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¡¾Ñо¿·½Ïò¡¿£ºTheir research centers on the development of new chemistry, physics, and technological applications of nanomaterials -- a novel class of  materials with feature size <100 nm. New technologies will emerge from these materials that can improve the way we live just as microtechnology has done over the past several decades.
1. Understanding and Control of Nanomaterial Synthesis
2. Colloidal Self-Assembly and Photonic Crystals
3. Biomedical Applications of Nanomaterials




¡¾¸öÈ˼òÀú¡¿£ºDr. Younan Xia is the McKelvey Professor of Biomedical Engineering appointment in Biochemistry and Radiology at Washington University in St. Louis.

Dr. Xia received his Ph.D. degree in physical chemistry from Harvard University (with Prof. George M. Whitesides) in 1996, M.S. degree in inorganic chemistry from University of Pennsylvania (with Prof. Alan G. MacDiarmid) in 1993, and B.S. degree in chemical physics from the University of Science and Technology of China (USTC) in 1987.  He came to the United States in 1991.

Dr. Xia has received a number of prestigious awards that include the 2006 NIH Director's Pioneer Award (NDPA), Leo Hendrik Baekeland Award (2005), Camille Dreyfus Teacher Scholar (2002), David and Lucile Packard Fellow in Science and Engineering (2000), Alfred P. Sloan Research Fellow (2000), NSF Early Career Development Award (2000), ACS Victor K. LaMer Award (1999), and Camille and Henry Dreyfus New Faculty Award (1997).

Dr. Xia is an Associate Editor of Nano Letters and sits on the Advisory Board of Nano Today (2006-), Langmuir (2005-), Chemistry of Materials (2005-), International Journal of Nanoscience (2004-), International Journal of Nanotechnology (2004-), and Advanced Functional Materials (2001-).  He has also served as a Guest Editor of Advanced Materials five times and MRS Bulletin one time.  He is a member of ACS, MRS, APS, and AAAS.

¡¾ÁªÏµ·½Ê½¡¿£ºDepartment of Chemistry University ofWashington Seattle,WA 98195-1700 (USA)

E-mail£ºxia@chem.washington.edu
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lPeng Q, Dong YJ, Li YD*ZnSe semiconductor hollow microspheres, Angew. Chem. Int. Edit. 42 (26): 3027-3030, 2003

lSun XM, Li YD* Colloidal carbon spheres and their Core/shell structures with noble metal nanoparticles, Angew. Chem. Int. Edit., 43(5): 597-601, 2004

lLiu JF, Li QH, Wang TH, Yu DP, Li YD* Metastable vanadium dioxide nanobelts: Hydrothermal synthesis, electrical transport, and magnetic properties, Angew. Chem. Int. Edit., 43 (38): 5048-5052, 2004

lDeng H, Li XL, Peng Q, Wang X, Chen JP, Li YD* Monodisperse magnetic single-crystal ferrite microspheres, Angew. Chem. Int. Edit. 44 (18): 2782-2785, 2005

lWang LY, Yan RX, Hao ZY, Wang L, Zeng JH, Bao H, Wang X, Peng Q, Li YD* Fluorescence resonant energy transfer biosensor based on upconversion-luminescent nanoparticles,Angew. Chem. Int. Edit., 44 (37): 6054-6057, 2005

lWang X, Zhuang J, Peng Q, Li YD*. A General Strategy for Nanocrystal Synthesis. Nature 437, 121-124, 2005

lWang X, Peng Q, Li YD*, Interface-mediated growth of monodispersed nanostructures, Acc. Chem. Res, 40, 635-643, 2007

lBai F, Wang DS, Huo ZY, Li YD*, et al., A versatile bottom-up assembly approach to colloidal spheres from nanocrystals, Angew. Chem. Int. Ed., 46, 6650-6653, 2007

lWang DS, Xie T, Li YD*, et al., Ag, Ag2S, and Ag2Se nanocrystals: Synthesis, assembly, and construction of mesoporous structures, J. Am. Chem. Soc. 130, 4016-4022, 2008

lWang LY, Li P, Li YD*, et al., Carboxylic acid enriched nanospheres of semiconductor nanorods for cell imaging, Angew. Chem. Int. Ed.,47, 1054-1057, 2008

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1. Sun XM, Li YD* Ga2O3 and GaN semiconductor Hollow Spheres Angew. Chem. Int. Edit., 2004, in press

2. Ge JP, Li YD* A General APCVD Synthesis and Crystallographic Study to Transition Metal Sulfide One-dimensional Nanostructures, Chem.-Eur. J, 2004, in press

3. Wang X, Zhuang J, Chen J, Zhou KB, Li YD* Thermally Stable Silicate Nanotubes, Angew. Chem. Int. Edit., 43: 2017-2020, 2004

4. Sun XM, Li YD* Colloidal carbon spheres and their Core/shell structures with noble metal nanoparticles Angew. Chem. Int. Edit., 43(5): 597-601, 2004

5. Ge JP, Li YD Selective atmospheric pressure chemical vapor deposition route to CdS arrays, nanowires, and nanocombs, Adv. Funct. Mater. 14 (2): 157-162, 2004

6. Li XL, Li YD* Synthesis of scroll-type composites microtubes of Mo2C/MoCO by controlled pyrolysis of Mo(CO)6, Chem.-Eur. J 10 (2): 433-439, 2004

7. Li WJ, Wang X, Li YD* Single-Step in Situ Synthesis of Double bond-Grafted Yttrium-hydroxide Nanotube Composites, Chem. Commun (2): 164-165, 2004

8. Wang X, Li YD* Rare earth compounds nanowires, nanotubes and fullerene-like nanoparticles: synthesis, characterization and properties Chem.-Eur. J, 9 (22): 5627-5635, 2003.

9. Peng Q, Dong YJ, Li YD* ZnSe semiconductor hollow microspheres Angew. Chem. Int. Edit. 42 (26): 3027-3030, 2003

10. Wang X, Li YD* Fullerene-like rare-earth nanoparticles Angew. Chem. Int. Edit. 42 (30): 3497-3500, 2003

11. Wang X, Sun XM, Li YD* et al. Rare earth compound nanotubes Adv. Mater. 15 (17): 1442-1445, 2003

12. Wang JW, Li YD* Rational synthesis of metal nanotubes and nanowires from lamellar structures Adv. Mater. 15 (5): 445-447, 2003

13. Li XL, Li YD* Formation MoS2 inorganic fullerenes (IFs) by the reaction of MoO3 nanobelts and S, Chem.-Eur. J 9 (12): 2726-2731, 2003

14. Sun XM, Li YD* Synthesis and characterization of ion-exchangeable titanate nanotubes Chem.-Eur. J 9 (10): 2229-2238, 2003

15. Wang X, Li YD* Synthesis and formation mechanism of manganese dioxide nanowires/nanorods, Chem.-Eur. J 9 (1): 300-306, 2003

16. Ge JP, Li YD* Controllable CVD route to CoS and MnS single-crystal nanowires Chem. Commun(19): 2498-2499, 2003

17. Wang JW, Li YD* Synthesis of single-crystalline nanobelts of ternary bismuth oxide bromide with different compositions Chem. Commun (18): 2320-2321, 2003

18. Sun XM, Li YD* Size-controllable luminescent single crystal CaF2 nanocubes Chem. Commun (14): 1768-1769, 2003

19. Peng Q, Dong YJ, Li YD* Synthesis of uniform CoTe and NiTe semiconductor nanocluster wires through a novel coreduction method Inorg. Chem. 42 (7): 2174-2175, 2003

20. Deng ZX, Li LB, Li YD* Novel inorganic-organic-layered structures: Crystallographic understanding of both phase and morphology formations of one-dimensional CdE (E = S, Se, Te) nanorods in ethylenediamine Inorg. Chem. 42 (7): 2331-2341, 2003

21. Dong YJ, Peng Q, Li YD* et al. Synthesis and characterization of an open framework gallium selenide: Ga4Se7(en)(2)center dot(enH)(2) Inorg. Chem. 42 (6): 1794-1796, 2003

22. Li XL, Liu JF, Li YD* Large-scale synthesis of tungsten oxide nanowires with high aspect ratio Inorg. Chem.42 (3): 921-924, 2003

23. Wang X, Li YD* Selected-control hydrothermal synthesis of alpha- and beta-MnO2 single crystal nanowires, J. Am. Chem. Soc. 124 (12): 2880-2881, 2002

24. Li YD*, Li XL, He RR, et al. Artificial lamellar mesostructures to WS2 nanotubes, J. Am. Chem. Soc.124 (7): 1411-1416, 2002

25. Wang X, Li YD* Synthesis and characterization of lanthanide hydroxide single-crystal nanowires Angew. Chem. Int. Edit. 41 (24): 4790-4793, 2002

26. Li YD*, Li XL, Deng ZX, et al. From surfactant-inorganic mesostructures to tungsten nanowires Angew. Chem. Int. Edit.41 (2): 333, 2002

27. Li XL, Liu JF, Li YD* Low-temperature synthesis of large-scale single-crystal molybdenum trioxide (MoO3) nanobelts, Appl. Phys. Lett. 81 (25): 4832-4834, 2002

28. Ge JP, Li YD*, Yang GQ Mechanism of aqueous ultrasonic reaction: controlled synthesis, luminescence properties of amorphous cluster and nanocrystalline CdSe Chem. Commun (17): 1826-1827, 2002

29. Wang X, Li YD* Rational synthesis of alpha-MnO2 single-crystal nanorods Chem. Commun (7): 764-765, 2002

30. Peng Q, Dong YJ, Li YD* et al Selective synthesis and magnetic properties of alpha-MnSe and MnSe2 uniform microcrystals J. Phys. Chem.B 106 (36): 9261-9265, 2002

31. Xu S, Zhou HC, Li YD* et al. Synthesis of size-tunable silver iodide nanowires in reverse miceIles Langmuir 18 (26): 10503-10504, 2002

32. Sun XM, Chen X, Li YD* Large-scale synthesis of sodium and potassium titanate nanobelts Inorg. Chem. 41 (20): 4996-4998, 2002

33. Peng Q, Dong YJ, Li YD* et al Selective synthesis and characterization of CdSe nanorods and fractal nanocrystals Inorg. Chem. 41 (20): 5249-5254, 2002

34. Chen X, Sun XM, Li YD* Self-assembling vanadium oxide nanotubes by organic molecular templates Inorg. Chem.41 (17): 4524-4530, 2002

35. Liang JH, Deng ZX, Li YD* et al Photoluminescence of tetragonal ZrO2 nanoparticles synthesized by microwave irradiation Inorg. Chem.41 (14): 3602-3604, 2002

36. Deng ZX, Wang C, Li YD* et al Structure-directing coordination template effect of ethylenediamine in formations of ZnS and ZnSe nanocrystallites via solvothermal route Inorg. Chem.41 (4): 869-873, 2002

37. Li YD*, Wang JW, Deng ZX, et al. Bismuth nanotubes: A rational low-temperature synthetic route, J. Am. Chem. Soc.123 (40): 9904-9905, 2001

38. Li YD*, Wang ZY, Duan XF, et al. Solvothermal reduction synthesis of InSb nanocrystals Adv. Mater. 13 (2): 145-148, 2001

39. Wang C, Deng ZX, Li YD* The synthesis of nanocrystalline anatase and rutile titania in mixed organic media Inorg. Chem. 40 (20): 5210-5214, 2001

40. Peng Q, Dong YJ, Li YD* et al Low-temperature elemental-direct-reaction route to II-VI semiconductor nanocrystalline ZnSe and CdSe Inorg. Chem. 40 (16): 3840, 2001

41. Li YD*, Sui M, Ding Y, et al. Preparation of Mg(OH)2 nanorods£¬Adv. Mater. 12 (11): 818-821, 2000

42. Wang C, Li YD*, Zhang GH, et al. Synthesis of SnSe in various alkaline media under mild conditions Inorg. Chem.39 (19): 4237-4239, 2000

43. Li YD*, Huang Y, Bai T, et al. ¡°Straightforward conversion route to nanocrystalline monothiooxides of rare earths through a high-temperature colloid technique¡± Inorg. Chem. 39 (15): 3418, 2000

44. Li YD* Yi Ding, and Zhaoyu Wang et al. ¡°A Novel Chemical Route To ZnTe Semiconductor Nanorods¡± Adv. Mater. 11 (10): 847, 1999

45. Li YD* Z. Wang, Y. Ding, ¡°Room Temperature synthesis of Metal Chaleogenides inEthylenediamine¡±, Inorg.Chem. 38 (21): 4737-4740, 1999

46. Li YD* H.Liao and Y.Qian et al. ¡° Novel Solvothermal Synthesis of CdE (E=S,Se,Te) Semiconductor Nanorod. ¡± Inorg. Chem. 38 (7): 1382-1387, 1999

47. Li YD*, Y.Qian, H.Liao et al. ¡°A Reduction-Pyrolysis-Catalysis Synthesis of Diamond¡± Science, 281, 146, 1998

48. Li YD*, X.Duan, H.Liao et al ¡°Self-Regulation Synthesis of Nanocrystalline ZnGa2O4 by Hydrothermal Reaction.¡± Chem. Mater. 10(1), 17, 1998

49. Li YD* H. Liao and Y. Qian et al. ¡°Non-aqueous Synthesis of CdS Nanorod Smiconductor. ¡± Chem. Mater. 10(9), 2301, 1998

50. Li YD*, X. Duan, Y.Qian et al. ¡°Solvothermal Co-reduction Route to the Nanocrystalline III-V Semiconductor InAs.¡± J. Am. Chem. Soc.119(33),7867, 1997

51. Wang X, Sun XM, Xu J, Li YD*, Nanowires and Nanobelts materials, properties and devices, (Chapter 10, Nanowires and Nanotubes of Complex Oxides), Kluwer publisher, American, 2003
12Â¥2008-12-16 14:28:46
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¡¾ÁªÏµ·½Ê½¡¿CHEM 245
Phone: 479-575-4612
FAX: 479-575-4049
xpeng@uark.edu
Publications/Presentations:
Publications after 2000
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1. ¡°Efficient and Color-Tunable Mn-Doped ZnSe Nanocrystal Emitters: Control of Optical Performance via Greener Synthetic Chemistry¡±, Pradhan, Narayan; Peng, Xiaogang, J. Am. Chem. Soc. 2007, ASAP.

2. ¡°Interparticle Influence on Size/Size Distribution Evolution of Nanocrystals¡± Thessing, Jason; Qian, Jianghong; Chen, Haiyan; Pradhan, Narayan; Peng, Xiaogang, J. Am. Chem. Soc. , 2007, ASAP.

3. ¡°Efficient, Stable, Small, and Water-Soluble Doped ZnSe Nanocrystal Emitters as Non-Cadmium Biomedical Labels¡±, Nano Letter, 2007, vol 7, 312-317.

4. ¡°University spin-offs: Opportunity or challenge?¡±, Peng, Xiaogang, Nature Materials (2006), 5(12), 923-925

5. "Initialization and read-out of spins in coupled core-shell quantum dots¡±, Berezovsky, J.; Gywat, O.; Meier, F.; Battaglia, D.; Peng, X.; Awschalom, D. D. Nature Physics (2006), 2(12), 831-834

6. ¡°Crystalline nanoflowers with different chemical compositions and physical properties grown by limited ligand protection¡±, Narayanaswamy, Arun; Xu, Huifang; Pradhan, Narayan; Peng, Xiaogang, Angewandte Chemie, International Edition (2006), 45(32), 5361-5364. (Cover and VIP paper)

7. ¡°Formation of Nearly Monodisperse In2O3 Nanodots and Oriented-Attached Nanoflowers: Hydrolysis and Alcoholysis vs Pyrolysis¡±, Narayanaswamy, Arun; Xu, Huifang; Pradhan, Narayan; Kim, Myeongseob; Peng, Xiaogang, J. Am. Chem. Soc. (2006), 128(31), 10310-10319.

8. "Colloidal CdSe Quantum Wires by Oriented Attachment¡±, Pradhan, Narayan; Xu, Huifang; Peng, Xiaogang, Nano Letters, 2006, 6, 720-724.

9. ¡°Modelling the formation of high aspect CdSe quantum wires: axial-growth versus oriented-attachment mechanisms¡±, Barnard, Amanda S.; Xu, Huifang; Li, Xiaochun; Pradhan, Narayan; Peng, Xiaogang; Nanotechnology, 2006, vol 17, 5707-5714

10. ¡°An Alternative of CdSe Nanocrystal Emitters: Pure and Tunable Impurity Emissions in ZnSe Nanocrystals¡±, Pradhan, N.; Goorskey, D.; Thessing, J.; Peng, X., Am. Chem. Soc., 2005, 127, 17586-17587 (highlighted in Science as ¡°Editor¡¯s Choice¡±)

11. ¡°Side Reactions in Controlling the Quality, Yield, and Stability of High Quality Colloidal Nanocrystals¡±, Chen. Y.; Kim, M.; Lian, G.; Johnson, M. B.; Peng, X. J. Am. Chem. Soc., 2005, 127(38), 13331-13337.

12. ¡°Coupled and Decoupled Dual Quantum Systems in a Semiconductor Nanocrystal¡±, D. Battaglia, N. Mallette, X. Peng, J. Am. Chem. Soc., 2005, vol 127, p 10889-10897.

13. ¡°Size Dependent Dissociation pH of Thiol-coated Cadmium Chalcogenides Nanocrystals¡±, J. Aldana, N. Mallette, X. Peng, J. Am. Chem. Soc., 2005, 127(8), 2496-2504.

14. ¡°Bioreactive Surfaces Prepared via the Self-Assembly of Dendron Thiols and Subsequent Dendrimer Bridging Reactions,¡± Yang M., Tsang E.M.W., Wang Y.A., Peng X., Langmuir, (2005), 21(5), 1858-1865

15. ¡°Spin Dynamics and Level Structure of Quantum-dot Quantum Wells,¡±Berezovsky, Jesse; Ouyang, Min; Meier, Florian; Awschalom, David D.; Battaglia, David; Peng, Xiaogang. Physical Review B: (2005), 71(8), 081309/1-081309/4

16. ¡°Exciton radiative recombination in spherical CdS/CdSe/CdS Quantum-well Nanostructures,¡± Xu, J., Xioa, M., Battaglia, D., Peng, X., Appl. Phys. Lett., (2005), 87(4), 043107/1-043107/3.
8. ¡°Super-stable, High-quality Fe3O4 Dendron-nanocrystals Dispersible in Both Organic and Aqueous Solutions,¡± Kim, M., Chen, Y., Liu, Y., Peng, X., Adv. Mater., (2005), 17(11), 1429-1432.

17. ¡°Photoluminescence from Colloidal CdS-CdSe-CdS Quantum Wells,¡± Xu, J., Battaglia, D., Peng, X., Xiao, M., J. of the Opticla Soc. Of Am. B: Optical Physics, (2005), 22(5), 1112-1116.

18. ¡°High Quality ZnSe and ZnS Nanocrystals Formed by Activating Zinc Carboxylate Precursors¡±, L. Li, N. Pradhan, Y. Wang, X. Peng, Nano Lett., vol 4, 2261-2264

19. ¡°Size- and Shape-Controlled Magnetic (Cr, Mn, Fe, Co, Ni) Oxide Nanocrystals via a Simple and General Approach¡±, N. Jana, Y. Chen, X. Peng, Chem. Mater. 2004, vol 20, p. 3931-3935

20. ¡°Environmental Effects on Photoluminescence of Highly Luminescent CdSe and CdSe/ZnS Core/Shell Nanocrystals in Polymer Thin Films¡± A. Nazzal, X. Wang, L. Qu, W. Yu, Y. Wang, X. Peng, M. Xiao, J. Phys. Chem., 2004, vol 108, p 5507

21. ¡°In Situ Observation of the Nucleation and Growth of CdSe Nanocrystals¡±, L. Qu, W. Yu, X. Peng, Nano Lett., 2004, vol 4, p5507

22. "Photocatalytic activity of gold nanocrystals and its role in determining the stability of surface thiol monolayers¡±, J. J. Li, X. Peng, J. Nanoscience & Nanotechnology, 2004, vol 6, p. 565-568. (invited)

23. ¡°Single-Phase and Gram-Scale Synthesis of Au and Other Noble Metal Nanocrystals¡±, N. R. Jana, X. Peng, J. Am. Chem. Soc., 2003, vol 125, p 14280.

24. ¡°Colloidal Two-Dimensional Systems, CdSe Quantum Shells and Wells¡±, D. Battaglia, J. J. Li, Y. Wang, X. Peng, Angew. Chem. Int. Ed., 2003, vol 43, p 5035.

25. ¡°Large-Scale Synthesis of Nearly Monodisperse CdSe/CdS Core/Shell Nanocrystals Using Air-Stable Reagents via Successive Ion Layer Adsorption and Reaction.¡± J. Li, Y. A. Wang, W. Guo, J. C. Keay, T. D. Mishima, M. B. Johnson, X. Peng. J. Am. Chem. Soc., 2003, vol 125, p 12567.

26. ¡°Luminescent CdSe/CdS Core/Shell Nanocrystals in Dendron Boxes: Superior Chemical, Photochemical and Thermal Stability¡±, W. Guo, J. Li, Y. A. Wang, X. Peng, J. Am. Chem. Soc., 2003, vol 125, p 3901 (highlighted as a ¡°heart cut item¡± in the ACS website)

27. ¡°Photoluminescence upconversion in colloidal CdTe quantum dots¡±, X. Wang, W. Yu, J. Zhang, J. Aldana, X. Peng, M. Xiao, Phys. Rev. B: 2003, vol 68, p 125318.

28. 1 ¡°Formation and Stability of Size-, Shape-, and Structure-Controlled CdTe Nanocrystals: Ligand Effects on Monomers and Nanocrystals¡±, W. W. Yu, Y. A. Wang, X. Peng, Chem. Mater. 2003, p 4300.

29. ¡°Photon-Activated CdSe Nanocrystal Nanosensors for Gases¡±, A. Nazzal, L. Qu, M. Xiao, X. Peng, Nano letters, 2003, vol 3, p 819

30. ¡°Nanocrystal in dendron-box: a versatile solution to the chemical, photochemical, and thermal instability of colloidal nanocrystals¡± Comptes Rendus Chimie, 2003, p 989. (invited)

31. ¡°Mechanisms of Shape Control and Shape Evolution of Colloidal Nanocrystals¡±, Peng, x., Adv. Mater., 2003, vol 15, p 459. (invited)

32. ¡°Evaluation of nonlinear optical properties of cadmium chalcogenide nanomaterials¡±, Ceo, J. T.; Yang, Q.; Creekmore, S.; Temple, D.; Qu, L.; Yu, W.; Wang, A.; Peng, X.; Mott, A.; Namkung, M.; Jung, S. S.; Kim, J. H. Physica E: 2003, vol 17, p 101.

33. ¡°Experimental determination of the size Dependent Extinction Coefficients of High Quality CdTe, CdSe and CdS nanocrystals¡±, W. Yu, L. Qu, W. Guo, X. Peng, Chem. Mater., 2003, vol 15, p 2845.

34. ¡°Conjugation Chemistry and Bio-Applications of Semiconductor Box-Nanocrystals Prepared via Dendrimer-Bridging¡± W. Guo, J. Li, Y. A. Wang, X. Peng, Chem. Mater., 2003, vol 15, p 3125.

35. "Surface-related emission in highly-luminescent CdSe quantum dots¡±, Wang, X.; Qu, L.; Zhang, J.; Peng, X.; and Xiao, M., Nano Letters, 2003, vol 3, p 1103.

36. ¡°Formation of High Quality CdS and Other II-VI Semiconductor Nanocrystals in Non-Coordinating Solvent, Tunable Reactivity of Monomers¡±, Yu W., Peng X., Angew. Chem. Int. Ed., 2002, vol 41, p 2368 (Announced as a ¡°hot paper¡± by the journal)

39. ¡°Green Chemical Approaches toward High Quality Semiconductor Nanocrystals¡±, Peng X., Chem. Eu. J., 2002, vol 8, p 334 (invited concept article).

38. "Control of Photoluminescence Properties of CdSe Nanocrystals in Growth", Qu L., Peng, X., J. Am. Chem. Soc., 2002, vol 124, p 2049.

39. ¡°Stabilize Inorganic Nanocrystals by Organic Dendrons¡±, Wang, Y. A., Li, J. J., Chen, H., Peng, X., J. Am. Chem. Soc., 2002, vol 124, p 2293.

40. ¡°Nearly Monodisperse and Shape-Controlled CdSe Nanocrystals via Alternative Routes: Nucleation and Growth¡± Peng, Z.; Peng, X., J. Am. Chem. Soc., 2002, vol 124, p 3343.

41. ¡°Formation of High Quality InP and InAs Nanocrystals in a Non-Coordinating Solvent¡±, D. Battaglia, Peng, X., Nanolett., 2002, vol 2, p1027

42. ¡°Lattice contraction in free-standing CdSe nanocrystals¡±, J. Zhang, X. Wang, Min Xiao, L. Qu and X. Peng, Appl. Phys. Lett., 2002 vol 81, p 2076

43. ¡°Future directions in solid state chemistry: report of the NSF-sponsored workshop¡±, Cava, Robert J.; et al., Progress in Solid State Chem., 2002, vol 30, p 1.

44. ¡°Photoluminescence from single CdSe quantum rods¡±, Chen, X.; Nazzal, Amjad Y.; Xiao, Min; Peng, Z. Adam; Peng, Xiaogang, J. Luminescence 2002, vol 97, p 205

45. ¡°Synthesis of High Quality Cadmium Chalcogenides Semiconductor Nanocrystals Using CdO as precursor¡±, Peng Z. A., Peng X., J. Am. Chem. Soc., 2001, vol 123, p 168. (highlighted in C&En News)

46. ¡°Mechanisms of the Shape Evolution of CdSe Nanocrystals¡±, Peng Z. A., Peng X., J. Am. Chem. Soc., 2001, vol 123, p 1389.

47. " Photochemical Instability of CdSe Nanocrystals Coated by Hydrophilic Thiols¡±, Aldana J., Wang, Y. A., Peng, X., J. Am. Chem. Soc., 2001, 123, p 8844.

48. ¡°Alternative Routes toward High Quality CdSe Nanocrystals¡±, Qu, L., Peng Z. A., Peng X., Nano Lett., 2001, vol 1, p 333.

49.¡°Polarization Spectroscopy of Single CdSe Quantum Rods¡±, X. Chen, A. Nazzal, D. Goorskey and M. Xiao, Z. A. Peng and X. Peng, Phys. Rev. B., 2001, vol 64, p 245304.

50. ¡°Spin spectroscopy of dark excitons in CdSe quantum dots to 60 T¡±, Johnston-Halperin, E.; Awschalom, D. D.; Crooker, S. A.; Efros, Al. L.; Rosen, M.; Peng, X.; Alivisatos, A. P., Phys. Rev. B, 2001, vol 63, p 205309/1

51. "Shape control of CdSe nanocrystals: from dots to rods and back¡±, Peng X., Mann L., Wickham J., Kadvanish A., Alivisatos A. P., Nature, 2000, vol 404, p 59
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Dr. Shuming Nie is the Wallace H. Coulter Distinguished Chair Professor in Biomedical Engineering at Emory University and the Georgia Institute of Technology, with joint appointments in chemistry, materials science and engineering, and hematology and oncology.  He is the Principal Investigator and Director of the Emory-Georgia Tech Nanotechnology Center for Personalized and Predictive Oncology, one of the eight national centers funded by the National Cancer Institute (NIH/NCI). His research interest is broadly in biomolecular engineering and nanotechnology, with a focus on bioconjugated nanoparticles for cancer molecular imaging, molecular profiling, pharmacogenomics, and targeted therapy.  His research program is currently supported by three large-scale grants from the National Institutes of Health.  During the last 10 years, Professor Nie has published nearly 100 scholarly papers, filed 20 patents/inventions, and has delivered more than 350 invited talks and keynote lectures.  

In recognition of his work, Professor Nie has received many awards and honors including the Merck Award (2007), Elected Fellow of the American Institute of Biological and Medical Engineering (2006), the Cheung Kong Professorship (The Ministry of Education of China, 2006), the Rank Prize in Opto-electronics (London, UK, 2005), the Georgia Distinguished Cancer Scholar Award (Georgia Cancer Coalition, 2002-2007), the Beckman Young Investigator Award, the National Collegiate Inventors Award, and the NSFC Overseas Young Scholar Award. Dr. Nie serves on the scientific advisory/editorial boards of 5 biotech companies and 6 scientific journals. Professor Nie received his BS degree from Nankai University (China) in 1983, earned his MS and PhD degrees from Northwestern University under the direction of Professor Richard P. Van Duyne (1984-1990), and did postdoctoral research at both Georgia Institute of Technology and Stanford University (1990-1994).  

For further information, see the Provost¡¯s Website of Great Scholars at Emory University:
http://www.emory.edu/PROVOST/greatscholars/ShumingNie.htm.
1: Shi C, Zhu Y, Cerwinka WH, Zhau HE, Marshall FF, Simons JW, Nie S, Chung LW.  Quantum Dots: Emerging applications in urologic oncology. Urol Oncol. 2008 Jan-Feb;26(1):86-92. PMID: 18190836 [PubMed - in process]

2: Qian X, Peng XH, Ansari DO, Yin-Goen Q, Chen GZ, Shin DM, Yang L, Young AN,Wang MD, Nie S. In vivo tumor targeting and spectroscopic detection with surface-enhanced Raman nanoparticle tags. Nat Biotechnol. 2008 Jan;26(1):83-90. Epub 2007 Dec 23. PMID: 18157119 [PubMed - in process]

3: Ruan G, Agrawal A, Marcus AI, Nie S. Imaging and tracking of tat peptide-conjugated quantum dots in living cells: new insights into nanoparticle uptake, intracellular transport, and vesicle shedding.
J Am Chem Soc. 2007 Nov 28;129(47):14759-66. Epub 2007 Nov 6.
PMID: 17983227 [PubMed - indexed for MEDLINE]

4: Xing Y, Smith AM, Agrawal A, Ruan G, Nie S.  Molecular profiling of single cancer cells and clinical tissue specimens with semiconductor quantum dots. Int J Nanomedicine. 2006;1(4):473-81. Review. PMID: 17722280 [PubMed - indexed for MEDLINE]

5: Rhyner MN, Smith AM, Gao X, Mao H, Yang L, Nie S.  Quantum dots and multifunctional nanoparticles: new contrast agents for tumor imaging.  Nanomed. 2006 Aug;1(2):209-17. Review. PMID: 17716110 [PubMed - indexed for MEDLINE]

6: Wang MD, Shin DM, Simons JW, Nie S. Nanotechnology for targeted cancer therapy. Expert Rev Anticancer Ther. 2007 Jun;7(6):833-7. Review. PMID: 17555393 [PubMed - indexed for MEDLINE]

7: Xing Y, Chaudry Q, Shen C, Kong KY, Zhau HE, Chung LW, Petros JA, O'Regan RM, Yezhelyev MV, Simons JW, Wang MD, Nie S. Bioconjugated quantum dots for multiplexed and quantitative immunohistochemistry.  Nat Protoc. 2007;2(5):1152-65. PMID: 17546006 [PubMed - indexed for MEDLINE]

8: Agrawal A, Sathe T, Nie S. Single-bead immunoassays using magnetic microparticles and spectral-shifting quantum dots. J Agric Food Chem. 2007 May 16;55(10):3778-82. Epub 2007 Apr 25. PMID: 17455953 [PubMed - indexed for MEDLINE]

9: Nie S, Xing Y, Kim GJ, Simons JW. Nanotechnology applications in cancer. Annu Rev Biomed Eng. 2007;9:257-88. Review. PMID: 17439359 [PubMed - indexed for MEDLINE]

10: Duan H, Nie S. Cell-penetrating quantum dots based on multivalent and endosome-disrupting surface coatings. J Am Chem Soc. 2007 Mar 1;129(11):3333-8. Epub 2007 Feb 24. PMID: 17319667 [PubMed - indexed for MEDLINE]

11: Duan H, Nie S. Etching colloidal gold nanocrystals with yperbranched and multivalent polymers: a new route to fluorescent and water-soluble atomic clusters. J Am Chem Soc. 2007 Mar 7;129(9):2412-3. Epub 2007 Feb 13. No abstract available. PMID: 17295485 [PubMed - indexed for MEDLINE]

12: Wei C, Lyubchenko YL, Ghandehari H, Hanes J, Stebe KJ, Mao HQ, Haynie DT, Tomalia DA, Foldvari M, Monteiro-Riviere N, Simeonova P, Nie S, Mori H, Gilbert SP, Needham D; American Academy of Nanomedicine.  New technology and clinical applications of nanomedicine: highlights of the second annual meeting of the American Academy of Nanomedicine (Part I). Nanomedicine. 2006 Dec;2(4):253-63. PMID: 17292151 [PubMed - indexed for MEDLINE]

13: Wang G, Agrawal A, Nie S, Wang M. Optically encoded nanoparticles for detecting single biomolecules and viruses: rapid analysis of two-color colocalization data by high-speed computing. Conf Proc IEEE Eng Med Biol Soc. 2005;2:1739-42. PMID: 17282550 [PubMed - in process]

14: Young A, Amin M, Petros J, Natan M, Nie S, Wang M.  Nanomolecular histopathology for renal tumor classification. Conf Proc IEEE Eng Med Biol Soc. 2005;1:723-6. PMID: 17282285 [PubMed - in process]

15: Kim G, O'regan R, Nie S.  Biomedical nanotechnology for molecular imaging, profiling, and drug targeting. Conf Proc IEEE Eng Med Biol Soc. 2005;1:714-6. PMID: 17282282 [PubMed - in process]

16: Gao X, Chung LW, Nie S.  Quantum dots for in vivo molecular and cellular imaging. Methods Mol Biol. 2007;374:135-45. PMID: 17237536 [PubMed - indexed for MEDLINE]

17: Sinha R, Kim GJ, Nie S, Shin DM. Nanotechnology in cancer therapeutics: bioconjugated nanoparticles for drug delivery.
Mol Cancer Ther. 2006 Aug;5(8):1909-17. Review. PMID: 16928810 [PubMed - indexed for MEDLINE]

18: Sathe TR, Agrawal A, Nie S. Mesoporous silica beads embedded with semiconductor quantum dots and iron oxide nanocrystals: dual-function microcarriers for optical encoding and magnetic separation.  Anal Chem. 2006 Aug 15;78(16):5627-32. PMID: 16906704 [PubMed - indexed for MEDLINE]

19: Yezhelyev MV, Gao X, Xing Y, Al-Hajj A, Nie S, O'Regan RM.
Emerging use of nanoparticles in diagnosis and treatment of breast cancer. Lancet Oncol. 2006 Aug;7(8):657-67. Review. PMID: 16887483 [PubMed - indexed for MEDLINE]

20: Emory SR, Jensen RA, Wenda T, Han M, Nie S. Re-examining the origins of spectral blinking in single-molecule and single-nanoparticle SERS. Faraday Discuss. 2006;132:249-59; discussion 309-19. PMID: 16833120 [PubMed - indexed for MEDLINE]

21: Smith AM, Dave S, Nie S, True L, Gao X.  Multicolor quantum dots for molecular diagnostics of cancer. Expert Rev Mol Diagn. 2006 Mar;6(2):231-44. Review. PMID: 16512782 [PubMed - indexed for MEDLINE]

22: Agrawal A, Zhang C, Byassee T, Tripp RA, Nie S.  Counting single native biomolecules and intact viruses with color-coded nanoparticles. Anal Chem. 2006 Feb 15;78(4):1061-70. PMID: 16478096 [PubMed - indexed for MEDLINE]

23: Smith AM, Ruan G, Rhyner MN, Nie S. Engineering luminescent quantum dots for in vivo molecular and cellular imaging.Ann Biomed Eng. 2006 Jan;34(1):3-14. Epub 2006 Feb 1. Review. PMID: 16450199 [PubMed - indexed for MEDLINE]

24: Ferrara DE, Weiss D, Carnell PH, Vito RP, Vega D, Gao X, Nie S, Taylor WR. Quantitative 3D fluorescence technique for the analysis of en face preparationsof arterial walls using quantum dot nanocrystals and two-photon excitation laser scanning microscopy. Am J Physiol Regul Integr Comp Physiol. 2006 Jan;290(1):R114-23. Epub 2005 Oct13.  PMID: 16223849 [PubMed - indexed for MEDLINE]

25: Agrawal A, Tripp RA, Anderson LJ, Nie S. Real-time detection of virus particles and viral protein expression with two-color nanoparticle probes. J Virol. 2005 Jul;79(13):8625-8. PMID: 15956604 [PubMed - indexed for MEDLINE]

26: Gao X, Nie S. Quantum dot-encoded beads. Methods Mol Biol. 2005;303:61-71. PMID: 15923675 [PubMed - indexed for MEDLINE]

27: Gao X, Yang L, Petros JA, Marshall FF, Simons JW, Nie S.
In vivo molecular and cellular imaging with quantum dots.  Curr Opin Biotechnol. 2005 Feb;16(1):63-72. Review.  PMID: 15722017 [PubMed - indexed for MEDLINE]

28: Smith AM, Gao X, Nie S.  Quantum dot nanocrystals for in vivo molecular and cellular imaging. Photochem Photobiol. 2004 Nov-Dec;80(3):377-85. Review. PMID: 15623319 [PubMed - indexed for MEDLINE]

29: Haes AJ, Stuart DA, Nie S, Van Duyne RP.  Using solution-phase nanoparticles, surface-confined nanoparticle arrays and single nanoparticles as biological sensing platforms. J Fluoresc. 2004 Jul;14(4):355-67. Review. PMID: 15617378 [PubMed - indexed for MEDLINE]

30: Bailey RE, Strausburg JB, Nie S.  A new class of far-red and near-infrared biological labels based on alloyed semiconductor quantum dots.  J Nanosci Nanotechnol. 2004 Jul;4(6):569-74. PMID: 15518388 [PubMed - indexed for MEDLINE]

31: Smith AM, Nie S.  Chemical analysis and cellular imaging with quantum dots. Analyst. 2004 Aug;129(8):672-7. Review. PMID: 15344262 [PubMed - indexed for MEDLINE]

32: Gao X, Cui Y, Levenson RM, Chung LW, Nie S. In vivo cancer targeting and imaging with semiconductor quantum dots. Nat Biotechnol. 2004 Aug;22(8):969-76. Epub 2004 Jul 18. PMID: 15258594 [PubMed - indexed for MEDLINE]

33: Liang Z, Wu T, Lou H, Yu X, Taichman RS, Lau SK, Nie S, Umbreit J, Shim H. Inhibition of breast cancer metastasis by selective synthetic polypeptide against CXCR4. Cancer Res. 2004 Jun 15;64(12):4302-8.
PMID: 15205345 [PubMed - indexed for MEDLINE]

34: Nitin N, Santangelo PJ, Kim G, Nie S, Bao G.  Peptide-linked molecular beacons for efficient delivery and rapid mRNA detection
in living cells. Nucleic Acids Res. 2004 Apr 14;32(6):e58.
PMID: 15084673 [PubMed - indexed for MEDLINE]

35: Gao X, Nie S. Quantum dot-encoded mesoporous beads with high brightness and uniformity: rapid readout using flow cytometry.
Anal Chem. 2004 Apr 15;76(8):2406-10. PMID: 15080756 [PubMed - indexed for MEDLINE]

36: Doering WE, Nie S. Spectroscopic tags using dye-embedded nanoparticles and surface-enhanced Raman scattering. Anal Chem. 2003 Nov 15;75(22):6171-6. PMID: 14615997 [PubMed - indexed for MEDLINE]

37: Gao X, Nie S. Molecular profiling of single cells and tissue specimens with quantum dots. Trends Biotechnol. 2003 Sep;21(9):371-3. Review. PMID: 12948664 [PubMed - indexed for MEDLINE]

38: Bailey RE, Nie S. Alloyed semiconductor quantum dots: tuning the optical properties without changing the particle size. J Am Chem Soc. 2003 Jun 11;125(23):7100-6. PMID: 12783563 [PubMed - indexed for MEDLINE]

39: Gao X, Chan WC, Nie S. Quantum-dot nanocrystals for ultrasensitive biological labeling and multicolor optical encoding. J Biomed Opt. 2002 Oct;7(4):532-7. PMID: 12421118 [PubMed - indexed for MEDLINE]

40: Maxwell DJ, Taylor JR, Nie S. Self-assembled nanoparticle probes for recognition and detection of biomolecules. J Am Chem Soc. 2002 Aug 14;124(32):9606-12. PMID: 12167056 [PubMed - indexed for MEDLINE]

41: Chan WC, Maxwell DJ, Gao X, Bailey RE, Han M, Nie S.  Luminescent quantum dots for multiplexed biological detection and imaging. Curr Opin Biotechnol. 2002 Feb;13(1):40-6. Review. PMID: 11849956 [PubMed - indexed for MEDLINE]

[ Last edited by fanhbu on 2008-12-18 at 13:24 ]
19Â¥2008-12-18 13:20:57
ÒÑÔÄ   »Ø¸´´ËÂ¥   ¹Ø×¢TA ¸øTA·¢ÏûÏ¢ ËÍTAºì»¨ TAµÄ»ØÌû

fanhbu

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kqy920(½ð±Ò+5):лл·ÖÏí£¡»¶Ó­³£À´
ÐÕ      Ãû¡¿£ºA. Paul Alivisatos


¡¾Ñо¿·½Ïò¡¿£ºhttp://www.cchem.berkeley.edu/pagrp/overview.html
NANOCRYSTALS: BUILDING BLOCKS FOR SOLID STATE CHEMISTRY AND MATERIALS DESIGN

Nanometer size inorganic crystals are playing an increasingly important role in solid state physics, chemistry, materials science, and even biology. Many fundamental properties of a crystal (e.g., ionization potential, melting point, band gap, saturation magnetization) depend upon the solid being periodic over a particular length scale, typically in the nm regime. By precisely controlling the size and surface of a nanocrystal, its properties can be tuned. Using techniques of molecular assembly, new nanocrystal based materials can in turn be created.

II. SCALING LAWS

As the number of atoms in a cluster increases, there is a critical size above which one particular bonding geometry; characteristic of an extended solid "locks in." As more atoms are added, the total volume and the number of surface atoms change, but the basic nature of the chemical bonds in the cluster does not. In this regime, the properties of nanocrystals vary smoothly, slowly extrapolating to bulk values, according to scaling laws. Many scaling laws have been hypothesized, a few are verified. For instance, the band gap of a semiconductor, such as Si, InAs, or CdSe, all increase with size, roughly as 1/r2, and their melting temperatures all decrease with size, roughly as 1/r, and these observations can be described well theoretically. Other size dependent scaling laws are topics of current research: How long does it take for a crystal to isomerize between two stable bonding geometries? How do the selection rules for absorption and emission of light depend upon the crystal size (translational symmetry)? What is the largest crystal that can be made defect free? In our fundamental studies of nanocrystal physics, we employ a wide range of spectroscopic and structural experimental tools, as well as computer simulation.

III. SYNTHESIS

The ability to make nanocrystals of high quality (uniform size, no defects except the ones we want, designed surface, etc.) is key to this area of science, and also interesting in its own right. We grow nanocrystals by injecting organometallic precursors into pure, hot surfactants. Some important questions of solid state chemistry can be addressed in the synthesis of nanocrystals. How does nucleation of a solid occur? What governs the rate of growth of a crystal? What is the stress and strain at the interface between a core and a shell of different materials? In addition to fundamental studies of nanocrystal synthesis, we are interested in developing automated, self-correcting nanocrystal syntheses, surface derivitization, and methods for nanocrystal characterization and assembly.

IV. MATERIALS DESIGN TARGETS

Nanocrystal/polymer composites for light emitting diodes and photovoltaics
Single nanocrystal-single electron transistor (with P. McEuen, Physics)
Nanocrystal/antibody conjugates as biological tag molecules (with S. Weiss, LBNL)
DNA directed assembly of nanocrystal patterns (with P. Schultz)
Nanocrystal photo-catalysis
Mechanical properties of nanocrystal composites
http://www.cchem.berkeley.edu/pagrp/overview.html




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Á¿×ÓµãÁìÓòÀïÃæµÄ´óÅ££¬ÅíЦ¸ÕÔøÔÚÄÇ×ö²©ºó£¬ÄÇÆª·¢±íÔÚnatureÉϵľ­µäÎÄÏײ»Öª±»ÒýÁ˶àÉÙ´ÎÁË£¬Ëû¶ÔÁ¿×ÓµãµÄÓ¦ÓÿªÍØÁ˲»ÉÙеÄÁìÓò£¬Í¬ÄôÊéÃ÷ǰºó·¢±íÔÚscienceÉϵÄÁ¿×ÓµãÔÚÉúÎïÉϵÄÓ¦Ó÷îΪ¾­µä£¬ÁíÍ⣬Ëû¹ØÓÚÄÉÃ×Á£×ÓµÄÄÇÆª×ÛÊöÒýÓôÎÊýÒѳ¬¹ý3000´Î£¬ÊÇΪ±Ø¶ÁÎÄÏס£
1.  Title: Semiconductor clusters, nanocrystals, and quantum dots
Author(s): Alivisatos AP
Source: SCIENCE   Volume: 271   Issue: 5251   Pages: 933-937   Published: FEB 16 1996
Times Cited: 3,699
  
2.  Title: Semiconductor nanocrystals as fluorescent biological labels
Author(s): Bruchez M, Moronne M, Gin P, et al.
Source: SCIENCE   Volume: 281   Issue: 5385   Pages: 2013-2016   Published: SEP 25 1998
Times Cited: 2,204
  
3.  Title: Shape control of CdSe nanocrystals
Author(s): Peng XG, Manna L, Yang WD, et al.
Source: NATURE   Volume: 404   Issue: 6773   Pages: 59-61   Published: MAR 2 2000
Times Cited: 1,402
  
4.  Title: LIGHT-EMITTING-DIODES MADE FROM CADMIUM SELENIDE NANOCRYSTALS AND A SEMICONDUCTING POLYMER
Author(s): COLVIN VL, SCHLAMP MC, ALIVISATOS AP
Source: NATURE   Volume: 370   Issue: 6488   Pages: 354-357   Published: AUG 4 1994
Times Cited: 1,327
  
5.  Title: Perspectives on the physical chemistry of semiconductor nanocrystals
Author(s): Alivisatos AP
Source: JOURNAL OF PHYSICAL CHEMISTRY   Volume: 100   Issue: 31   Pages: 13226-13239   Published: AUG 1 1996
Times Cited: 1,308
  
6.  Title: Hybrid nanorod-polymer solar cells
Author(s): Huynh WU, Dittmer JJ, Alivisatos AP
Source: SCIENCE   Volume: 295   Issue: 5564   Pages: 2425-2427   Published: MAR 29 2002
Times Cited: 1,164
  
7.  Title: Organization of 'nanocrystal molecules' using DNA
Author(s): Alivisatos AP, Johnsson KP, Peng XG, et al.
Source: NATURE   Volume: 382   Issue: 6592   Pages: 609-611   Published: AUG 15 1996
Times Cited: 1,016
  
8.  Title: Colloidal nanocrystal shape and size control: The case of cobalt
Author(s): Puntes VF, Krishnan KM, Alivisatos AP
Source: SCIENCE   Volume: 291   Issue: 5511   Pages: 2115-2117   Published: MAR 16 2001
Times Cited: 946
  
9.  Title: Epitaxial growth of highly luminescent CdSe/CdS core/shell nanocrystals with photostability and electronic accessibility
Author(s): Peng XG, Schlamp MC, Kadavanich AV, et al.
Source: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   Volume: 119   Issue: 30   Pages: 7019-7029   Published: JUL 30 1997
Times Cited: 808
  
10.  Title: Synthesis of soluble and processable rod-, arrow-, teardrop-, and tetrapod-shaped CdSe nanocrystals
Author(s): Manna L, Scher EC, Alivisatos AP
Source: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   Volume: 122   Issue: 51   Pages: 12700-12706   Published: DEC 27 2000
Times Cited: 698


.

[ Last edited by fanhbu on 2008-12-18 at 13:44 ]
20Â¥2008-12-18 13:31:39
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