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英译汉 ,三句话---有机羟吲哚衍生物方面
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| A general and efficient method for the synthesis of oxindole derivatives through visible-light-induceddifluoromethylenephosphonation of N-arylacrylamides has been developed. The phosphonodifluoromethyl radicals, which is generated in situ from the corresponding BrCF2PO(OEt)2 under visible-lightirradiation, in combination with N-arylacrylamides furnished difluoromethylenephosphonated oxindoles via a proposed tandem radical cyclization process. Notable advantages of this method include its simplicity and mild conditions, avoidance of toxic reagents, and compatibility with a variety of functionalgroups. |
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