ 2018-10-12 07:33:24
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Accession number: 20173604119644

Preparation of NiWO4Catalyst and Its Application in the Oxidation Desulfurization of Model Oil
Accession number: 20173604119644
Authors: Xing, Pengfei 1 ; Shi, Weiwei 1 ; Li, Xiuping 2 ; Zhao, Rongxiang 1  
Author affiliations : 1 College of Petrochemical Engineering, Liaoning University of Petroleum & Chemical Technology, Fushun; 113001, China
2 College of Chemistry & Material Science Engineering, Liaoning University of Petroleum & Chemical Technology, Fushun; 113001, China
Corresponding author: Zhao, Rongxiang (zylhzrx@126.com)
Source title: Shiyou Xuebao, Shiyou Jiagong/Acta Petrolei Sinica (Petroleum Processing Section)
Abbreviated source title: Shiyou Xuebao Shiyou Jiagong
Volume: 33
Issue: 2
Issue date: March 25, 2017
Publication Year: 2017
Pages: 334-341
Language: Chinese
ISSN: 10018719
CODEN: SXSHEY
Document type: Journal article (JA)
Publisher: Science Press
Abstract: The water-insoluble NiWO4nanoparticles were successfully prepared by hydrothermal method. The morphology and structure characteristics of the prepared NiWO4were characterized by XRD, SEM, EDS and BET. The oxidative desulfurization of model oil containing DBT was carried out with NiWO4as catalyst, H2O2as oxidant agent and 1-ethyl-3-methylimidazolium ethylsulfate ([EMIM][EtSO4]) as extractant. The influences of the different oxidative desulfurization system, the amount of H2O2, NiWO4and [EMIM][EtSO4], temperature on the desulfurization rate were investigated. The oxidative desulfurization of different kinds of sulfur-containing compounds in this oxidative desulfurization system was also discussed. The results showed that NiWO4possessed excellent desulfurization activity under mild operative conditions. Under the optimal reaction conditions, which were V(Oil)=5.00 mL, V(H2O2)=0.20 mL, V(ILs)=0.50 mL, m(NiWO4)=0.01 g, T=80¡æ and t=160 min, the desulfurization rate for DBT reached 98.46%. NiWO4could be recycle used at least ten times without any clearly decrease in catalytic activity. In addition,the reaction mechanism of the oxidative desulfurization was investigated.
© 2017, Editorial Office of Acta Petrolei Sinica(Petroleum Processing Section). All right reserved.
Number of references: 32
Main heading: Nickel compounds
Controlled terms: Catalyst activity -  Desulfurization -  Hydrogen peroxide -  Ionic liquids -  Sulfur compounds
Uncontrolled terms: Desulfurization rate -  Dibenzothiophenes -  Hydrothermal methods -  Morphology and structures -  NiWO4 -  Optimal reaction condition -  Oxidative desulfurization -  Sulfur containing compound
Classification code: 804Chemical Products Generally  -  804.2Inorganic Compounds
Numerical data indexing: Percentage 9.85e+01%
DOI: 10.3969/j.issn.1001-8719.2017.02.019
Database: Compendex
Compilation and indexing terms, © 2018 Elsevier Inc.
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