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金虫 (小有名气)

[求助] 长晶体 已有1人参与

请问前辈们有做过稀土和卟啉配位长单晶的吗?想做,不知道怎么合成

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morningbear

至尊木虫 (著名写手)

【答案】应助回帖

感谢参与,应助指数 +1
卟啉酞菁的单晶很难长。大部分都是做纳米MOFs,或者对MOFs进行修饰的工作。你可以参考一下。
很多年前,稀土和卟啉酞菁还有做夹心配合物的。
[1]        Zhao X, Yuan L, Zhang Z-q, et al. Synthetic methodology for the fabrication of porous porphyrin materials with metal–organic–polymer aerogels. Inorg Chem, 2016, 55(11): 5287-5296
[2]        Lee DH, Kim S, Hyun MY, et al. Controlled growth of narrowly dispersed nanosize hexagonal mof rods from mn(iii)-porphyrin and in(no3)3 and their application in olefin oxidation. Chem Commun, 2012, 48(44): 5512-5514
[3]        Lu K, He C, Guo N, et al. Chlorin-based nanoscale metal–organic framework systemically rejects colorectal cancers via synergistic photodynamic therapy and checkpoint blockade immunotherapy. J Am Chem Soc, 2016, 138(38): 12502-12510
[4]        Sun Y, Sun L, Feng D, et al. An in situ one-pot synthetic approach towards multivariate zirconium mofs. Angew Chem Int Ed, 2016, 55(22): 6471-6475
[5]        Wang K, Lv X-L, Feng D, et al. Pyrazolate-based porphyrinic metal–organic framework with extraordinary base-resistance. J Am Chem Soc, 2016, 138(3): 914-919
[6]        Zhang Z, Su X, Yu F, et al. Three novel metal-organic frameworks based on flexible porphyrin tetracarboxylic acids as highly effective catalysts. J Solid State Chem, 2016, 238, 53-59
[7]        Xu R, Wang Y, Duan X, et al. Nanoscale metal–organic frameworks for ratiometric oxygen sensing in live cells. J Am Chem Soc, 2016, 138(7): 2158-2161
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