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请问有谁知道四面体的Zn与八面体的Zn在热力学稳定上有什么区别啊，文章审稿意见要求我们从这方面进行解释。谢谢大家了，文章投稿问题不断，请大家多多帮忙。 2) Moreover I doubt that the solubility of the different compounds should be an issue for vapour phase reactions and moreover coordination polymers are not dissolved as persisting periodic entities. Nevertheless, assuming a solvent film on the particles this could affect the product formation, mentioning of Ostwalds step rule would ease the understanding. In addition, I would suggest to compare the energetics of tetrahedral and octahedral zinc carboxylates. Considering the predominantly occuring tetrahedral coordination of zinc in similar compounds might be the reason why reactions only proceed from octahedral to tetrahedral and not vice versa. 老师让我从这方面进行比较 Compare the thermal stability of these tetrahedral and octahedral Zn complexes by the way of energy 在分子动力学方面如何解释，H2O,DMF,MeOH,在空气中的浓度问题 Methanol, water and DMF have significantly different volatility: at 25 °C the vapor pressure of methanol is about 127 mmHg, of water is about 24 mmHg, of DMF is about 4 mmHg. This means that there is about 32 times more methanol than DMF available for the VAG process, do the authors have an idea of the possible effects on the kinetics of the reaction? |
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