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4. Heavy Metal Test
The heavy metal test is a technique to determine whether a sample releases an amount of heavy metals that exceeds the allowable maximum. For the purposes of this test, ¡°heavy metal¡± refers to metallic substances that exhibit a dark color when exposed to the acidity of a sodium sulfide
reagent. The quantity is indicated as the quantity of lead (Pb).
Procedure
Place 20 ml of sample solution in a Nessler tube, and to this add enough water to bring the total volume to 50 ml. In a separate Nessler tube, place 2 ml of lead standard solution (for heavymetal testing) and 20 ml of leaching solution and enough water to bring the total volume to 50 ml; this is the control solution. To both solutions add two drops each of sodium sulfide reagentand leave for 5 minutes, then view both Nessler tubes from the top and sides against a white background. The sample solution should not appear darker in color than the control solution. If the leaching solution used is water, add 5 ml of 4% acetic acid to the sample solution and the
lead standard solution, then add enough water to bring the total volume to 50 ml.
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