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¡¾ÐÕ      Ãû¡¿£ºHarry Kroto


¡¾Ñо¿·½Ïò¡¿£º  Main research areas:  
   
I Spectroscopy of Unstable Species and Reaction Intermediates (Infrared, Photoelectron, Microwave and Mass Spectrometry)
II Astrophysics (Interstellar Molecules and Circumstellar Dust)
III Cluster Science (Carbon and Metal Clusters, Microparticles, Nanofibres)  
IV Fullerene Chemistry, Nanoscience and Nanotechnology  
   
Research Highlights (Ref Nos - Key Refs List)
   
a) First detection of 1¦¤ state of a polyatomic free radical (NCN by flash photolysis) [3,4]
b) Theoretical studies of ground and electronically excited sates of small molecules [5,6]
c)  Detection of liquid phase intermolecular interactions using Raman Spectroscopy [ 7-10]
d) Breakthrough in the detection of new unstable species (thioaldehydes, thiocarbonyls thioborines) using combination of microwave and photoelectron spectroscopy techniques [12,15,18-22,31,80]
e) Synthesis in 1976 of the first phoaphaalkenes (compounds containing the free carbon phosphorus double bond) in particular CH2=PH (with N P C Simmons and J F Nixon, Sussex), [28, 80]
f) Monograph ¡°Molecular Rotation Spectra¡± [23]
g) Synthesis in 1976 of the first analogues of HCP, the phosphaalkynes which contain the carbon phoshorus triple bond - in particular CH3CP (with N P C Simmons and J F Nixon, Sussex), [29,80]
h) The discovery (1976-8) of the cyanopolyynes, HCnN (n=5,7,9), in interstellar space (with D R M Walton A J Alexander and C Kirby (Sussex) and T Oka, L W Avery, N W Broten and J M MacLeod (NRC Ottawa)), Ref 4-6, based on microwave measurements made at Sussex, [27,30,35,80]  
i) The discovery of C60: Buckminsterfullerene in 1985 (with J R Heath, S C O'Brien, R F Curl and R E Smalley), [100,112,139,239]  
j) The detection of endohedral metallofullerene complexes (with J R Heath, S C O'Brien, Q Zhang, Y Liu, R F Curl, F K Tittel and R E Smalley), [101,139]  
k) The prediction that C60 should be produced in combustion processes and might indicate how soot is formed (with Q L Zhang, S C O'Brien, J R Heath, Y Liu, R F Curl and R E Smalley) [103,139]  
l) The explanation of why C70 is the second stable fullerene (after C60) and the discovery of the Pentagon Isolation Rule as a criterion for fullerene stability in general [107,112,139,239]  
m) The prediction of the tetrahedral structure of C28 and the possible stability of "tetravalent" derivatives such as C28H4 [107,112,139,239]   
n) The prediction that giant fullerenes have quasi-icosahedral shapes and the detailed structure of concentric shell graphite microparticles (with K G McKay), [111,112,139,239]
o) The mass spectrometric identification and solvent extraction (with J P Hare and A Abdul-Sada) of C60 from arc processed carbon in 1990 - independently from and simultaneously with the Heidelberg/Tucson group; Refs [121,239]  
p) The chromatographic separation/purification of C60 and C70 and 13C NMR measurements which provided unequivocal proof that these species had fullerene cage structures (with J P Hare and R Taylor, Sussex), Refs [121,139,239]  
q) Crystal structure of C60 [135,138]  
r) Main Fullerene chemistry breakthroughs: C60(ferrocene)2 [162], characterisation of C60Hal6 [174,149], C60(P4)2 [187], [192]
s) Nanoscience and Nanotechnology advances: Condensed phase nanotubes [205], nanoscale BN structures [224], partly aligned-nanotube bundles [233], nanotube formation mechanisms [161,238], silicon oxide nanostructures [247], Si surface-deposited fullererene studies [251], insulated carbon nanotube conductors [297]   
   


¡¾¸öÈ˼òÀú¡¿£º[Professor Sir Harry Kroto FRS] in 1996 Professor Kroto was jointly awarded the Nobel Lauriate for chemistry with Richard Smalley and Robert Curl, for the discovery of C60 [buckyballs], and later that year he received a Knighthood by Queen Elizabeth II. (In 1985 his experiment, designed to unravel the carbon chemistry in red giant stars, revealed the existence of Buckminsterfullerene)
    Since 1990 he has been chairman of the editorial board of the Chemical Society Reviews. Currently he is researching Synthetic Fullerene Chemistry, Nanotubes and nanoparticles, Cluster beam studies [Generation of small fullerenes (C24, C28 etc...) by laser vaporisation], and Astrophysical studies monitoring of red giant stars in the search for C60 in space, at the Sussex Fullerene Research Centre
http://www.kroto.info/General_info/CV_B.html
41Â¥2008-12-29 19:14:39
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¡¾ÐÕ      Ãû¡¿£ºDr. Chad Mirkin
¡¾Ñо¿·½Ïò¡¿£º  Main research areas:
Dr. Chad A. Mirkin's research focuses on developing methods for controlling the architecture of molecules and materials on the 1-100 nm length scale, and utilizing such structures in the development of analytical tools that can be used in the areas of chemical and biological sensing, lithography, catalysis, and optics. Mirkin has pioneered the use of biomolecules as synthons in materials science and the development of nanoparticle-based biodiagnostics. Many of the concepts and materials developed within his laboratories are now the basis for commercial detection and lithography systems.
¡¾Publications¡¿£º

Huo, F.; Zheng, Z.; Zheng, G.; Giam L. R.; Zhang, H.; Mirkin, C. A. ¡°Polymer Pen Lithography¡± Science 2008, online  DOI: 10.1126/science.1162193  (pdf reprint)
Kuwabara, J.; Ovchinnikov, M. V.; Stern, C. L.; Mirkin, C. A. ¡°The Reactivity of Dinuclear Rhodium(I) Macrocycles Formed via the Weak-Link Approach,¡± Organometallics 2008, 27, 789-792.
Kim, K.-H.; Sanedrin, K.; Ho, A. M.; Lee, S.-W.; Moldovan, N.; Mirkin, C. A.; Espinosa, H. D. ¡°Direct Delivery and Submicrometer Patterning of DNA by a Nanofountain Probe,¡± Adv. Mater. 2008, 20, 330-334.
Lee, J.-S.; Ulmann, P. A.; Han, M. S.; Mirkin, C. A. ¡°A DNA-Gold Nanoparticle Based Colorimetric Competition Assay for the Detection of Cysteine,¡° Nano Lett. 2008, 8, 529-533.
Ciszek, J. W.; Huang, L.; Wang, Y.; Mirkin, C. A. ¡°Kinetically-Controlled, Shape-Directed Assembly of Nanorods,¡° Small 2008, 4, 206-210.
Park, S. Y.; Lytton-Jean, A. K. R.; Lee, B.; Weigand, S.; Schatz, G. C.; Mirkin, C. A. ¡°DNA-Programmable Nanoparticle Crystallization,¡° Nature 2008, 451, 553-556.
Oliveri, C. G.; Nguyen, S.; Mirkin, C. A. ¡°A Highly Modular and Convergent Approach for the Synthesis of Stimulant-Responsive Heteroligated Cofacial Porphyrin Tweezer Complexes,¡± Inorg. Chem. 2008, 47, 2755-2763.
Sanedrin, R. G.; Huang, L.; Jang, J.-W.; Kakkassery, J.; Mirkin, C. A. ¡°Polyethylene Glycol as a Novel Resist and Sacrificial Material for Generating Positive and Negative Nanostructures,¡° Small 2008, in press.
Zheng, G.; Qin, L.; Mirkin, C. A. ¡°Spectroscopically Enhancing Electrical Nanotraps,¡± Angew. Chem. Int. Ed. 2008, 47, 1938-1941.
Lithography-Based Molecular Transport Junctions: A New Testbed for Molecular Electronics¡° J. Am. Chem. Soc. 2008, in press.
Xue, C.; Metraux, G. S.; Millstone, J. E.; Mirkin, C. A. ¡°A Mechanistic Study of Photomediated Triangular Silver Nanoprism Growth¡± J. Am. Chem. Soc. 2008, in press.
Banholzer, M. J.; Millstone, J. E.; Mirkin, C. A. ¡°Rationally Designed Nanostructures for Surface Enhanced Raman Spectroscopy,¡° Chemical Society Reviews 2008, 37, 885-897.
Banholzer, M. J.; Millstone, J. E.; Mirkin, C. A. ¡°On-Wire Lithography: Designing Nanostructures with Optimal SERS Behavior,¡° SPIE Newsroom (Online 2008), April 25, 2008. http://spie.org/x24237.xml (accessed May 5, 2008).
Xu, X.; Zhao, Z.; Qin, L.; Wei, W.; Levine, J. E.; Mirkin, C. A. ¡°A Fluorescence Recovery Assay for the Detection of Protein - DNA Binding,¡° Analytical Chem. 2008, in press.
Oliveri, C. G.; Ulmann, P. A.; Wiester, M. J.; Mirkin, C. A. ¡°Heteroligated Supramolecular Coordination Complexes Formed via the Halide Induced Ligand Rearrangement Reaction,¡° Acc. Chem. Res. 2008, in press.
Lee, J.-S.; Seferos, D. S.; Giljohann, D. A.; Mirkin, C. A. ¡°Synthesis, Thermodynamically Controlled Separation, and Characterization of Polyvalent 2-nm Gold Nanoparticle-Oligonucleotide Conjugates,¡± J. Am. Chem. Soc. 2008, 130, 5430-5431.
Jeon, Y.-M.; Heo, J.; Mirkin, C. A. ¡°Amorphous Infinite Coordination Polymer Microparticles: A New Class of Selective Hydrogen Storage Materials,¡± Adv. Materials 2008, 20, 2105-2110.
Jang, J.-W.; Sanedrin, R.; Maspoch, D.; Hwang, S.; Fujigaya, T.; Jeon, Y.-M.; Vega, R.; Chen, X.; Mirkin, C. A. ¡±Electrically Biased Nanolithography with KOH Coated AFM Tips,¡± Nano Lett. 2008, 8, 1451-1455.
Jeon, Y.-M.; Kim, D.; Mirkin, C. A.; Golen, J. A.; Rheingold, A. L. ¡±Pyrene-Appended Fluorescent Tweezers Generated via the Weak-Link Approach,¡± Tetrahedron 2008,  in press.
Bae, Y.-S.; Farha, O. K.; Spokoynyy, A. M.; Mirkin, C. A.; Hupp, J. T.; Snurr, R. Q. ¡°Carborane-Based Metal-Organic Frameworks as Highly Selective Sorbents for CO2 over Methane,¡± ChemComm 2008, in press
Giljohann, D. A.; Mirkin, C. A. ¡°Tiny Tiles, Tiny Targets,¡°  Nature Biotechnology 2008, 26, 299-300.
Hill, H. D.; Macfarlane, R. J.; Senesi, A. J.; Lee, B.; Park, S. Y.; Mirkin, C. A. ¡°Controlling the Lattice Parameters of Gold Nanoparticle FCC Crystals with Duplex DNA Linkers,¡° Nano Lett. 2008, in press.
Lenhert, S.; Sun, P.; Wang, Y.; Fuchs, H.; Mirkin, C. A. ¡°Massively Parallel Dip-Pen Nanolithography of Heterogeneous Supported Phospholipid Multilayer Patterns,¡± Small, 2007, 3, 71-75.
Xue, C.; Mirkin, C. A. ¡°pH-Switchable Silver Nanoprism Growth Pathways,¡± Angew. Chem. Int. Ed. 2007, 46, 2036-2038.
Zhou, S.; Maspoch, D.; Wang, Y.; Mirkin, C. A.; Schatz, G. C. ¡°Rings of Single-Walled Carbon Nanotubes: Molecular-Template Directed Assembly and Monte-Carlo Modeling,¡± Nano Letters, 2007, 7, 276-280.
Jeon, Y.-M.; Heo, J.; Mirkin, C. A. ¡°Acid-Functionalized Dissymmetric Salen Ligands and Their Manganese (III) Complexes,¡± Tetrahedron Lett. 2007, 48, 2591-2595.
Salaita, K. S.; Wang, Y.; Mirkin, C. A. ¡°Applications of Dip-Pen Nanolithography,¡± Nature Nanotech. 2007, 2, 145-155.
Jang, J.-W., Maspoch, D.; Fujigaya, T.; Mirkin, C. A. ¡°A Molecular Eraser for Dip-Pen Nanolithography,¡± Small 2007, 3, 600-605.
Ulmann, P. A.; Brown, A. M.; Ovchinnikov, M. V.; Mirkin, C. A.; DiPasquale, A. G.; Rheingold, A. L. ¡°Spontaneous Formation of Heteroligated PtII Complexes with Chelating Hemilabile Ligands,¡± Chemistry ¨C A European Journal 2007, 13, 4529-4534.
Xu, X.; Han, M. S.; Mirkin, C. A. ¡°A Gold Nanoparticle-Based, Real-Time Colorimetric Screening Method for Endonuclease Activity and Inhibition,¡± Angew. Chem. Int. Ed. 2007, 46, 3468-3470.
Lee, J.-S.; Han, M. S.; Mirkin, C. A. ¡°Colorimetric Detection of Mercuric Ion (Hg2+) in Aqueous Media Using DNA-Functionalized Gold Nanoparticles,¡± Angew. Chem. Int. Ed. 2007, 46, 4093-4096.
Jeon, Y.-M.; Heo, J.; Mirkin, C. A. ¡°Dynamic Interconversion of Amorphous Microparticles and Crystalline Rods in Salen-based Homochiral Infinite Coordination Polymers,¡± J. Am. Chem. Soc. 2007, 129, 7480-7481.
Masar, M. S. III; Gianneschi, N. C.; Oliveri, C. G.; Stern, C. L.; Nguyen, S. T.; Mirkin, C. A. ¡°Allosterically Regulated Supramolecular Catalysis of Acyl Transfer Reactions for Signal Amplification and Detection of Small Molecules,¡± J. Am. Chem. Soc. 2007, 129, 10149-10158.
Heo, J.; Jeon, Y.-M.; Mirkin, C. A. ¡°Reversible Interconversion of Homochiral Triangular Macrocycles and Helical Coordination Polymers,¡± J. Am. Chem. Soc. 2007, 129, 7712-7713.
Lytton-Jean, A. K. R.; Han, M. S.; Mirkin, C.A. ¡°Microarray Detection of Duplex and Triplex DNA Binders with DNA-Modified Gold Nanoparticles,¡± Analytical Chem. 2007, 79, 6037-6041.
Vega, R. A.; Shen, C. K.-F.; Maspoch, D.; Robach, J. G.; Lamb, R. A.; Mirkin, C. A. ¡°Monitoring Single Cell Infectivity from Virus Particle Nanoarrays Fabricated by Parallel Dip-Pen Nanolithography,¡± Small 2007, 3, 1482-1485.
Hurst, S. J.; Han, M. S.; Lytton-Jean, A. K. R.; Mirkin, C. A. ¡°Screening the Sequence Selectivity of DNA-Binding Molecules Using a Gold Nanoparticle-based Colorimetric Approach,¡± Analytical Chemistry 2007, 79, 7201-7205.
Seferos, D. S.; Giljohann, D. A.; Rosi, N. L.; Mirkin, C. A. ¡°Locked Nucleic Acid-Nanoparticle Conjugates,¡±ChemBioChem. 2007, 8, 1230-1232.
Xu, X.; Georganopoulou, D. G.; Hill, H. D.; Mirkin, C. A. ¡°Homogeneous Detection of Nucleic Acids Based upon the Light Scattering Properties of Silver-Coated Nanoparticle Probes,¡± Analytical Chem. 2007, 79, 6650-6654.

Tang, S.; Zhao, J.; Storhoff, J. J.; Norris, P. I.; Little, R. F.; Yarchoan, R.; Stramer, S. L.; Patno, T.; Domanus, M.; Bernal, Y.; Dhar, A.; Mirkin, C. A.; Hewlett, I.

¡°Nanoparticle Based Biobarcode Amplification Assay (BCA) for Sensitive and Early Detection of Human Immunodeficiency Type 1 Capsid (p24) Antigen,¡± J. Aids 2007, 46, 231-237.

Lee, J.-S.; Lytton-Jean, A. K. R.; Hurst, S.; Mirkin, C. A. ¡°Silver Nanoparticle Oligonucleotide Conjugates Based on Triple Cyclic Disulfide Moieties,¡± Nano Lett. 2007, 7, 2112-2115.

Kuwabara, J.; Stern, C. L.; Mirkin, C. A. ¡°A Coordination Chemistry Approach to a Multieffector Enzyme Mimic,¡± J. Am. Chem. Soc. 2007, 129, 10074-10075.

Qin, L.; Banholzer, M. J.; Millstone, J. E.; Mirkin, C. A.  ¡°Nanodisk Codes,¡° Nano Lett.  2007, 7, 3849-3853.

Oliveri, C. G.; Heo, J.; Nguyen, S. T.; Mirkin, C. A.; Wawrzak, Z. ¡°A Convergent Coordination Chemistry-Based Approach to Dissymmetric Macrocyclic Cofacial Porphyrin Complexes,¡± Inorganic Chem. 2007, 46, 7716-7718.

Xue, C.; Chen, X.; Hurst, S. J.; Mirkin, C. A. ¡°Self-Assembled Monolayer Mediated Silica Coating of Silver Triangular Nanoprisms,¡± Adv. Mater. 2007, 19, 4071-4074.

Hill, H. D.; Vega, R. A.; Mirkin, C. A. ¡°Non-Enzymatic Detection of Bacterial Genomic DNA Using the Bio-Barcode Assay,¡° Analytical Chem. 2007, 79, 9218-9223.

Xue, C.; Millstone, J. E.; Mirkin, C. A. ¡°Plasmon-Driven Synthesis of Triangular Nanoprisms from Isotropic Gold Cores,¡± Angew. Chem. Int. Ed. 2007, 46, 8436-8439.

Giljohann, D. A.; Seferos, D. S.; Patel, P. C.; Millstone, J. E.; Rosi, N. L.; Mirkin, C. A. ¡°Oligonucleotide Loading Determines Cellular Uptake of DNA-Modified Nanoparticles,¡° Nano Lett. 2007, 7, 3818-3821.
Seferos, D. S.; Giljohann, D. A.; Hill, H. D.; Prigodich, A. E.; Mirkin, C. A. ¡°Nanoflares: Probes for Transfection, RNA Visualization, and Detection of Transcripts in Living Cells,¡± J. Am. Chem. Soc. 2007, 129, 15477-15479.

Farha, O. K.; Spokoyny, A. M.; Mulfort, K. L.; Hawthorne, M. F.; Mirkin, C. A.; Hupp, J. T. ¡°Synthesis and Hydrogen Sorption Properties of Carborane-Based Metal-Organic Framework  Materials,¡± J. Am. Chem. Soc. 2007, 129, 12680-12681.

Mirkin, C. A. ¡°The Power of the Pen: Development of Massively Parallel Dip-Pen Nanolithography,¡± ACS Nano 2007, 1, 79-83.

Qin, L.; Banholzer, M. J.; Xu, X.; Huang, L.; Mirkin, C. A. ¡°Rational Design and Synthesis of Catalytically Driven Nano Rotors,¡± J. Am. Chem. Soc. 2007, 129, 14870-14871.

Yoon, H. J.; Heo, J.; Mirkin, C. A. ¡°Allosteric Regulation of Phosphate Diester Transesterification Based Upon a Dinuclear Zinc Catalyst Assembled via the Weak-Link Approach,¡± J. Am. Chem. Soc. 2007, 129, 14182-14183.

[ Last edited by kinmer on 2009-1-1 at 11:47 ]
42Â¥2009-01-01 11:46:37
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2009
1. Qiao Zhang, Shu-Juan Liu, Shu-Hong Yu*, Recent Advances in Oriented Attachment Growth and Synthesis of Functional Materials: Concept, Evidence, Mechanism, and Its Future, J. Mater. Chem.. 2009, 19, Issue 2,Invited Feature Article. Online. Inside Cover.
2. Hai-Wei Liang, Shuo Liu, Jun-Yan Gong, Shang-Bing Wang, Lei Wang, Shu-Hong Yu*, Ultrathin Te Nanowires: An Excellent Platform for Controlled Synthesis of Ultrathin Platinum and Palladium Nanowires/Nanotubes with Very High Aspect Ratio,Adv. Mater.. 2009, 21, 10.1002/adma.200802286. In press.
3. Weihong Xu, Shu-Hong Yu*, Conducting Performance of Individual Ag@C Coaxial Nanocable: Ideal Building Blocks for Interconnects in Nanoscale Devices, Small . 2009, 5, smll.200801236, in press.
4. Huai-Ping Cong, Shu-Hong Yu*, Self-assembly of functionalized inorganic-organic hybrids, Curr. Opin. Colloid Interface Sci. . 2009, Invited Review, Online.
5. Jian-Hua Zhu, Shu-Hong Yu*, An-Wu Xu, Helmut C?lfen, Biomimetic Mineralization of Double-Stranded and Cylindrical Helical BaCO3 Nanofibres, Chem. Commun.. 2008, in press..
6. Yu-Xue Zhou, Hong-Bin Yao, Qiao Zhang, Jun-Yan Gong, Shu-Juan Liu, Shu-Hong Yu*, Hierarchical FeWO4 Microcrystals: Solvothermal Synthesis, and Their Photocatalytic and Magnetic Properties, Inorg. Chem.. 2008, Invited review.
7. Jun-Yan Gong, Shi-Rui Guo, Hai-Sheng Qian, Wei-Hong Xu, Shu-Hong Yu*, A general approach for synthesis of a family of functional inorganic nanotubes using highly active carbonaceous nanofibers as templates, J. Mater. Chem. . 2009, 19, Online. Theme issue of nanotubes. Invited.
8. Shu-Juan Liu, Jun-Yan Gong, Bo Hu, Shu-Hong Yu*, Mesocrystals of Rutile TiO2: Mesoscale Transformation, Crystallization and Growth by a Biologic Molecules-Assisted Hydrothermal Process, Crystal Growth Design. 2009, in press.
9. Huai-Ping Cong, Shu-Hong Yu*, Shape Control of Cobalt Carbonate Particles by Hydrothermal Process in a Mixed Solvent: An Efficient Precursor to Nanoporous Cobalt Oxide Architectures and Their Sensing Property, Crystal Growth Design . 2008,Online
10. Jian-Hua Zhu, Ji-Ming Song, Wei-Qing Zhang, Jin-Xia Shi, Shu-Hong Yu*, Mineralization for Micropatterned Growth of Carbonate Nanofibers, CrystEng. Commun.. 2009,Invited. In press.
11. Shu-Juan Liu, Xiao-Xi Wu, Bo Hu, Jun-Yan Gong, Shu-Hong Yu*, Novel anatase TiO2 boxes and urchin-like flowers assembled by hollow tubes: D,L-malic acid-assisted hydrothermal synthesis, growth mechanism and photocatalytic properties, Crystal Growth & Design. 2009,in press.
2008
12. Yongjie Zhan, Shu-Hong Yu*, Necklace-Like Cu@cross-linked poly(vinyl alcohol) (PVA) core-shell Microncables, J. Am. Chem. Soc.. 2008, 130(17), 5650-5651.
13. Ming-Jun Hu, Yang Lu, Sen Zhang, Shi-Rui Guo, Bin Lin, Meng Zhang, Shu-Hong Yu*, High Yield Synthesis of Bracelet-like Hydrophilic Ni-Co Magnetic Alloy Flux-closure Nanorings, J. Am. Chem. Soc. . 2008,130(35), 11606 ¨C 11607.
14. Weitang Yao, Shu-Hong Yu*, Synthesis of Semiconducting Functional Materials in Solution: From II-VI Semiconductor to Inorganic/organic Hybrid Semiconductor Nanomarerials, Adv. Funct. Mater.. 2008, 18, 3357-3366. Feature Article. Inside Cover. .
15. Bo Hu, Shu-Hong Yu*, Kan Wang, Lei Liu, Xue Wei Xu, Functional Carbonaceous Materials from Hydrothermal Carbonization of Biomass: An Effective Chemical Process, Dalton Trans.. 2008, (40), 5414-5423.Invited Perspective, Cover. Highlighted by RSC. .
16. Shi-Rui Guo, Jun-Yan Gong, Peng Jiang, Mian Wu, Shu-Hong Yu*, Novel biocompatible and luminescent silver@phenol formaldehyde resin (PFR) core/shell nanospheres: Large scale synthesis and application for in vivo bio-imaging, Adv. Funct. Mater.. 2008, 18(6), 872-879. Most-assessed. .
17. Huai-Ping Cong, Shu-Hong Yu*, Synthesis of Microraft-shaped Zinc-Phenylalanine Complexes and Zinc-Phenylalanine/dye Hybrid Bundles with New Optical Properties, Adv. Funct. Mater. . 2008, 18(2), 195-202.
18. Jun-Jie Wang, Jun Jiang, Bo Hu, Shu-Hong Yu*, Uniformly-Shaped Poly (p-phenylenediamine) (PpPD) Microparticles: Shape Control Synthesis and Their Potential Application in Removal of Lead Irons in Water, Adv. Funct. Mater. 2008, 18(7), 1105-1111. Adv. Funct. Mater. . 2008, 18(7), 1105-1111.
19. Weihong Xu, Jiming Song, Lian Sun, Jinlong Yang, Wenping Hu, Zhuoyu Ji, Shu-Hong Yu*, Structural, Electrical, and Photoconductive Properties of Individual Single Crystalline Tellurium Nanotube Synthesized by a Chemical Route: Doping Effects on Its Electrical Structures, Small . 2008, 4(7), 888-893. Most accessed articles..
20. Jie Chen, Chunyan Wu, Jinping Tian, Wenjie Li, Shu-Hong Yu*, and Yangchao Tian*, Three-dimensional imaging of nanoscopic superstructures in a complex concaved cuboctahedron copper sulfide crystal by x-ray nanotomography. Appl. Phys. Lett. . 2008, 92, 233104-233106. DOI:10.1063/1.2943337. Virtual Journal of Nanoscale Science and Technology. Highlighted by Nature China with title ¡°Nanotomography: Crystal clear¡±. http://www.nature.com/nchina/200 ... china.2008.147.html .
21. An-Wu Xu,* Markus Antonietti, Shu-Hong Yu, and Helmut C?lfen*, Polymer-Mediated Mineralization and Self-Similar Mesoscale-Organized Calcium Carbonate with Unusual Superstructures, Adv. Mater. . 2008,20, 1333-1338.
22. Zheng-An Zang, Hong-Bin Yao, Yu-Xue Zhou, Wei-Tang Yao, Shu-Hong Yu*, Synthesis and Magnetic Properties of New [Fe18S25](TETAH)14 (TETAH = Protonated Triethylenetetramine) Nanoribbons: An Efficient Precursor to Fe7S8 Nanowires and Porous Fe2O3 Nanorods, Chem. Mater.. 2008, 20(14), 4749-4755.
23. Shu-Juan Liu, Hai-Yang Cheng, Feng-Yu Zhao, Shu-Hong Yu*, Controllable synthesis of novel VSB-5 microspheres and microrods: Growth mechanism and elective hydrogenation catalytic property, Chem. Eur. J.. 2008, 14(13), 4074-4081.
24. Bo Hu, Shao-Feng Chen, Shu-Juan Liu, Qing-Song Wu, Wei-Tang Yao, Shu-Hong Yu*, Controllable Synthesis of Zinc-Substituted ?- and ¦Â-Nickel Hydroxide Nanostructures and Their Collective Intrinsic Properties, Chem. Eur. J.. 2008,14, 8928-8938.
25. Yi Ding, Yong Wan, Yu-Lin Min, Wei Zhang, Shu-Hong Yu*, General Synthesis and Phase Control of Metal Molybdate Hydrates MMoO4 ?nH2O (M = Co, Ni, Mn, n = 0, 3/4, 1) Nano/Microcrystals by Hydrothermal Approach: Magnetic, Photocatalytic and Electrochemical Properties, Inorg. Chem.. 2008, 47, 7813-7823.
26. Yong Wan, Yu-Lin Min, Shu-Hong Yu*, Synthesis of Carbon-Silica Encapsulated Core-shell Spheres: Their Templating for Other Unique Coreshell Structures and Applications in in-situ Loading Noble-Metal Nanoparticles, Langmuir. 2008,24(9), 5024-5028.
27. Hai-Sheng Qian, Shu-Hong Yu*, Can t-Te Nanowires Really Give Blue-Violet Emission ?: Reply on Comment on High-Quality Luminescent Tellurium Nanowires of Several Nanometers in Diameter and High Aspect Ratio Synthesized by a Poly (Vinyl Pyrrolidone)-Assisted Hydrothermal Process, Langmuir. 2008, 24(15), 8393-8394.
28. Yong-Jie Zhan, Shu-Hong Yu*, Direct Synthesis of Carbon Sub-microtubes by Combination of a Solvothermal Route and a Succeeding Self-assembly Process, J. Phys. Chem. C. 2008, 112(11), 4024-4028. Letter..
29. Yong Wan, Shu-Hong Yu*, Polyelectrolyte Controlled Large-Scale Synthesis of Hollow Silica Spheres with Tunable Size and Wall Thickness¡±, J. Phys. Chem. C . 2008, 112(10), 3641-3647.
30. Bo Hu, Shang-Bing Wang, Kan Wang, Meng Zhang, Shu-Hong Yu*, Microwave Assisted Rapid Facile ¡°Green¡± Synthesis of Uniform Silver Nanoparticles: Self-Assembly into Multilayered Films and Optical Property, J. Phys. Chem. C. 2008, 112(30), 11169-11174.
31. Yu-Xue Zhou, Qiao Zhang, Jun-Yan Gong, Shu-Hong Yu*, Surfactant-assisted Hydrothermal Synthesis and Magnetic Properties of Urchin-like MnWO4 Microspheres and Nanorods, J. Phys. Chem. C. 2008, 112(35), 13383-13389.
32. Xiaohui Guo, An-Wu Xu, Shu-Hong Yu*, Crystallization of Calcium Carbonate Mineral with Hierarchical Structures in DMF Solution under Control of Poly (ethylene glycol)-b-poly(L-glutamic acid): Effects of Crystallization Temperature and Polymer Concentration, Crystal Growth Design . 2008, 8(4), 1233-1242.
33. Jiming Song, Yunzhi Lin, Yongjie Zhan, Yangchao Tian, Gang Liu, Shu-Hong Yu*, Superlong High-Quality Tellurium Nanotubes: Synthesis, Characterization, and Optical Property, Crystal Growth Design. 2008, 8(6), 1902-1908.
34. Yang Xu, Jun Jiang, Yang Lu, Ru-Jie Sun, Jiming Song, Lei Ren, Shu-Hong Yu*, Facile Surfactant-free Synthesis of Water-Dispersible Willow-Leaf-Like Carbonate Apatite Nanorods in Ethanol/Water Mixed Solution and Their Cytotoxicity, Crystal Growth & Design . 2008,8(10); 3822-3828.
35. Chun-Liu Fang, Kun Qian, Jianhua Zhu, Shangbin Wang, Xiaoxuan Lv, Shu-Hong Yu*, Monodisperse ¦Á-Fe2O3@SiO2@Au Core/Shell Nanocomposite Spheres: Synthesis, Characterization, and Property, Nanotechnology. 2008, 19, 125601-125607. Most accessed article..
36. Ming-Jun Hu, Bin Lin, Shu-Hong Yu*, Magnetic-Field Induced Solvothermal Synthesis of Uniform One-Dimensional Assembly of NixCo1-x Alloy Microparticles¡±, Nano Research. 2008, 1(4), 303-312.
37. Wei-Qing Zhang, Yang Lu, Tie-Kai Zhang, Weiping Xu, Meng Zhang, Shu-Hong Yu*, Controlled Synthesis and Biocompatibility of Water-soluble ZnO Nanorods/Au Nanocomposites with Tunable UV and Visible Emission Intensity, Phys. Chem. C. 2008, 112(50), 19872-19877.
38. Sheng-Liang Zhong, Ji-Ming Song, Sen Zhang, Hongbin Yao, An-Wu Xu, Shu-Hong Yu*, Hematite Microrings: Template-free Synthesis and Formation Mechanism, J. Phys. Chem. C. 2008, 112(50), 19916-19921.

[ Last edited by samalanqi on 2009-1-5 at 21:57 ]
45Â¥2009-01-05 21:54:37
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46Â¥2009-01-06 10:10:58
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taijun_2008

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Alchemist

Marie-Paule PILENI

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kqy920(½ð±Ò+4):лл·ÖÏí£¡»¶Ó­³£À´£¡
¡¾ÐÕ    Ãû¡¿£ºProfessor Marie-Paule PILENI

¡¾Ñо¿·½Ïò¡¿£ºPhysical Collective Properties due to self organization of nanocrystals, Control of the reactivity in colloidal systems

¡¾¸öÈ˼òÀú¡¿£ºProfessor Pileni¡¯s research has been highly interdisciplinary in over all of her scientific career. Her accomplishments have impacted the broad areas of photochemistry, photobiology, solar energy conversion, nanomaterials, colloidal assembly and self-assembly. Most significantly, she has demonstrated an unprecedented control of chemical reactivity in colloidal systems and established novel physical principles, which govern the assembly of nanocrystals into supramolecular structures of great potential applicability. Professor Pileni¡¯s accomplishments have been recognized by the increasing frequency of invitations to be a plenary lecturer at American, Japanese and other international scientific meetings, symposia and congresses.

International awards have recognized the importance of her contributions to these fields. She received the Langmuir prize of the American Chemical Society (2000), the prize of the Colloid Division of the Japanese Chemical Society (2001), the prize of the Alexander von Humboldt foundation in Germany (2003), the Descartes-Huygens prize in the Netherlands (2004) and the Blaise Pascal Medal from the European Academy (2005). In 2002, she was given the degree of Doctor Honoris Causa of the University of Chalmers at Göteborg (Sweden). She was made member of European Academy of Sciences (2003) and of the Royal Academy of Sciences and Technology of Sweden (2004). She was awarded the prize of the most cited French scientist, from 1981 to 1998, in 2000 by the Institute of Scientific Information.

In all her career, she has paid special attention to the promotion of women in research. Since 1988, she has trained 19 women and 23 men. Currently her laboratory has 18 members with 50% of men and women. According to Science Watch (July-August 2003) she is the 25th highest cited scientist on nanotechnology with 9.64 citation per paper.

¡¾ÂÛÎÄ£¨2008£©¡¿£º[173] Shape-Controlled Platinum Nanocubes and Their Assembly into Two-Dimensional and Three-Dimensional Superlattices. A. Demorti¨¨res, P. Launois, N. Goubet, P.A. Albouy and C. Petit in press (J. Chem. Phys. C)

[172] Motif Transfer: Down to 3 nm in Resolution Using Individual Nanocrystals.
Doroth¨¦e Ingert and Marie-Paule Pileni in press (Adv. Mat.)

[171] Vibration Dynamics of Supra-Crystals of Cobalt Nanocrystals Studied With Femtosecond Laser Pulses.
Isabelle Lisiecki, Val¨¦rie Halt¨¦, Christophe Petit, Marie-Paule Pileni and Jean-Yves Bigot Adv. Mat. 20, 1 (2008)

[170] Probing atomic ordering and multiple twinning in metal nanocrystals through their vibrations. H. Portales, N. Goubet, L. Saviot, S. Adichtchev, D.B. Murray, A. Mermet, E. Duval and M.P. Pileni Proc. Natl. Acad. Sci. USA 105, 14784 (2008)

[169] Self-organization of magnetic nanoparticles: a Monte Carlo study. J. Richardi, M.P. Pileni and J.J. Weis Phys Rev E Stat Nonlin Soft Matter Phys 77, 061510 (2008)

[168] Self-assembly of inorganic magnetic nanocrystals: a new physics emerges. M.P. Pileni Journal of Physics D: Applied Physics 134002 (2008)

[167] Cracks in magnetic nanocrystal films: Do directional and isotropic crack patterns follow the same scaling law? A.T. Ngo, J. Richardi and M.P. Pileni Nano Letters 8, 2485-2489 (2008)

[166] Use of reverse micelles to make either spherical or worm-like palladium nanocrystals: Influence of stabilizing agent on nanocrystal shape. K. Naoe, C. Petit and M.P. Pileni Langmuir 24, 2792-2798 (2008)

[165] Quantitative absorption spectroscopy of a single gold nanorod. O.L. Muskens, G. Bachelier, N. Del Fatti, F. Vall¨¦e, A. Brioude, X.C. Jiang and M.P. Pileni J. Phys. Chem. C 112, 8917-8921 (2008)

[164] 2D self-organization of core/shell Cohcp/Co nanocrystals. I. Lisiecki, M. Walls, D. Parker and M.P. Pileni Langmuir 24, 4295-4299 (2008)

[163] Tuning of solid phase in supracrystals made of silver nanocrystals. A.I. Henry, A. Courty, M.P. Pileni, P.A. Albouy and J. Israelachvili Nano Letters 8, 2000-2005 (2008)

[162] How do self-ordered silver nanocrystals influence their growth into triangular single crystals? A.I. Henry, A. Courty, N. Goubet and M.P. Pileni J. Phys. Chem. C 112, 48-52 (2008)

[161] Difference between the magnetic properties of the magnetotactic bacteria and those of the extracted magnetosomes: Influence of the distance between the chains of magnetosomes.
E. Alphandery, A.T. Ngo, C. Lefevre, I. Lisiecki, L.F. Wu and M.P. Pileni J. Phys. Chem. C 112, 12304-12309 (2008)


¡¾ÁªÏµ·½Ê½¡¿£ºPhone : 33 (0)1 44 27 25 16
Fax : 33 (0)1 44 27 25 15
E-mail : pileni@sri.jussieu.fr

[ Last edited by taijun_2008 on 2009-1-7 at 14:08 ]
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47Â¥2009-01-07 13:34:29
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fanhbu

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kqy920(½ð±Ò+4):лл·ÖÏí£¡»¶Ó­³£À´£¡
¡¾ÐÕ      Ãû¡¿£ºWilson Ho STM¾ø¶ÔµÄ´óÅ£
http://www.physics.uci.edu/~wilsonho/wilsonho.html
Mailing Address:  
Department of Physics and Astronomy
4129 Frederick Reines Hall  
University of California, Irvine, CA  92697-4575
Telephone: (949) 824-5234
Fax: (949) 824-2174



Professor Ho received B.S. and M.S. degrees in chemistry from the California Institute of Technology in 1975 and his Ph.D. in physics from the University of Pennsylvania in 1979. He spent a year at the AT&T Bell Laboratories as a Member of the Technical Staff and was on the faculty of Cornell University prior to joining the UCI faculty in 2000.


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Our research focuses on nanoscale chemical and physical phenomena with an emphasis on probing the basic properties of single atoms and molecules in their nono-environment on solid surfaces. The goal is to obtain detailed descriptions of single atoms and molecules which form the basis for understanding chemical and physical processes at surfaces and properties of nanostructured condensed matter and molecular materials.

The understanding of matter and its interactions with the surrounding at the atomic and molecular level is the central theme of our research program. The ability to control chemistry at the level of individual atoms and molecules underpins the way they interact and use the available energy to affect chemical transformation. The study of magnetism down to single atoms allows the understanding of how the electron spins play a role in chemical and physical processes.

The scanning tunneling microscope (STM) is a tool which not only allows us literally to see individual atoms and molecules but also to manipulate and spectroscopically characterize them. It is an all-purpose tool and is in effect a nanoreactor carrying out reactions with atoms and molecules in the nanocavity of the tunnel junction. Since the coupling of electrons to the nuclear motions provides the driving force for chemical transformation, the STM with its tunneling electrons can be tuned to induce atomic and molecular motions and to dissociate and form chemical bonds.

Tunneling electrons can be spin polarized. The STM can be used to probe magnetism and the effect of magnetic impurity on superconductivity and other solid state phenomena associated with the electron spin.
Selected Publications
Single Molecule Chemistry by Tunneling Electrons. Physical Review Letters 1997, 78, 4410. B.C. Stipe, M.A. Rezaei, W. Ho, S. Gao, M. Persson, and B.I. Lundqvist.

Inducing and Viewing the Rotational Motion of a Single Molecule. Science 1998, 279, 1907. B.C. Stipe, M.A. Rezaei, and W. Ho.

Single-Molecule Vibrational Spectroscopy and Microscopy. Science 1998, 280, 1732. B.C. Stipe, M.A. Rezaei, and W. Ho.

Coupling of Vibrational Excitation to the Rotational Motion of a Single Adsorbed Molecule. Physical Review Letters 1998, 81, 1263. B.C. Stipe, M.A. Rezaei, and W. Ho.

Localization of Inelastic Tunneling and the Determination of Atomic-Scale Structure with Chemical Sensitivity. Physical Review Letters 1999, 82, 1724. B.C. Stipe, M.A. Rezaei, and W. Ho.

Single Bond Formation and Characterization with a Scanning Tunneling Microscope. Science 1999, 286, 1719. H.J. Lee and W. Ho.

Control and Characterization of a Multistep Unimolecular Reaction. Physical Review Letters 2000, 84, 1527. L.J. Lauhon and W. Ho.

Electronic Resonance and Symmetry in Single-Molecule Inelastic Electron Tunneling. Physical Review Letters 2000, 85, 1915. J.R. Hahn, H.J. Lee, and W. Ho.

Vibrationally-Mediated Negative Defferential Resistance in a Single Molecule. Physical Review Letters 2000, 85, 1918. J. Gaudioso, L.J. Lauhon, and W. Ho.

Direct Observation of the Quantum Tunneling of Single Hydrogen Atoms with a Scanning Tunneling Microscope. Physical Review Letters 2000, 85, 4566. L.J. Lauhon and W. Ho
48Â¥2009-01-07 22:39:58
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¡¾ÐÕ      Ãû¡¿£ºGeorge M. Whitesides  ¾ø¶ÔµÄ»¯Ñ§½ç´óÅ£ ÏÄÓ×Äв©Ê¿Àϰå ÎÄÕÂ×ÜÒýÓÃÊýλ¾Ó»¯Ñ§½çǰ5
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Surface Science
Microcontact Printing of Self-Assembled Monolayers
Electrochemical Desorption of Self-Assembled Monolayers
Surface Analytical Techniques


Select Publications

1. Laibinis, P. E. et al. "Orthogonal self-assembled monolayers: alkanethiols on gold and alkane carboxylic acids on alumina." Science (1989), 245(4920), 845-7.

2. Abbott, N. L., Folkers, J. P. and Whitesides, G. M. "Manipulation of the wettability of surfaces on the 0.1- to 1-micrometer scale through micromachining and molecular self-assembly." Science (1992), 257(5075), 1380-2.

3. Kumar, A., Biebuyck, H. A. and Whitesides, G. M. "Patterning Self-Assembled Monolayers: Applications in Materials Science." Langmuir (1994), 10(5), 1498-511.

4. Wilbur, J. L. et al. "Microcontact printing of self-assembled monolayers: applications in microfabrication." Nanotechnology (1996), 7(4), 452-457.

5. Kane, R. S. et al. "Patterning proteins and cells using soft lithography." Biomaterials (1999), 20(23/24), 2363-2376.

6. Jiang, X. et al. "Electrochemical desorption of self-assembled monolayers noninvasively releases patterned cells from geometrical confinements." JACS (2003), 125, 2366-2367.
Title: FORMATION OF MONOLAYER FILMS BY THE SPONTANEOUS ASSEMBLY OF ORGANIC THIOLS FROM SOLUTION ONTO GOLD
Author(s): BAIN CD, TROUGHTON EB, TAO YT, et al.
Source: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   Volume: 111   Issue: 1   Pages: 321-335   Published: JAN 4 1989
Times Cited: 2,385
  
2.  Title: MOLECULAR SELF-ASSEMBLY AND NANOCHEMISTRY - A CHEMICAL STRATEGY FOR THE SYNTHESIS OF NANOSTRUCTURES
Author(s): WHITESIDES GM, MATHIAS JP, SETO CT
Source: SCIENCE   Volume: 254   Issue: 5036   Pages: 1312-1319   Published: NOV 29 1991
Times Cited: 1,600
  
3.  Title: Geometric control of cell life and death
Author(s): Chen CS, Mrksich M, Huang S, et al.
Source: SCIENCE   Volume: 276   Issue: 5317   Pages: 1425-1428   Published: MAY 30 1997
Times Cited: 1,442
  
4.  Title: Rapid prototyping of microfluidic systems in poly(dimethylsiloxane)
Author(s): Duffy DC, McDonald JC, Schueller OJA, et al.
Source: ANALYTICAL CHEMISTRY   Volume: 70   Issue: 23   Pages: 4974-4984   Published: DEC 1 1998
Times Cited: 1,236
  
5.  Title: COMPARISON OF THE STRUCTURES AND WETTING PROPERTIES OF SELF-ASSEMBLED MONOLAYERS OF NORMAL-ALKANETHIOLS ON THE COINAGE METAL-SURFACES, CU, AG, AU
Author(s): LAIBINIS PE, WHITESIDES GM, ALLARA DL, et al.
Source: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   Volume: 113   Issue: 19   Pages: 7152-7167   Published: SEP 11 1991
Times Cited: 1,107
  
6.  Title: Soft lithography
Author(s): Xia YN, Whitesides GM
Source: ANNUAL REVIEW OF MATERIALS SCIENCE   Volume: 28   Pages: 153-184   Published: 1998
Times Cited: 962

7.  Title: Self-assembly at all scales
Author(s): Whitesides GM, Grzybowski B
Source: SCIENCE   Volume: 295   Issue: 5564   Pages: 2418-2421   Published: MAR 29 2002
Times Cited: 949
  
8.  Title: Self-assembled monolayers of thiolates on metals as a form of nanotechnology
Author(s): Love JC, Estroff LA, Kriebel JK, et al.
Source: CHEMICAL REVIEWS   Volume: 105   Issue: 4   Pages: 1103-1169   Published: APR 2005
Times Cited: 907
  
9.  Title: FEATURES OF GOLD HAVING MICROMETER TO CENTIMETER DIMENSIONS CAN BE FORMED THROUGH A COMBINATION OF STAMPING WITH AN ELASTOMERIC STAMP AND AN ALKANETHIOL INK FOLLOWED BY CHEMICAL ETCHING
Author(s): KUMAR A, WHITESIDES GM
Source: APPLIED PHYSICS LETTERS   Volume: 63   Issue: 14   Pages: 2002-2004   Published: OCT 4 1993
Times Cited: 853
  
10.  Title: SELF-ASSEMBLED ORGANIC MONOLAYERS - MODEL SYSTEMS FOR STUDYING ADSORPTION OF PROTEINS AT SURFACES
Author(s): PRIME KL, WHITESIDES GM
Source: SCIENCE   Volume: 252   Issue: 5009   Pages: 1164-1167   Published: MAY 24 1991
Times Cited: 853

[ Last edited by fanhbu on 2009-1-7 at 22:52 ]
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