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The presence and content of Mn3+ have been demonstrated to intricately affect the electrode performance [5]. On the one hand, the larger ionic radius of Mn3+ relative to Mn4+ results in an expanded lattice, which benefits fast Li+ diffusion [15]. On the other hand, Mn3+ can induce a Jahn¨CTeller structural distortion and dissolve into the electrolyte via a disproportionation reaction, which has an adverse effect on the capacity retention ·¢×ÔСľ³æAndroid¿Í»§¶Ë |
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