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Low-temperature synthesis and characterization of helical carbon fibers by one-step chemical vapour deposition. Applied Surface Science. 2015, 324: 438-442.

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±êÌâ: Low-temperature synthesis and characterization of helical carbon fibers by one-step chemical vapour deposition
×÷Õß: Jin, YZ (Jin, Yongzhong); Chen, J (Chen, Jian); Fu, QS (Fu, Qingshan); Li, BH (Li, Binghong); Zhang, HZ (Zhang, Huazhi); Gong, Y (Gong, Yong)
À´Ô´³ö°æÎï: APPLIED SURFACE SCIENCE  ¾í: 324  Ò³: 438-442  DOI: 10.1016/j.apsusc.2014.10.107  ³ö°æÄê: JAN 1 2015  
ÕªÒª: Helical carbon fibers (HCNFs) were synthesized by one-step chemical vapour deposition using cupric tartrate as a catalyst at temperature below 500 degrees C. The bound rubber of natural rubber (NR)/HCNFs were also prepared in this study. The results of thermogravimetry-differential scanning calorimetry (TG/DSC) for cupric tartrate nanoparticles show that the transformation of C4H4CuO6 -> Cu reaction occurs at similar to 250-310 degrees C. The characterization of scanning electron microscopy (SEM), transmission electron microscope (TEM), X-ray diffraction (XRD) and Raman spectrum for the synthesized products confirms that the synthesis of HCNFs is highly temperature-dependent. The straight fibers with the fiber diameter of 100-400 nm are obtained at 280 degrees C and HCNFs can be synthesized at higher temperature, with the coil diameter of 0.5-1 mu m and fiber diameter of 100-200 nm at 380 degrees C, and the coil diameter of 100 nm and fiber diameter of similar to 80 nm at 480 degrees C. The maximum of the bound-rubber content (37%) can be obtained with the addition of similar to 100 wt.% HCNFs in NR, which indicates that the coiled configuration of HCNFs makes a noticeable contribution to the reinforcement of NR/CB system. (C) 2014 Elsevier B.V. All rights reserved.
Èë²ØºÅ: WOS:000346088500057
ISSN: 0169-4332
eISSN: 1873-5584
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Ðľ²_ÒÀÈ»: LS-EPI+1, ¸ÐлӦÖú 2017-09-04 08:58:34
Low-temperature synthesis and characterization of helical carbon fibers by one-step chemical vapour deposition
×÷Õß:Jin, YZ (Jin, Yongzhong)[ 1 ] ; Chen, J (Chen, Jian)[ 1 ] ; Fu, QS (Fu, Qingshan)[ 1 ] ; Li, BH (Li, Binghong)[ 2,3 ] ; Zhang, HZ (Zhang, Huazhi)[ 1 ] ; Gong, Y (Gong, Yong)[ 1 ]


APPLIED SURFACE SCIENCE


¾í: 324
Ò³: 438-442
DOI: 10.1016/j.apsusc.2014.10.107

³ö°æÄê: JAN 1 2015

²é¿´ÆÚ¿¯Ó°Ïì

APPLIED SURFACE SCIENCE  

³ö°æÉÌ ELSEVIER SCIENCE BV, PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS

ISSN: 0169-4332
eISSN: 1873-5584

Ñо¿ÁìÓò Chemistry
Materials Science
Physics



ÕªÒª
Helical carbon fibers (HCNFs) were synthesized by one-step chemical vapour deposition using cupric tartrate as a catalyst at temperature below 500 degrees C. The bound rubber of natural rubber (NR)/HCNFs were also prepared in this study. The results of thermogravimetry-differential scanning calorimetry (TG/DSC) for cupric tartrate nanoparticles show that the transformation of C4H4CuO6 -> Cu reaction occurs at similar to 250-310 degrees C. The characterization of scanning electron microscopy (SEM), transmission electron microscope (TEM), X-ray diffraction (XRD) and Raman spectrum for the synthesized products confirms that the synthesis of HCNFs is highly temperature-dependent. The straight fibers with the fiber diameter of 100-400 nm are obtained at 280 degrees C and HCNFs can be synthesized at higher temperature, with the coil diameter of 0.5-1 mu m and fiber diameter of 100-200 nm at 380 degrees C, and the coil diameter of 100 nm and fiber diameter of similar to 80 nm at 480 degrees C. The maximum of the bound-rubber content (37%) can be obtained with the addition of similar to 100 wt.% HCNFs in NR, which indicates that the coiled configuration of HCNFs makes a noticeable contribution to the reinforcement of NR/CB system. (C) 2014 Elsevier B.V. All rights reserved.

¹Ø¼ü´Ê
×÷Õ߹ؼü´Ê:Helical carbon fibers; Nanomaterials; Chemical vapor deposition; Bound rubber

KeyWords Plus:NANOTUBES; MECHANISM; DECOMPOSITION; NANOFIBERS; COMPOSITE; ACETYLENE; CATALYST; BLACK

×÷ÕßÐÅÏ¢
ͨѶ×÷ÕßµØÖ·: Chen, J (ͨѶ×÷Õß) Sichuan Univ Sci & Engn, Dept Mat & Chem Engn, Zigong 643000, Sichuan, Peoples R China.
  ÔöÇ¿×éÖ¯ÐÅÏ¢µÄÃû³Æ
    Sichuan University of Science & Engineering  


µØÖ·:  [ 1 ] Sichuan Univ Sci & Engn, Dept Mat & Chem Engn, Zigong 643000, Sichuan, Peoples R China
  ÔöÇ¿×éÖ¯ÐÅÏ¢µÄÃû³Æ
    Sichuan University of Science & Engineering  
       [ 2 ] China Rubber Grp Carbon Black Ind Res, Zigong 643000, Sichuan, Peoples R China
       [ 3 ] Design Inst, Zigong 643000, Sichuan, Peoples R China


µç×ÓÓʼþµØÖ·:wuhangzs@163.com

»ù½ð×ÊÖúÖÂл
»ù½ð×ÊÖú»ú¹¹ ÊÚȨºÅ
National Natural Science Foundation of China  51072125  
Scientific and Technical Project of Sichuan Province  2013JQ0024
2013JY0124  
Breeding Project of Sichuan University of Science and Engineering  2011PY06  
²é¿´»ù½ð×ÊÖúÐÅÏ¢¹Ø±Õ»ù½ð×ÊÖúÐÅÏ¢   

The authors thank the National Natural Science Foundation of China (51072125), the Scientific and Technical Project of Sichuan Province (2013JQ0024 and 2013JY0124) and the Breeding Project of Sichuan University of Science and Engineering (2011PY06) for the financial support of this research.

³ö°æÉÌ
ELSEVIER SCIENCE BV, PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS

Àà±ð / ·ÖÀà
Ñо¿·½Ïò:Chemistry; Materials Science; Physics

Web of Science Àà±ð:Chemistry, Physical; Materials Science, Coatings & Films; Physics, Applied; Physics, Condensed Matter

ÎÄÏ×ÐÅÏ¢
ÎÄÏ×ÀàÐÍ:Article

ÓïÖÖ:English

Èë²ØºÅ: WOS:000346088500057

ISSN: 0169-4332

eISSN: 1873-5584

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Web of Science ºËÐĺϼ¯ÖÐµÄ "ÒýÓõIJο¼ÎÄÏ×": 26

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4Â¥2017-08-31 15:16:11
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ÒýÓûØÌû:
4Â¥: Originally posted by baiyuefei at 2017-08-31 15:16:11
Low-temperature synthesis and characterization of helical carbon fibers by one-step chemical vapour deposition
×÷Õß:Jin, YZ (Jin, Yongzhong) ; Chen, J (Chen, Jian) ; Fu, QS (Fu, Qingshan) ; Li, BH  ...

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