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ÎÄÕÂÃû£ºSynthesis, characterization and properties of TAP©\6FDA hyperbranched polyimides with different branching degree ×÷ÕߣºYing Chen, Qiuyu Zhang, Wanlu Sun, Xingfeng Lei, Pan Yao ³ö°æÐÅÏ¢£ºPolymer International, 2014, 63: 788-795. ÇóÕâÆªÎÄÕµÄSCI Ë÷ÒýÐÅÏ¢£¬ÈçÓÐPDF¼ìË÷ÐÅÏ¢Çë·¢¸øÎÒ¡£ |
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Synthesis, characterization and properties of TAP-6FDA hyperbranched polyimides with different branching degrees ×÷Õß:Chen, Y (Chen, Ying)[ 1 ] ; Zhang, QY (Zhang, Qiuyu)[ 1 ] ; Sun, WL (Sun, Wanlu)[ 1 ] ; Lei, XF (Lei, Xingfeng)[ 1 ] ; Yao, P (Yao, Pan)[ 1 ] POLYMER INTERNATIONAL ¾í: 63 ÆÚ: 4 Ò³: 788-795 DOI: 10.1002/pi.4594 ³ö°æÄê: APR 2014 ²é¿´ÆÚ¿¯ÐÅÏ¢ POLYMER INTERNATIONAL ³ö°æÉÌ WILEY-BLACKWELL, 111 RIVER ST, HOBOKEN 07030-5774, NJ USA ISSN: 0959-8103 eISSN: 1097-0126 Ñо¿ÁìÓò Polymer Science ÕªÒª A series of hyperbranched polyimides were successfully synthesized by condensation polymerization of A(2)-type dianhydride monomer 2,2-bis(3,4-dicarboxylphenyl) hexafluoropropane dianhydride (6FDA) and B ' B-2-type triamine monomer 2,4,6-triaminopyrimidine (TAP). Polymers with different branching degrees (DB) and terminated groups were obtained by changing the monomer addition order and the monomer molar ratio. Fourier transform infrared spectroscopy and H-1 NMR were used to verify the structure of the prepared polyimides, which indicated that the amino group still existed in all the products. The DB of the polymers indicated by H-1 NMR increased from 30% to 79% with the molar ratio of TAP:6FDA decreasing from 1:1 to 1:2. The absolute molecular weights were measured by size-exclusion chromatography with multi-angle laser light-scattering detection, which suggested that the highest molecular weight would be obtained when the molar ratio of amino groups:anhydride groups of the monomers was 3:3.2. With the DB increasing, the d-spacing values indicated by wide angle X-ray diffraction increased from 5.15 angstrom to 5.68 angstrom and the UV - visible spectra of the polymers exhibited decreasing cut-off wavelengths. The 5% weight loss temperature in nitrogen increased with decreasing content of TAP monomer, and the glass transition temperatures of the obtained polyimides decreased from 282 degrees C to 258 degrees C with increasing DB. (c) 2013 Society of Chemical Industry ¹Ø¼ü´Ê ×÷Õ߹ؼü´Ê:polyimides; properties; synthesis; hyperbranched; branching degree KeyWords Plus:GAS-TRANSPORT PROPERTIES; AROMATIC POLYIMIDES; 3,3',4,4'-BENZOPHENONETETRACARBOXYLIC DIANHYDRIDE; DENDRITIC POLYMERS; 1,3,5-TRIS(4-AMINOPHENOXY)BENZENE; ORGANOSOLUBILITY; ANHYDRIDE; SYSTEM ×÷ÕßÐÅÏ¢ ͨѶ×÷ÕßµØÖ·: Zhang, QY (ͨѶ×÷Õß) Northwestern Polytech Univ, Dept Appl Chem, Sch Sci, Xian 710129, Peoples R China. ÔöÇ¿×éÖ¯ÐÅÏ¢µÄÃû³Æ Northwestern Polytechnical University µØÖ·: [ 1 ] Northwestern Polytech Univ, Dept Appl Chem, Sch Sci, Xian 710129, Peoples R China ÔöÇ¿×éÖ¯ÐÅÏ¢µÄÃû³Æ Northwestern Polytechnical University µç×ÓÓʼþµØÖ·:qyzhang2012@163.com »ù½ð×ÊÖúÖÂл »ù½ð×ÊÖú»ú¹¹ ÊÚȨºÅ National Natural Science Foundation of China 51173146 51173147 Northwestern Polytechnical University Z2013163 ²é¿´»ù½ð×ÊÖúÐÅÏ¢¹Ø±Õ»ù½ð×ÊÖúÐÅÏ¢ The authors are grateful for the financial support provided by the National Natural Science Foundation of China (no. 51173146, no. 51173147) and the Graduate Starting Seed Fund of Northwestern Polytechnical University (grant no. Z2013163). ³ö°æÉÌ WILEY-BLACKWELL, 111 RIVER ST, HOBOKEN 07030-5774, NJ USA Àà±ð / ·ÖÀà Ñо¿·½Ïò olymer ScienceWeb of Science Àà±ð olymer ScienceÎÄÏ×ÐÅÏ¢ ÎÄÏ×ÀàÐÍ:Article ÓïÖÖ:English Èë²ØºÅ: WOS:000332393600027 ISSN: 0959-8103 eISSN: 1097-0126 ÆäËûÐÅÏ¢ IDS ºÅ: AC3CW Web of Science ºËÐĺϼ¯ÖÐµÄ "ÒýÓõIJο¼ÎÄÏ×": 34 Web of Science ºËÐĺϼ¯ÖÐµÄ "±»ÒýƵ´Î": 2 JCR® Àà±ð JCR ·ÖÇø POLYMER SCIENCE Q2 Êý¾ÝÀ´×ÔµÚ 2015 °æ Journal Citation Reports® |
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