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【答案】应助回帖
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感谢参与，应助指数 +1
hwoda: 金币+10, ★★★★★最佳答案, 谢谢“一直向前走走”的帮助！ 2017-05-23 15:13:08
lazy锦溪: LS-EPI+1 2017-05-23 15:19:34
Photo-induced atom transfer radical polymerization of MMA with chlorophll A as photoinitiator
作者:Wang, GX (Wang, Guo-Xiang)[ 1 ] ; He, JY (He, Jie-Yu)[ 2 ] ; Liu, LC (Liu, Li-Chao)[ 1 ] ; Wu, H (Wu, Hu)[ 1 ] ; Zhong, M (Zhong, Ming)[ 1 ]
JOURNAL OF POLYMER RESEARCH
卷: 23
期: 5
文献号: 101
DOI: 10.1007/s10965-016-0995-4
出版年: APR 28 2016
查看期刊信息
摘要
In this work, photoinduced free radical polymerization of methyl methacrylate (MMA) was performed at ambient temperature in dimethyl sulfoxide with chlorophll A as a photosensitizer. Well controlled polymerization of MMA was achieved. The linear first order plot of ln([M](0)/[M]) vs time was observed. Well-defined polymethyl methacrylates (PMMA) with narrow molecular weight distribution (M-w/M-n) were prepared. It indicated that the polymerization was controllable. The chain-end fidelity was demonstrated by H-1 NMR spectra. Chain extension experiments demonstrated the living feature of polymerization. The initiation and moderation of polymerization were manipulated by the periodic light on-off experiments.
关键词
作者关键词 hoto-induced; Chlorophll A; Living polymerization; MMA
KeyWords PlusET-RAFT POLYMERIZATION; OXYGEN TOLERANCE; METHYL-METHACRYLATE; ATRP
作者信息
通讯作者地址: He, JY (通讯作者)
Hainan Trop Ocean Univ, Expt Ctr Sci & Technol, Sanya 572022, Hainan, Peoples R China.
地址:
[ 1 ] Hunan Inst Sci & Technol, Coll Chem & Chem Engn, Yueyang 414006, Hunan, Peoples R China
[ 2 ] Hainan Trop Ocean Univ, Expt Ctr Sci & Technol, Sanya 572022, Hainan, Peoples R China
电子邮件地址:Hejieyu555@163.com
基金资助致谢
基金资助机构 授权号
Key Research and Development Project of Hainan Province
ZDYF2016020
Scientific Research Fund of Hunan Provincial Education Department
13A031
National Natural Science Foundation of China
21276071
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出版商
SPRINGER, VAN GODEWIJCKSTRAAT 30, 3311 GZ DORDRECHT, NETHERLANDS
类别 / 分类
研究方向olymer Science
Web of Science 类别olymer Science
文献信息
文献类型:Article
语种:English
入藏号: WOS:000391693200001
ISSN: 1022-9760
eISSN: 1572-8935
期刊信息
Impact Factor (影响因子): Journal Citation Reports®
其他信息
IDS 号: EH3SW
Web of Science 核心合集中的 "引用的参考文献": 17
Web of Science 核心合集中的 "被引频次": 0 |
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