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戴宏杰
Hongjie Dai's research lab at Stanford University
The research of Dai group interfaces with chemistry, physics, materials science and biophysics. We are interested in solid state and soft condensed materials that have well-defined atomic structures. Ongoing projects include developing new synthetic routes to ordered nanomaterial architectures; electrical, mechanical, electromechanical and electrochemical characterizations at the nanoscale; and probing the real-space structures and functions of biological molecules. Our work are in the areas of material chemistry, inorganic synthesis, solid state physics, electron transport and scanning probe microscopy.
A specific research program involves the development of new synthesis methods to obtain ordered carbon nanotube architectures on surfaces. These novel nanowire architectures are ideal model systems for addressing fundamental physics problems in low dimensions, and for future device applications. Our overall approach involves the combination of inorganic synthesis of mesoporous catalytic materials and chemical vapor deposition with microfabrication techniques. With the synthesized nanowire architectures, we are carrying out electrical and electromechanical measurements of individual nanotube molecular wires, aimed to understand the properties of quasi-one-dimensional solids, elucidating quantum mechanical effects in small systems, and explore their applications in future miniaturized devices.
Another project involves using scanning probe microscopy techniques to probe the structural properties of biological macromolecules, and elucidate the interactions between individual molecular pairs. Our approach involves the development of atomic force microscopy probes that are tipped by individual nanotubes that are as small as ten angstroms in diameter. Such a molecular tip should allow structural imaging of biological systems with unprecedented resolution and sensitivity. We are also interested in electrochemical studies of biological systems using chemically functionalized nanotube electrodes.
Research Projects
From basic science in physical chemistry, materials chemistry and solid state physics to molecular electronics, nanoelectronics, and nanobiotechnology
(1) Carbon nanotubes chemistry and physics
(1.1) Synthesis.
(1.2) Electrical, mechanical, electromechanical, electro-thermal and electro-optical properties of single nanotube molecules.
(2) Molecular electronics
(2.1) Pushing the performance limit of nanoscale transistors.
(2.2) Molecular organic molecule transistors.
(3) Semiconducting nanowires.
(4) Surface science and functionalization
(5) Nano-biotechnology and Nanomedicine
(5.1). Single walled carbon nanotubes for in vitro drug and gene delivery
(5.2). In vivo behaviors and long term fate of carbon nanotubes
(5.3). Preliminary efforts in cancer treatment by nanotechnology
(5.4). Carbon nanotubes for biological imaging
(5.5). Extension to other novel nano-materials
(6) Graphene
(6.1) Synthesis
(6.2) Nano-electronics
(6.3) Quantum electrical transport
Publications
144 Won Seok Seo, Se Mi Kim, Young-Min Kim, Xiaoming Sun, and Hongjie Dai. “Synthesis of Ultrasmall Ferromagnetic Face-Centered Tetragonal FePt–Graphite Core–Shell Nanocrystals” small 4, 11, 1968–1971. 2008
143 Zhuo Chen, Scott M Tabakman, Andrew P Goodwin, Michael G Kattah, Dan Daranciang, Xinran Wang, Guangyu Zhang, Xiaolin Li, Zhuang Liu, Paul J Utz, Kaili Jiang, Shoushan Fan & Hongjie Dai. “Protein microarrays with carbon nanotubes as multicolor Raman labels” Nature Biotechnology Vol. 26, No. 11, 1285-1292, November 2008
142 Zhuang Liu, Xiaolin Li, Scott M. Tabakman, Kaili Jiang, Shoushan Fan, and Hongjie Dai. “Multiplexed Multicolor Raman Imaging of Live Cells with Isotopically Modified Single Walled Carbon Nanotubes” J. AM. CHEM. SOC. 130, 13540–13541, 2008
141 Xiaoming Sun, Zhuang Liu, Kevin Welsher, Joshua Tucker Robinson, Andrew Goodwin, Sasa Zaric, and Hongjie Dai. “Nano-Graphene Oxide for Cellular Imaging and Drug Delivery” Nano Res 1: 203-212, 2008
140 Adam de La Zerda, Cristina Zavaleta, Shay Keren, Srikant Vaithilingam, Sunil Bodapati, Zhuang Liu, Jelena Levi, Bryan R. Smith, Te-Jen Ma, Omer Oralkan, Zhen Cheng, Xiaoyuan Chen, Hongjie Dai, Butrus T. Khuri-Yakub and Sanjiv S. Gambhir. “Carbon Nanotubes As Photoacoustic Molecular Imaging Agents In Living Mice” Nature Nanotechnology Vol. 3, 556-562, September 2008
139 Xiaolin Li, Guangyu Zhang, Xuedong Bai, Xiaoming Sun, Xinran Wang, Enge Wang, and Hongjie Dai. “Highly conducting graphene sheets and Langmuir–Blodgett films” Nature Nanotechnology Vol. 3, 538-542, September 2008
138 Shanta Dhar, Zhuang Liu, Jürgen Thomale, Hongjie Dai, and Stephen J. Lippard. “Targeted Single-Wall Carbon Nanotube-Mediated Pt(IV) Prodrug Delivery Using Folate as a Homing Device” J. AM. CHEM. SOC. 130, 11467–11476, 2008
137 Zhuang Liu, Joshua T. Robinson, Xiaoming Sun, and Hongjie Dai. “PEGylated Nanographene Oxide for Delivery of Water-Insoluble Cancer Drugs” J. AM. CHEM. SOC. 130, 10876–10877, 2008
136 Zhuang Liu, Kai Chen, Corrine Davis, Sarah Sherlock, Qizhen Cao, Xiaoyuan Chen, and Hongjie Dai. “Drug Delivery with Carbon Nanotubes for In vivo Cancer Treatment” Cancer Res. 68: (16), 6652-6660, August 15, 2008
135 Islam Hamad, A. Christy Hunter, Kenneth J. Rutt, Zhuang Liu, Hongjie Dai, S. Moein Moghimi, “Complement activation by PEGylated single-walled carbon nanotubes is independent of C1q and alternative pathway turnover” Molecular Immunology 45, 3797–3803, 2008
134 Xinran Wang, Scott M. Tabakman, and Hongjie Dai. “Atomic Layer Deposition of Metal Oxides on Pristine and Functionalized Graphene” J. AM. CHEM. SOC. 130, 8152–8153, 2008
133 Xiaoming Sun, Sasa Zaric, Dan Daranciang, Kevin Welsher, Yuerui Lu, Xiaolin Li, and Hongjie Dai. “Optical Properties of Ultrashort Semiconducting Single-Walled Carbon Nanotube Capsules Down to Sub-10 nm” J. AM. CHEM. SOC. 130, 6551–6555, 2008
132 Xinran Wang, Yijian Ouyang, Xiaolin Li, Hailiang Wang, Jing Guo, and Hongjie Dai. “Room-Temperature All-Semiconducting Sub-10-nm Graphene Nanoribbon Field-Effect Transistors” Physical Review Letters, Vol.100, No.20, 206803, 20 May 2008
131 M. A. Panzer, G. Zhang, D. Mann, X. Hu, E. Pop, H. Dai, and K. E. Goodson. “Thermal Properties of Metal-Coated Vertically Aligned Single-Wall Nanotube Arrays” Journal of Heat Transfer, Vol. 130, 052401, May 2008
130 Meike L. Schipper, Nozomi Nakayama-Ratchford, Corrine R. Davis, Nadine Wong Shi Kam, Pauline Chu, Zhuang Liu, Xiaoming Sun, Hongjie Dai, and Sanjiv S. Gambhir. “A pilot toxicology study of single-walled carbon nanotubes in a small sample of mice” Nature Nanotechnology, Vol. 3, 216-221, 2008
129 Kevin Welsher, Zhuang Liu, Dan Daranciang and Hongjie Dai. “Selective Probing and Imaging of Cells with Single Walled Carbon Nanotubes as Near-Infrared Fluorescent Molecules.” Nano Lett. Vol. 8, No. 2, 586-590, 2008
128 Li Zhang, Sasa Zaric, Xiaomin Tu, Xinran Wang, Wei Zhao, and Hongjie Dai. “Assessment of Chemically Separated Carbon Nanotubes for Nanoelectronics” J. AM. CHEM. SOC., 130, 2686-2691,2008
127 Zhuang Liu, Corrine Davis, Weibo Cai, Lina He, Xiaoyuan Chen, and Hongjie Dai. “Circulation and long-term fate of functionalized, biocompatible single-walled carbon nanotubes in mice probed by Raman spectroscopy” PNAS, Vol. 105, No. 5, 1410–1415, February 5, 2008
126 Xiaolin Li, Xinran Wang, Li Zhang, Sangwon Lee, and Hongjie Dai. “Chemically Derived, Ultrasmooth Graphene Nanoribbon Semiconductors” Science, Vol. 319, 1229-1232, February 29, 2008
125 Anton Nikitin, Xiaolin Li, Zhiyong Zhang, Hirohito Ogasawara, Hongjie Dai, and Anders Nilsson*. “Hydrogen Storage in Carbon Nanotubes through the Formation of Stable C-H Bonds” Nano Lett., Vol. 8, No. 1, 162-167, 2008
124 Xinran Wang, Li Zhang, Yuerui Lu, and Hongjie Dai, Y. K. Kato, Eric Pop. “Electrically driven light emission from hot single-walled carbon nanotubes at various temperatures and ambient pressures” APPLIED PHYSICS LETTERS, 91, 261102, 2007
123 Xiaolin Li, Xiaomin Tu, Sasa Zaric, Kevin Welsher, Won Seok Seo, Wei Zhao, and Hongjie Dai*. “Selective Synthesis Combined with Chemical Separation of Single-Walled Carbon Nanotubes for Chirality Selection” J. AM. CHEM. SOC., Vol. 129, 15770-15771, 2007
122 Zhuang Liu, Xiaoming Sun, Nozomi Nakayama-Ratchford, and Hongjie Dai*. “Supramolecular Chemistry on Water-Soluble Carbon Nanotubes for Drug Loading and Delivery” ACS NANO, Vol. 1, No. 1, 50-56, 2007
121 Rodney P. Feazell, Nozomi Nakayama-Ratchford, Hongjie Dai, and Stephen J. Lippard. “Soluble Single-Walled Carbon Nanotubes as Longboat Delivery Systems for Platinum(IV) Anticancer Drug Design” J. AM. CHEM. SOC., Vol. 129, 8438-8439, 2007
120 Ryan Tu, Li Zhang, Yoshio Nishi, and Hongjie Dai. “Measuring the Capacitance of Individual Semiconductor Nanowires for Carrier Mobility Assessment” Nano Letters, Vol.7, No. 6, 1561-1565, 2007
119 Eric Pop, David A. Mann, Kenneth E. Goodson, Hongjie Dai. “Electrical and thermal transport in metallic single-wall carbon nanotubes on insulating substrates” J. Appl. Phys. 101, 093710, 2007
118 Zhuang Liu, Mark Winters, Mark Holodniy, Hongjie Dai. “siRNA Delivery into Human T Cells and Primary Cells with Carbon-Nanotube Transporters” Angew. Chem. Int. Ed. 46, 2023 –2027, 2007
117 Nozomi Nakayama-Ratchford, Sarunya Bangsaruntip, Xiaoming Sun, Kevin Welsher, Hongjie Dai. “Noncovalent Functionalization of Carbon Nanotubes by Fluorescein-Polyethylene Glycol: Supramolecular Conjugates with pH-Dependent Absorbance and Fluorescence” JACS Communications [Online] February 7, 2007
116 Zhuang Liu, Weibo Cai, Lina He, Nozomi Nakayama, Kai Chen, Xiaoming Sun, Xiayuan Chen, Hongjie Dai. "In vivo biodistribution and highly efficient tumour targeting of carbon nanotubes in mice" Nature Nanotechnology, Vol. 2, 47-52, January 2007
115 David Mann, Y. K. Kato, Anika Kinkhabwala, Eric Pop, Jien Cao, Xinran Wang, Li Zhang, Qian Wang, Jing Guo, Hongjie Dai. "Electrically driven thermal light emission from individual single-walled carbon "Nature Nanotechnology, Vol. 2, 33-38, January 2007
114 Guangyu Zhang, Pengfei Qi, Xinran Wang, Yuerui Lu, Xiaolin Li, Ryan Tu, Sarunya Bangsaruntip, David Mann, Li Zhang, Hongjie Dai. "Selective Etching of Metallic Carbon Nanotubes by Gas-Phase Reaction" Science, Vol 314, 974-977, 10 Nov 2006
113 Li Zhang, Ryan Tu, and Hongjie Dai. "Parallel Core-Shell Metal-Dielectric-Semiconductor Germanium Nanowires for High-Current Surround-Gate Field-Effect Transistors" Nano Letters, vol. 6, No. 12. 2785-2789, 2006
112 Won Seok Seo, Jin Hyung Lee, Xiaoming Sun, Yoriyasu Suzuki, David Mann, Zhuang Liu, Masahiro Terashima, Philip C. Yang, Michael V. McConnell, Dwight G. Nishimura, and Hongjie Dai. "FeCo/graphitic-shell nanocrystals as advancedmagnetic-resonance-imaging and near-infrared agents"Nature Materials, VOL 5, 971, 2006
111 Hongjie Dai, Ali Javey, Eric Pop, David Mann and Yuerui Lu. "Electrical Transport Properties and Field-Effect Transistors of Carbon Nanotubes" NANO: Brief Reports and Reviews, vol. 1, No. 1, 1-4, 2006
110 D. Wang, H. Dai, "Germanium nanowires: from synthesis, surface chemistry, and assembly to devices" Appl. Phys. A 85, 217-225, 2006
109 Guangyu Zhang, Pengfei Qi, Xinran Wang, Yuerui Lu, David Mann, Xiaolin Li, and Hongjie Dai, "Hydrogenation and Hydrocarbonation and Etching of Single-Walled Carbon Nanotubes" J. AM. CHEM. SOC. 128, 6026-6027, 2006
108 Yuerui Lu, Sarunya Bangsaruntip, Xinran Wang, Li Zhang, Yoshio Nishi, and Hongjie Dai, "DNA Functionalization of Carbon Nanotubes for Ultrathin Atomic Layer Deposition of High K Dielectrics for Nanotube Transistors with 60 mV/Decade Switching" J. AM. CHEM. SOC. 128, 3518-3519, 2006
107 E. Pop, D. Mann, J. Reifenberg, K. E. Goodson and H. Dai, "Electro-Thermal Transport in Metallic Single-Wall Carbon Nanotubes for Interconnect Applications," IEEE Intl. Electron Devices Meeting (IEDM), Washington, DC., Dec. 2005
106 E. Pop, D. Mann, Q. Wang, K. E. Goodson and H. Dai, "Thermal Conductance of an Individual Single-Wall Carbon Nanotube above Room Temperature," Nano Letters, vol. 6, no. 1, p. 96, 2006
105 David Mann, Eric Pop, Jien Cao, Qian Wang, Kenneth Goodson, and Hongjie Dai "Thermally and Molecularly Stimulated Relaxation of Hot Phonons in Suspended Carbon Nanotubes" Physical Letters B 110, 1502-1505 2006
104 A. Nikitin, H. Ogasawara, D. Mann, R. Denecke, Z. Zhang, H. Dai, K. Cho, and A. Nilsson, "Hydrogenation of Single-Walled Carbon Nanotubes" Phys. Rev. Lett. 95, 225507 2005.
103 Nadine Wong Shi Kam, Zhuang Liu, and Hongjie Dai "Carbon Nanotubes as Intracellular Transporters for Proteins and DNA: An Investigation of the Uptake Mechanism and Pathway" Angew. Chem. Int. Ed., 44, 1 – 6, 2005
102 Guangyu Zhang, David Mann, Li Zhang, Ali Javey, Yiming Li, Erhan Yenilmez, Qian Wang, James P. McVittie, Yoshio Nishi,, James Gibbons, and Hongjie Dai, "Ultra-high-yield growth of vertical single-walled carbon nanotubes: Hidden roles of hydrogen and oxygen" PNAS 102 no. 45 16141–16145 2005
101 Woong Kim, Ali Javey, Ryan Tu, Jien Cao, Qian Wang, and Hongjie Dai, "Electrical contacts to carbon nanotubes down to 1 nm in diameter", APPLIED PHYSICS LETTERS 87, 173101 2005 |
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