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Iron oxyhydroxides (FeOOH), with ¦Á-, ¦Â-, and ¦Ã-phases, are
among the most common constituents of the Earth's crust.
They play a crucial role in regulating the mobility of phos?phates in natural aquatic and soil environments, as phos?phate ions can be strongly bound to the surface of FeOOH.
Intensive efforts have been devoted to the study of the inter?actions between PO4
3? and FeOOH, covering a great number
of topics, such as the phase and size effects of FeOOH,35,36
the nature and conditions for the formation of iron phos?phate on the surface,36¨C38 and the surface adsorption models
and mechanisms.12,37,39¨C41 To our knowledge, there is no re?port on the intended synthesis of bulk iron phosphates from
FeOOH.

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