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zhsj1112

铜虫 (小有名气)

应助: 0 (幼儿园)
金币: 99.3
帖子: 91
在线: 54.2小时
虫号: 1906138
注册: 2012-07-23
专业: 无机纳米化学

[求助] birnessite晶体解析！

最近投了一篇稿子，这已经是第三轮大修了。详细审稿意见如下。
(2) Structure birnessites.
I appreciate a thorough literature review on the crystallography of the birnessite. However, the structure and composition of birnessite strongly depends on the synthesis conditions, especially in case of the substrate-directed growth presented in this manuscript. Therefore, it absolutely necessary to perform structure refinement in this case. The explanation provided by the Authors can be true, but if not supported by experimental refinement cannot be accepted. Without the experimental structure refinement, the Authors need to remove their strong statements related to the positions ofMn(III) and ions between the layers. This however will also impact the conclusions made by the Authors.
本人做了一个beta-MnO2上面生长birnessite的复合物。因为进行了试验条件的调控，birnessite里面的Mn3+含量有所提高。第二轮审稿意见追问提高的Mn3+在什么位置。所以查找相关文献加以说明！可是审稿人并不信服，要求做structure refinement！本人在这方面完全没有接触过，看了一些资料，完全超出能够理解的范围，现求助：

（1）可否在beta-MnO2上面生长birnessite的复合物做structure refinement？beta-MnO2和birnessite都已确定为单晶
（2）如果可以做，我需要采集哪些数据。确认birnessite里面Mn3+和Mn4+的位置
（3）求助帮忙做structure refinement大神，金币不多。其他方式答谢亦可！

这段时间急死了，吃不好，睡不着。希望能得到大神的帮助！

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