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| Super absorbent polymer (SAP) sorbs copious amount of liquid water but its sorption power for water vapor is quite low. On the other hand, mesoporous silica loaded with CaCl2 (MPS-CC) has high sorption capacity for water vapor. However, this is determined by the salt loading, which is limited due to its corrosiveness. Even by simple powder blending of 75 mass% of SAP and the balance of MPS-CC (SAP75/MPS-CC25), the 3-hour maximum specific water uptake (g H2O/g sorbent) reached the maximum, 3 times the equilibrium uptake of MPS-CC. The sorption property was further enhanced by developing a new sorbent in which mesoporous silica was grown on the surface of swelling SAP and then impregnated by CC in ethanol. In the new sorbent (SAP-iMPS-CC), MPS grew organized, straight and lengthwise by the help of SAP. Owing to such intimate contact between MPS and SAP, the 3-hour specific water uptake of the new sorbents grown for more than 24 h (SAP-iMPS-CC24) was kept constant at the value of 2 times that of SAP75/MPS25. The SAP mass% of SAP-iMPS-144 could reach 25 without the sacrifice of sorption capacity. |
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3Â¥2016-05-18 13:53:04
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DreamX~: ½ð±Ò+20, ·ÒëEPI+1, ¡ï¡ï¡ï¡ï¡ï×î¼Ñ´ð°¸ 2016-05-18 13:52:54
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Owing to such intimate contact between MPS and SAP, the 3-hour specific water uptake of the new sorbents grown for more than 24 h (SAP-iMPS-CC24) was kept constant at the value of 2 times that of SAP75/MPS25. The SAP mass% of SAP-iMPS-144 could reach 25 without the sacrifice of sorption capacity. MPS ºÍ SAP Ö®¼äµÄ½Ó´¥Èç´Ë½ôÃÜ£¬Ê¹µÃ·¢Óý24h ÒÔÉϵÄÕâÖÖÐÂÎü׿Á(SAP-iMPS-CC24)µÄ3Сʱ±ÈË®ÎüÊÕÖµÒ»Ö±Îȶ¨ÊÇSAP75/MPS25µÄ2±¶¡£SAP-iMPS-144ÖеÄSAPÖÊÁ¿°Ù·ÖÂʿɸߴï25¶ø»¹²»»á½µµÍÆäÎü¸½ÄÜÁ¦¡£ |
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