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°ïæ²éÒ»ÏÂÕâÆªÎÄÕÂÓÐûÓб»SCI¼ìË÷ £º Ya-nan Zhang and Shi-ai Xu, You have free access to this contentEffects of amylose/amylopectin starch on starch-based superabsorbent polymers prepared by ¦Ã-radiation£¬Starch£¬ 3 MAY 2016, DOI: 10.1002/star.201500294 |
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Effects of amylose/amylopectin starch on starch-based superabsorbent polymers prepared by -radiation ×÷Õß:Zhang, YN (Zhang, Ya-nan)[ 1,2 ] ; Xu, SA (Xu, Shi-ai)[ 1,2 ] STARCH-STARKE ¾í: 69 ÆÚ: 1-2 ÌØ¿¯: SI ÎÄÏ׺Å: UNSP 1500294 DOI: 10.1002/star.201500294 ³ö°æÄê: JAN 2017 ²é¿´ÆÚ¿¯ÐÅÏ¢ ÕªÒª Biodegradable superabsorbent polymers (SAPs) were synthesized in this study by graft copolymerization of acrylic acid onto amylose and amylopectin using N,N-methylenebisacrylamide as a cross-linker, initiated by an initiator (potassium persulfate) and -ray radiation, respectively. The structures of the resultant amylose-graft-poly(acrylic acid) (amylose-g-PAA) and amylopectin-graft-poly(acrylic acid) (amylopectin-g-PAA) SAPs were characterized by Fourier transform infrared (FTIR) spectroscopy, solid-state C-13 nuclear magnetic resonance (NMR) spectroscopy, and thermogravimetric analysis (TGA). The main purpose of this study is to investigate the effects of the two initiation modes and chain structures of starches on the grafting ratios (GR) and properties of these amylose-g-PAA and amylopectin-g-PAA SAPs. The results show that SAPs prepared by -radiation have higher water absorption and GR than SAPs prepared by the initiator. In addition, amylose-g-PAA SAPs have higher water absorption and GR than amylopectin-g-PAA SAPs. The optimum water absorption is 530g/g for amylose-g-PAA SAPs and 355g/g for amylopectin-g-PAA SAPs, respectively. It is concluded that -radiation is more time-saving, energy-saving, and efficient than the initiator. ¹Ø¼ü´Ê ×÷Õ߹ؼü´Ê:-Radiation; Acrylic acid; Amylopectin; Amylose; Superabsorbent polymers KeyWords Plus:GRAFT-COPOLYMERIZATION; RHEOLOGICAL PROPERTIES; HYDROGEL; ACID); IRRADIATION; WATER; COMPOSITE; KINETICS; CHLORIDE; REMOVAL ×÷ÕßÐÅÏ¢ µØÖ·: [ÏÔʾÔöÇ¿×éÖ¯ÐÅÏ¢µÄÃû³Æ] [ 1 ] Qinghai Univ, Chem Engn Coll, Xining 810016, Peoples R China [ÏÔʾÔöÇ¿×éÖ¯ÐÅÏ¢µÄÃû³Æ] [ 2 ] East China Univ Sci & Technol, Sch Mat Sci & Engn, Minist Educ, Key Lab Ultrafine Mat,Shanghai Key Lab Adv Polyme, Shanghai, Peoples R China µç×ÓÓʼþµØÖ·:saxu@ecust.edu.cn »ù½ð×ÊÖúÖÂл »ù½ð×ÊÖú»ú¹¹ ÊÚȨºÅ Fundamental Research Funds for the Central University WD1315012 Foundation from Qinghai Science and Technology Department 2014-HZ-817 ²é¿´»ù½ð×ÊÖúÐÅÏ¢ ³ö°æÉÌ WILEY-V C H VERLAG GMBH, POSTFACH 101161, 69451 WEINHEIM, GERMANY Àà±ð / ·ÖÀà Ñо¿·½Ïò:Food Science & Technology Web of Science Àà±ð:Food Science & Technology ÎÄÏ×ÐÅÏ¢ ÎÄÏ×ÀàÐÍ:Article ÓïÖÖ:English Èë²ØºÅ: WOS:000392428600002 ISSN: 0038-9056 eISSN: 1521-379X ÆÚ¿¯ÐÅÏ¢ Impact Factor (Ó°ÏìÒò×Ó): Journal Citation Reports® ÆäËûÐÅÏ¢ IDS ºÅ: EI3YI Web of Science ºËÐĺϼ¯ÖÐµÄ "ÒýÓõIJο¼ÎÄÏ×": 40 Web of Science ºËÐĺϼ¯ÖÐµÄ "±»ÒýƵ´Î": 0 |

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