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风过留音m新虫 (小有名气)
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作者: Peng Yang, Junxiao Yang and Guanjun Chang 文题: A Metal Coordination Crosslinking Novel High Performance Thermoset 期刊名: Materials Science Forum 期刊年份: Vol. 913，2018 卷(期),起止页码: 746-751 Doi: https://doi.org/10.4028/www.scientific.net/MSF.913.746@阿努 |
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A metal coordination crosslinking novel high performance thermoset Accession number: 20181104912224 Authors: Yang, Peng 1 ; Yang, Jun Xiao 1 ; Chang, Guan Jun 1 Author affiliation : 1 State Key Laboratory Cultivation Base for Nonmetal Composite and Functional Materials, School of Material Science and Engineering, Southwest University of Science and Technology, Mianyang; 621010, China Corresponding author: Chang, Guan Jun (gjchang@mail.ustc.edu.cn) Source title: Materials Science Forum Abbreviated source title: Mater. Sci. Forum Volume: 913 Part number: 1 of 1 Issue title: Functional and Functionally Structured Materials II - Chinese Materials Conference 2017, CMC 2017 Issue date: 2018 Publication Year: 2018 Pages: 746-751 Language: English ISSN: 02555476 CODEN: MSFOEP ISBN-13: 9783035712445 Document type: Conference article (CA) Conference name: Chinese Materials Conference, CMC 2017 Conference date: July 6, 2018 - July 12, 2018 Conference location: Yinchuan City, Ningxia, China Conference code: 211579 Sponsor: Chinese Materials Research Society (CMRS) Publisher: Trans Tech Publications Ltd Abstract: N-substituted crosslinking polybenzimidazole pyridine sulfone, as novel high performance functional polymers, was prepared by the coordination of N-substituted polybenzimidazole pyridine sulfone (Py-N-PBIS) ligand with varying content of metallic ion (Co2+, Ni2+, Zn2+). The structures of the polymers were characterized by means of FT-IR and1H NMR spectroscopy, and the results showed a good agreement with the proposed structures. TGA measurements exhibited that the crosslinking polymers possessed good thermal stability with high thermal decomposition temperatures (thermally stable up to 405-510 °C). Additionally, the thermal stability of the coordination polymers was improved constantly with the increasing of the content of Co2+, Ni2+or Zn2+. The metal coordination crosslinking N-substituted polybenzimidazole pyridine sulfone could be considered as a novel high performance thermoset. © 2018 Trans Tech Publications, Switzerland. Number of references: 18 Main heading: Crosslinking Controlled terms: Decomposition - Nuclear magnetic resonance spectroscopy - Pyridine - Substitution reactions - Thermodynamic stability - Thermosets Uncontrolled terms: 1H NMR spectroscopy - Coordination Polymers - Cross-linking polymers - High-performance thermosets - Metal coordination - Metallic ions - Polybenzimidazole - Thermally stable Classification code: 641.1Thermodynamics - 802.2Chemical Reactions - 804.1Organic Compounds - 815.1.1Organic Polymers Numerical data indexing: Temperature 6.78e+02K to 7.83e+02K DOI: 10.4028/www.scientific.net/MSF.913.746 Funding Details: Number; Acronym; Sponsor: 11447215; NSFC; National Natural Science Foundation of China Number; Acronym; Sponsor: 21202134; NSFC; National Natural Science Foundation of China Number; Acronym; Sponsor: 21504073; NSFC; National Natural Science Foundation of China Funding text: This work was financially supported by the National Natural Science Foundation of China (21504073, 21202134, 11447215), the National Engineering Technology Center for Insulation Materials, Southwest University of Science and Technology (16kfjc08), the Sichuan Youth Science & Technology Foundation (2016JQ0055), the Open Project of State Key Laboratory Cultivation Base for Nonmetal Composites and Functional Materials (11zxfk26). Database: Compendex Compilation and indexing terms, © 2018 Elsevier Inc. |
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