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有机化学方面,英译汉一个摘要,求助
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A general and efficient method for the synthesis of oxindole derivatives through visible-light-induced difluoromethylenephosphonation of N-arylacrylamides has been developed. The phosphonodifluoromethyl radicals, which is generated in situ from the corresponding BrCF2PO(OEt)2 under visible-light irradiation, in combination with N-arylacrylamides furnished difluoromethylenephosphonated oxindoles via a proposed tandem radical cyclization process. Notable advantages of this method include its simplicity and mild conditions, avoidance of toxic reagents, and compatibility with a variety of functional groups. |
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DJ_Tokyo
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