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Predictions of healing performance for solvent-promoted self-healing materials by using Hansen solubility

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Predictions of healing performance for solvent-promoted self-healing materials by using Hansen solubility parameters
×÷Õß:Ma, WP (Ma, Wanpeng)[ 1 ] ; Zhang, W (Zhang, Wei)[ 1 ] ; Zhao, Y (Zhao, Yang)[ 1 ] ; Yu, HL (Yu, Helong)[ 1 ] ; Wang, SJ (Wang, Sijie)[ 1 ] ; Wang, Y (Wang, Yong)[ 1 ]


MATERIALS LETTERS


¾í: 163
Ò³: 244-246
DOI: 10.1016/j.matlet.2015.10.090

³ö°æÄê: JAN 15 2016

²é¿´ÆÚ¿¯ÐÅÏ¢

MATERIALS LETTERS  

³ö°æÉÌ ELSEVIER SCIENCE BV, PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS

ISSN: 0167-577X
eISSN: 1873-4979

Ñо¿ÁìÓò Materials Science
Physics



ÕªÒª
Solvents have been used for self-healing materials for swelling mechanism. However, no study has investigated the prediction of solvent healing performance. In this work, we used Hansen solubility parameters (HSPs) to predict crack healing. A 2D solvent map was constructed by polarity and hydrogen bonding parameter. Results showed that the degree of swelling was relative to the HSP distance (D) between solvent and epoxy resin in the map. Moreover, manual healing experiments showed that solvent healing performance was correlated with swelling. Therefore, the healing performance of solvents could be predicted by using HSPs. For epoxy resin, solvents with D < 15 had excellent healing performance. This framework simultaneously considered D and water solubility and could be readily extended to fast screen green solvents for microcapsule-loaded self-healing materials. (C) 2015 Elsevier B.V. All rights reserved.

¹Ø¼ü´Ê
×÷Õ߹ؼü´Ê:Biomimetic; Polymers; Self-healing; Hansen solubility parameters; Welding; Functional

KeyWords PlusOLYMER; EPOXY; DICYCLOPENTADIENE; COMPOSITES; KINETICS

×÷ÕßÐÅÏ¢
ͨѶ×÷ÕßµØÖ·: Ma, WP (ͨѶ×÷Õß) Acad Armored Forces Engn, Sci & Technol Remfg Lab, Beijing 100072, Peoples R China.
  ÔöÇ¿×éÖ¯ÐÅÏ¢µÄÃû³Æ
    Academy of Armored Forces Engineering - China  


µØÖ·:  [ 1 ] Acad Armored Forces Engn, Sci & Technol Remfg Lab, Beijing 100072, Peoples R China
  ÔöÇ¿×éÖ¯ÐÅÏ¢µÄÃû³Æ
    Academy of Armored Forces Engineering - China  


µç×ÓÓʼþµØÖ·:mawp010@126.com

»ù½ð×ÊÖúÖÂл
»ù½ð×ÊÖú»ú¹¹ ÊÚȨºÅ
National Natural Science Foundation of China  50775222  
Equipment Repair and Reformation Program, China  2014WG13  
²é¿´»ù½ð×ÊÖúÐÅÏ¢¹Ø±Õ»ù½ð×ÊÖúÐÅÏ¢   

The work was supported by the National Natural Science Foundation of China (Grant no. 50775222) and the Equipment Repair and Reformation Program, China (Grant 2014WG13).

³ö°æÉÌ
ELSEVIER SCIENCE BV, PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS

Àà±ð / ·ÖÀà
Ñо¿·½Ïò:Materials Science; Physics

Web of Science Àà±ð:Materials Science, Multidisciplinary; Physics, Applied

ÎÄÏ×ÐÅÏ¢
ÎÄÏ×ÀàÐÍ:Article

ÓïÖÖ:English

Èë²ØºÅ: WOS:000366081400061

ISSN: 0167-577X

eISSN: 1873-4979

ÆÚ¿¯ÐÅÏ¢

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