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In the 250 and 1750 cm −1 region, the spectrum of MWNT-CoP 1 is dominated by the signals of the porphyrin, while the presence of MWNT is confirmed by the 2D and D+D¡ä bands at ¡«2730 and 2950 cm −1 , respectively. The spectra of the porphyrin-containing derivatives also exhibit interesting features between 2100 and 2200 cm −1 ; this region is known to be the one where the triple bond stretching mode is observed. The band at 2154 cm −1 (red spectrum) was attributed to the vibration of the protected acetylene moieties in CoP 3. After deprotection and polymerization this band disappears and gives two bands at ¡«2110 and 2190 cm −1 that was attributed to the ethynyl and 1,3-butadiynyl moieties,respectively.
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1223270778(fjtony163´ú·¢): ½ð±Ò+10, ´ú·¢ 2016-04-10 11:02:54
fjtony163: ·­ÒëEPI+1, ´ú·¢ 2016-04-10 11:03:00
In the 250 and 1750 cm −1 regions, the spectrum of MWNT-CoP 1 was dominated by the signals that belong to(or originate from) porphyrin, while the presence of MWNT was confirmed (signified) by the 2D and D+D¡ä bands at ¡«2730 and 2950 cm −1 , respectively. The spectra of the porphyrin-containing derivatives also exhibited interesting features between 2100 and 2200 cm −1 , a region known to have triple bond stretching. The band at 2154 cm −1 (red spectrum) was attributed to the vibration of the protected acetylene moieties in CoP 3, which  disappeared after deprotection and polymerization, and gave two new bands at ¡«2110 and 2190 cm −1 that was attributed to the ethynyl and 1,3-butadiynyl moieties, respectively.
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